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The motivation of the present work was to understand the mechanism by which alcohols produce less aromatic species in their combustion process than an equal amount of hydrocarbon with similar molecular structure does. Due to its numerous advantages over short-chain alcohols, butanol has been considered very promising in soot reduction. Excluding the influence of spray, vaporization and mixing process in engine cases, an adiabatic constant-pressure reactor model was applied to investigate the effect of butanol additives on aromatic species, which are known to be soot precursors, in fuel-rich butane flames. To keep the carbon flux constant, 5% and 10% oxygen by mass of the fuel were added to butane using butanol additive, respectively. Based on the soot reduction effects proposed in literature, effects on temperature, key radical concentrations and the carbon removal from the pathway to aromatic species were considered to identify the major mechanism of reduction in aromatic species.

A finite diffusion method is presented in this paper to model droplet evaporation for complex liquid mixture composed of different homogeneous groups. Multiple components fuel mixture is represented by separate distribution functions to describe the composition of each homogeneous group in the mixture. Only a few parameters are required to describe the mixture. Quasi-steady assumption is applied in the determination of evaporation rates and heat flux to the droplet, and the effects of surface regression, finite diffusion and preferential vaporization of the mixture are included in the liquid phase equations using an effective properties approach. The proposed model was validated by comparing against experimental measurements for single, isolated droplets of n-decane, kerosene, heptane-decane and diesel-butanol. The present model was applied to simulate the evaporation of isolated droplets with composition of typical diesel.

Butanol, which is a renewable biofuel, has been regarded as a promising alternative fuel for internal combustion engines. When blended with diesel and applied to pilot ignited natural gas engines, butanol has the capability to achieve lower emissions without sacrifice on thermal efficiency. However, high blend ratio of butanol is limited by its longer ignition delay caused by the higher latent heat and higher octane number, which restricts the improvement of emission characteristics. In this paper, the potential of increasing butanol blend ratio by adding hot exhaust gas recirculation (EGR) is investigated. 3D CFD model based on a detailed kinetic mechanism was built and validated by experimental results of natural gas engine ignited by diesel/butanol blends. The effects of hot EGR is then revealed by the simulation results of the combustion process, heat release traces and also the emissions under different diesel/butanol blend ratios.

Alcohols, because of their potential to be produced from renewable sources and their characteristics suitable for clean combustion, are considered potential fuels which can be blended with fossil-based gasoline for use in internal combustion engines. As such, n-butanol has received a lot of attention in this regard and has shown to be a possible alternative to pure gasoline. The main issue preventing butanol's use in modern engines is its relatively high cost of production. Acetone-Butanol-Ethanol (ABE) fermentation is one of the major methods to produce bio-butanol. The goal of this study is to investigate the combustion characteristics of the intermediate product in butanol production, namely ABE, and hence evaluate its potential as an alternative fuel. Acetone, n-butanol and ethanol were blended in a 3:6:1 volume ratio and then splash blended with pure ethanol-free gasoline with volumetric ratios of 0%, 20%, 40% to create various fuel blends.

In the present study, we developed a reduced chemical reaction mechanism consisted of n-heptane and toluene as surrogate fuel species for diesel engine combustion simulation. The LLNL detailed chemical kinetic mechanism for n-heptane was chosen as the base mechanism. A multi-technique reduction methodology was applied, which included directed relation graph with error propagation and sensitivity analysis (DRGEPSA), non-essential reaction elimination, reaction pathway analysis, sensitivity analysis, and reaction rate adjustment. In a similar fashion, a reduced toluene mechanism was also developed. The reduced n-heptane and toluene mechanisms were then combined to form a diesel surrogate mechanism, which consisted of 158 species and 468 reactions. Extensive validations were conducted for the present mechanism with experimental ignition delay in shock tubes and laminar flame speeds under various pressures, temperatures and equivalence ratios related to engine conditions.

With the development of advanced ABE fermentation technology, the volumetric percentage of acetone, butanol and ethanol in the bio-solvents can be precisely controlled. To seek for an optimized volumetric ratio for ABE-diesel blends, the previous work in our team has experimentally investigated and analyzed the combustion features of ABE-diesel blends with different volumetric ratio (A: B: E: 6:3:1; 3:6:1; 0:10:0, vol. %) in a constant volume chamber. It was found that an increased amount of acetone would lead to a significant advancement of combustion phasing whereas butanol would compensate the advancing effect. Both spray dynamic and chemistry reaction dynamic are of great importance in explaining the unique combustion characteristic of ABE-diesel blend. In this study, a semi-detailed chemical mechanism is constructed and used to model ABE-diesel spray combustion in a constant volume chamber.

Ternary blends of butanol-biodiesel-diesel with different blending ratios were tested inside a constant volume chamber under various ambient temperatures so as to investigate the spray and combustion characteristics of the fuels. Applying the high speed imaging, a sudden drop in spray penetration was observed at ambient temperature of 800 K and 900 K for fuels with certain blending ratio, but not at 1000 K and 1200 K. When the spray penetration of the butanol-biodiesel-diesel blends was compared to that of the biodiesel-diesel blends under non-combusting environment, a sudden drop in spray penetration length was also observed at 1100 K. The results indicated that for the non-combusting case, the tip of the spray jet erupted into a plume sometime after injection for the butanol-biodiesel-diesel blend at an ambient temperature of 1100 K. Such phenomenon was not seen with the biodiesel-diesel blend, neither with the same fuel but at a lower ambient temperature of 900 K.

In this work, an efficient and unified combustion model is introduced to simulate the flame propagation, diffusion-controlled combustion, and chemically-driven ignition in both SI and CI engine operation. The unified model is constructed upon a G-equation model which addresses the premixed flame propagation. The concept of the Livengood-Wu integral is used with tabulated ignition delay data to account for the chemical kinetics which is responsible for the spontaneous ignition of fuel-air mixture. A set of rigorously defined operations are used to couple the evolution of the G scalar field and the Livengood-Wu integral. The diffusion-controlled combustion is simulated equivalent to applying the Burke-Schumann limit. The combined model is tested in the simulation of the premixed SI combustion in a constant volume chamber, as well as the CI combustion in a conventional small bore diesel engine.

Acetone-Butanol-Ethanol (ABE), an intermediate product in the ABE fermentation process for producing bio-butanol, is considered a promising alternative fuel because it not only preserves the advantages of oxygenated fuel which typically emit less pollutants compared to conventional diesel, but also lowers the cost of fuel recovery for each individual component during the fermentation. With the development of advanced ABE fermentation technology, the volumetric percentage of acetone, butanol and ethanol in the bio-solvents can be precisely controlled. In this respect, it is desirable to estimate the performance of different ABE blends to determine the best blend and optimize the production process accordingly. ABE fuels with different component ratio, (A: B: E: 6:3:1; 3:6:1; 0:10:0, vol. %), were blended with diesel and tested in a constant volume chamber.

In order to comply with the stringent emission regulations, many researchers have been focusing on diesel-compressed natural gas (CNG) dual fuel operation in compression ignition (CI) engines. The diesel-CNG dual fuel operation mode has the potential to reduce both the soot and NOx emissions; however, the thermal efficiency is generally lower than that of the pure diesel operation, especially under the low and medium load conditions. The current experimental work investigates the potential of using diesel-1-butanol blends as the pilot fuel to improve the engine performance and emissions. Fuel blends of B0 (pure diesel), B10 (90% diesel and 10% 1-butanol by volume) and B20 (80% diesel and 20% 1-butanol) with 70% CNG substitution were compared based on an equivalent input energy at an engine speed of 1200 RPM. The results indicated that the diesel-1-butanol pilot fuel can lead to a more homogeneous mixture due to the longer ignition delay.

Dual-fuel combustion combining a premixed charge of compressed natural gas (CNG) and a pilot injection of diesel fuel offer the potential to reduce diesel fuel consumption and drastically reduce soot emissions. In this study, dual-fuel combustion using methane ignited with a pilot injection of No. 2 diesel fuel, was studied in a single cylinder diesel engine with optical access. Experiments were performed at a CNG substitution rate of 70% CNG (based on energy) over a wide range of equivalence ratios of the premixed charge, as well as different diesel injection strategies (single and double injection). A color high-speed camera was used in order to identify and distinguish between lean-premixed methane combustion and diffusion combustion in dual-fuel combustion. The effect of multiple diesel injections is also investigated optically as a means to enhance flame propagation towards the center of the combustion chamber.

The modeling of fuel jet atomization is key in the characterization of Internal Combustion (IC) engines, and 3D Computational Fluid Dynamics (CFD) is a recognized tool to provide insights for design and control purposes. Multi-hole injectors with counter-bored nozzle are the standard for Gasoline Direct Injection (GDI) applications and the Spray-G injector from the Engine Combustion Network (ECN) is considered the reference for numerical studies, thanks to the availability of extensive experimental data. In this work, the behavior of the Spray-G injector is simulated in a constant volume chamber, ranging from sub-cooled (nominal G) to flashing conditions (G2), validating the models on Diffused Back Illumination and Phase Doppler Anemometry data collected in vaporizing inert conditions.

Cavitation plays a significant role in the spray characteristics and the subsequent mixing and combustion process in engines. Cavitation has beneficial effects on the development of the fuel sprays by improving injection velocity and promoting primary break-up. On the other hand, intense pressure peaks induced by the vapor collapse may lead to erosion damage and severe degradation of the injector performance. In the present paper, the transient cavitating flow in the injector-like geometry was investigated using the modified turbulence model and cavitation criterion. A local density correction was used in the Reynolds-averaged Navier-Stokes turbulence model to reduce the turbulent viscosity, which facilitates the cavitation development. The turbulent stress was also considered in the cavitation inception stage. The modified model is capable of reproducing the cavitating flow with an affordable computational cost.

Recent research has shown that butanol, instead of ethanol, has the potential of introducing a more suitable blend in diesel engines. This is because butanol has properties similar to current transportation fuels in comparison to ethanol. However, the main downside is the high cost of the butanol production process. Acetone-butanol-ethanol (ABE) is an intermediate product of the fermentation process of butanol production. By eliminating the separation and purification processes, using ABE directly in diesel blends has the potential of greatly decreasing the overall cost for fuel production. This could lead to a vast commercial use of ABE-diesel blends on the market. Much research has been done in the past five years concerning spray and combustion processes of both neat ABE and ABE-diesel mixtures. Additionally, different compositions of ABE mixtures had been characterized with a similar experimental approach.

Butanol has proved to be a very promising alternative fuel in recent years. The production of bio-butanol, typically done using the acetone-butanol-ethanol (ABE) fermentation process is expensive and consumes a lot of energy. Hence it is of interest to study the intermediate fermentation product, i.e. water-containing ABE as a potential fuel. The combustion and emissions performance of ABE29.5W0.5 (29.5 vol.% ABE, 0.5 vol.% water and gasoline blend), ABE30 (30 vol.% ABE and gasoline blend) and ABE0 (pure gasoline) were investigated in this study. The results showed that ABE29.5W0.5 enhanced engine torque by 9.6%-12.7% and brake thermal efficiency (BTE) by 5.2%-11.6% compared to pure gasoline, respectively. ABE29.5W0.5 also showed similar brake specific fuel consumption (BSFC) relative to pure gasoline.

Ethanol is the most widely used renewable fuel in the world now. Compared to ethanol, butanol is another very promising renewable fuel for internal combustion engines. It is less corrosive, and has higher energy density, lower vapor pressure and lower solubility in water. However, the use of Acetone-Butanol-Ethanol (ABE), an intermediate product in ABE fermentation, presents a cost advantage over ethanol and butanol and has attracted much attention recently. In this study, three high-alcohol-content gasoline blends (85% vol. of ethanol, butanol and ABE, referred as E85, B85 and ABE85, respectively) were investigated in a port-injection spark-ignition engine. ABE has a component ratio of 3:6:1. In addition, pure gasoline was also tested as a baseline for comparison. All fuels were tested under the same conditions (1200 RPM, Φ = 0.83−1.25, BMEP = 3 bar).

In the new combustion strategies such as RCCI and dual-fuel combustion, the diesel pilot injection plays a pivotal role as it determines the ignition characteristics of the mixture and ultimately the combustion and emission performance. In this regard, equivalence ratio distribution resulted from the pilot injection becomes very important. In this work, computation study is carried out using KIVA-3V to simulate the engine compression stroke from intake valve close (IVC) to close to TDC so as to investigate the impact of piston geometry, injection start timing and flow initialization on the equivalence ratio distribution from a pilot injection in HSDI engine.

Hydrogen fuel is a future energy to solve the problems of energy crisis and environmental pollution. Hydrogen internal combustion engines can combine the advantage of hydrogen without carbon pollution and the main basic structure of the traditional engines. However, the power of the port fuel injection hydrogen engines is smaller than the same volume gasoline engine because the hydrogen occupies the volume of the cylinder and reduces the air mass flow. The turbocharger can increase the power of hydrogen engines but also increase the NOx emission. Hence, a comprehensive controlling strategy to solve the contradiction of the power, BTE and NOx emission is important to improve the performance of hydrogen engines. This paper shows the controlling strategy for a four-stroke, 2.3L hydrogen engine with a turbocharger. The controlling strategy divides the operating conditions of the hydrogen engine into six parts according to the engine speeds and loads.

The purpose of this study is to investigate the possibility of acetone-butanol-ethanol (ABE) blended with diesel without further component recovery which has high costs blocking the industrial-scale production of bio-butanol. The combustion characteristics of ABE and diesel blends were studied in a constant volume chamber. In this study, 50% and 80% vol. ABE (without water) were mixed with diesel and the vol. % of acetone, butanol and ethanol were kept at 30%, 60% and 10% respectively. The in-cylinder pressure was recorded using a pressure transducer and the time-resolved natural luminosity was captured by high speed imaging. Combustion visualization using laser diagnostics would provide crucial fundamental information of the fuel's combustion characteristics. With the different percentage of the ABE blended in the diesel, the soot oxidation, the ignition delay and the soot lift-off length were studied in this work.

Due to the increasing consumption of fossil fuels, alternative fuels in internal combustion engines have attracted a lot of attention in recent years. Ethanol is the most common alternative fuel used in spark ignition (SI) engines due to its advantages of biodegradability, positively impacting emissions reduction as well as octane number improvement. Meanwhile, acetone is well-known as one of the industrial waste solvents for synthetic fibers and most plastic materials. In comparison to ethanol, acetone has a number of more desirable properties for being a viable alternative fuel such as its higher energy density, heating value and volatility.