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A model which converts flame arrival times at a head gasket ionization probe, used in a spark-ignition engine, into flame contours has been developed. The head gasket was manufactured at MIT using printed circuit board techniques. It has eight electrodes symmetrically spaced around the circumference (top of cylinder liner) and it replaces the conventional head gasket. The model is based on engine flame propagation rate data taken from the literature. Data from optical studies of S.I. engine combustion or studies utilizing optical fiber or ionization probe diagnostics were analyzed in terms of the apparent flame speed and the entrainment speed (flame speed relative to the fluid ahead of the flame). This gives a scaling relationship between the flame speed and the mass fraction burned which is generic and independent of the chamber shape.

Difficulties in the starting and operation of diesel engines at low temperatures are an important consideration in their design and operation, and in selection of the fuels for their use. Improvements in operation have been achieved primarily through external components of the engine and associated subsystems. A Rapid Compression Machine (RCM) has been modified to operate over a wide range of temperatures (−20°C to 100°C). It is used to isolate the combustion chamber in an environment in which all significant parameters are carefully defined and monitored. The influence of temperature and cetane number on the ignition and combustion processes are analyzed. Examination of the combustion characteristics show that temperature is by far the most influential factor affecting both ignition delay and heat release profiles. Cetane number (ASTM D-613) is not found to be a strong indicator of ignition delay for the conditions investigated.

This paper describes the use of a modified quasi-dimensional spark-ignition engine simulation code to predict the extent of cycle-to-cycle variations in combustion. The modifications primarily relate to the combustion model and include the following: 1. A flame kernel model was developed and implemented to avoid choosing the initial flame size and temperature arbitrarily. 2. Instead of the usual assumption of the flame being spherical, ellipsoidal flame shapes are permitted in the model when the gas velocity in the vicinity of the spark plug during kernel development is high. Changes in flame shape influence the flame front area and the interaction of the enflamed volume with the combustion chamber walls. 3. The flame center shifts due to convection by the gas flow in the cylinder. This influences the flame front area through the interaction between the enflamed volume and the combustion chamber walls. 4. Turbulence intensity is not uniform in cylinder, and varies cycle-to-cycle.

This paper provides an overview of spark-ignition engine unburned hydrocarbon emissions mechanisms, and then uses this framework to relate measured engine-out hydrocarbon emission levels to the processes within the engine from which they result. Typically, spark-ignition engine-out HC levels are 1.5 to 2 percent of the gasoline fuel flow into the engine; about half this amount is unburned fuel and half is partially reacted fuel components. The different mechanisms by which hydrocarbons in the gasoline escape burning during the normal engine combustion process are described and approximately quantified. The in-cylinder oxidation of these HC during the expansion and exhaust processes, the fraction which exit the cylinder, and the fraction oxidized in the exhaust port and manifold are also estimated.

An analysis method for characterizing fuel behavior during spark-ignition engine starting has been developed and applied to several sets of start-up data. The data sets were acquired from modern production vehicles during room temperature engine start-up. Two different engines, two control schemes, and two engine temperatures (cold and hot) were investigated. A cycle-by-cycle mass balance for the fuel was used to compare the amount of fuel injected with the amount burned or exhausted as unburned hydrocarbons. The difference was measured as “fuel unaccounted for”. The calculation for the amount of fuel burned used an energy release analysis of the cylinder pressure data. The results include an overview of starting behavior and a fuel accounting for each data set Overall, starting occurred quickly with combustion quality, manifold pressure, and engine speed beginning to stabilize by the seventh cycle, on average.

The direct injection spark-ignition engine is the only internal combustion engine with the potential to equal the efficiency of the diesel and to tolerate a wide range of fuel types and fuel qualities without deterioration of performance. However, this engine has low combustion efficiency and excessive hydrocarbon emissions when operating at light load. In this paper, potential sources of hydrocarbon emissions during light load operation are postulated and analyzed. The placement of fuel away from the primary combustion process in conjunction with a lack of secondary burnup are isolated as important hydrocarbon emissions mechanisms. Analyses show that increasing cylinder gas temperatures can improve secondary burnup of fuel which would reduce hydrocarbon emissions. Practical means to achieve this include higher compression ratio and use of ceramic parts in the combustion chamber.

A dynamometer-mounted four-cylinder Saturn engine was used to accumulate combustion chamber deposits (CCD), using an additized fuel. During each deposit accumulation test, the HC emissions were continuously measured. The deposit thickness at the center of the piston was measured at the beginning of each day. After the 50 and 35-hour tests, HC emissions were measured with isooctane, benzene, toluene, and xylene, with the deposited engine, and again after the deposits had been cleaned from the engine. The HC emissions showed a rapid rise in the first 10 to 15 hours and stabilization after about 25 hours of deposit accumulation. The HC increase due to CCD accumulation accounted for 10 to 20% of the total engine-out HC emissions from the deposit build-up fuel and 10 to 30% from benzene, isooctane, toluene, and xylene, making CCDs a significant HC emissions source from this engine. The HC emissions stabilized long before the deposit thickness.

An experimental study was conducted on a direct-injection stratified-charge (DISC) engine incorporating a combustion process similar to the Texaco Controlled Combustion System and operated with gasoline. Analysis of the injected fuel flow and the heat release showed that the combustion process was characterized by three distinct phases: fuel injection and distribution around the piston bowl, flame propagation through the stratified fuel-air mixture, and mixing-controlled burn-out with the heat-release rate proportional to the amount of unburned fuel in the combustion chamber. This characterization was consistent with previous visualization studies conducted on rapid-compression machines with similar configurations. Experiments with varied injection timing, spark plug location, and spark timing showed that the combustion timing relative to injection was critical to the hydrocarbon emissions from the engine.

The purpose of this work was to develop an understanding of how liquid fuel transported into the cylinder of a port-fuel-injected gasoline-fueled SI engine contributes to hydrocarbon (HC) emissions. To simulate the liquid fuel flow from the valve seat region into the cylinder, a specially designed fuel probe was developed and used to inject controlled amounts of liquid fuel onto the port wall close to the valve seat. By operating the engine on pre-vaporized Indolene, and injecting a small amount of liquid fuel close to the valve seat while the intake valve was open, we examined the effects of liquid fuel entering the cylinder at different circumferential locations around the valve seat. Similar experiments were also carried out with closed valve injection of liquid fuel at the valve seat to assess the effects of residual blowback, and of evaporation from the intake valve and port surfaces.

An experimental study was performed in a firing SI engine at conditions representative of the warmup phase of operation in which liquid gasoline films were established at various locations in the combustion chamber and the resulting impact on hydrocarbon emissions was assessed. Unique about this study was that it combined, in a firing engine environment, direct visual observation of the liquid fuel films, measurements of the temperatures these films were subjected to, and the determination from gas analyzers of burned and unburned fuel quantities exiting the combustion chamber - all with cycle-level resolution or better. A means of deducing the exhaust hydrocarbon emissions that were due to the liquid fuel films in the combustion chamber was developed. An increase in exhaust hydrocarbon emissions was always observed with liquid fuel films present in the combustion chamber.

An experimental study was performed to investigate the effects of various intake charge motion control valves (CMCVs) on mixture preparation, combustion, and hydrocarbon (HC) emissions during the cold start-up process of a port fuel injected spark ignition (SI) engine. Different charge motions were produced by three differently shaped plates in the CMCV device, each of which blocked off 75% of the engine's intake ports. Time-resolved HC, CO and CO2 concentrations were measured at the exhaust port exit in order to achieve cycle-by-cycle engine-out HC mass and in-cylinder air/fuel ratio. Combustion characteristics were examined through a thermodynamic burn rate analysis. Cold-fluid steady state experiments were carried out with the CMCV open and closed. Enhanced charge motion with the CMCV closed was found to shorten the combustion duration, which caused the location of 50% mass fraction burned (MFB) to occur up to 5° CA earlier for the same spark timing.

Experiments were conducted to determine the effects of substantial spark retard on combustion, hydrocarbon (HC) emissions, and exhaust temperature, under cold engine conditions. A single-cylinder research engine was operated at 20° C fluid temperatures for various spark timings and relative air/fuel ratios. Combustion stability was observed to decrease as the phasing of the 50% mass fraction burned (MFB) occurred later in the expansion stroke. A thermodynamic burn rate analysis indicated combustion was complete at exhaust valve opening with -20° before top dead center (BTDC) spark timings. Chemical and thermal energy of the exhaust gas was tracked from cylinder-exit to the exhaust runner. Time-resolved HC concentrations measured in the port and runner were mass weighted to obtain an exhaust HC mass flow rate. Results were compared to time averaged well downstream HC levels.

The effects of combustion chamber and intake valve deposit build-up on the knocking characteristics of a spark ignition engine were studied. A Chrysler 2.2 liter engine was run continuously for 180 hours to build up intake valve and combustion chamber deposits. In the tests reported here, the gasoline used contained a deposit controlling fuel additive. The engines's octane requirement increased by 10 research octane numbers during this extended engine operating period. At approximately 24 hour intervals during these tests, the engine was audibly knock rated to determine its octane requirement. Cylinder pressure data was collected during knocking conditions to investigate the knocking characteristics of each cylinder, and deposit build-up effects on those statistics. Cylinder-to-cylinder variations in knock statistics were studied. Analysis of the data indicated that some 20 to 40 percent of cycles knock before the knock is audibly detected.

The flow into and out of the piston top-land crevice of a spark-ignition engine has been studied, using a square-cross-section single-cylinder engine with two parallel quartz glass walls which permit optical access to the entire cylinder volume. Schlieren short-time exposure photographs and high speed movies were used to define the essential features of this flow. The top-land crevice and the regions behind and between the rings consist of volumes connected through the ring gaps. A system model of volumes and orifices was therefore developed and used to predict the flow into and out of the crevice regions between the piston, piston rings and cylinder wall.

High levels of hydrocarbon emissions during light load operation keep the direct injection stratified charge engine from commercial application. Previous analytical work has identified several possible hydrocarbon emissions mechanisms which can result from poor in-cylinder fuel distribution. Poor fuel distribution can be caused by erratic fuel injection. Experiments conducted on a single cylinder DISC engine show a dramatic increase in the cycle to cycle variation in injection characteristics as engine load decreases. This is accompanied by an increase in cycle to cycle variation in combustion behavior suggesting that degradation in combustion results from the degradation in the quality of the injection event. Examination of combustion and injection characteristics on a cycle by cycle basis shows that, at light load, IMEP and heat release do not correlate with the amount of fuel injected into the cylinder.

An experimental study was performed to determine the fraction of unburned hydrocarbon emissions which are oxidized in the exhaust port of a spark ignition engine. The technique used was injection of a CO2 quench gas into the exhaust port, at various planes along the port centerline, to cool the exhaust gas and “freeze” the hydrocarbon oxidation reactions. By quenching the reaction of hydrocarbons at the cylinder exit plane, cylinder exit hydrocarbon emissions levels were determined. By differencing the concentration of hydrocarbons observed during quenching and nonquenching operation, the fraction of hydrocarbons reacting in each section of the exhaust was determined. Experiments were carried out to define the effects of engine operating conditions on the fraction of hydrocarbons oxidized. The variables studied were fuel-air equivalence ratio, speed, load, spark advance and compression ratio.

When hydrogen is added to a gasoline fueled spark ignition engine the lean limit of the engine can be extended. Lean running engines are inherently more efficient and have the potential for significantly lower NOx emissions. In the engine concept examined here, supplemental hydrogen is generated on-board the vehicle by diverting a fraction of the gasoline to a plasmatron where a partial oxidation reaction is initiated with an electrical discharge, producing a plasmatron gas containing primarily hydrogen, carbon monoxide, and nitrogen. Two different gas mixtures were used to simulate the plasmatron output. An ideal plasmatron gas (H2, CO, and N2) was used to represent the output of the theoretically best plasmatron. A typical plasmatron gas (H2, CO, N2, and CO2) was used to represent the current output of the plasmatron. A series of hydrogen addition experiments were also performed to quantify the impact of the non-hydrogen components in the plasmatron gas.

A method to collect and speciate the components of gasoline absorbed in the lubricant oil using gas chromatography has been developed. Samples were collected continuously from the piston skirt, baffle and sump in a Saturn engine. A long (18 hours) test was performed to determine the build up of hydrocarbons in the sump, and a shorter (25 min) test was performed to determine the build up of hydrocarbons in the piston skirt and baffle during engine warm-up. The first experiment showed that the total hydrocarbon concentration in the sump oil reached a steady state of about 1.35% mass fraction after 11 hours of engine operation. The relative concentration of individual fuel hydrocarbon species absorbed in the oil increases exponentially with boiling point. Most of the identified species in the oil consist of the heavy end aromatics. Similar compositions but lower concentrations were found for samples collected from the piston skirt during engine warm-up.

An experimental study was carried out that qualitatively examined the mixture preparation process in port fuel injected engines. The primary variables in this study were intake valve lift, intake valve timing, injector spray quality, and injection timing. A special visualization engine was used to obtain high-speed videos of the fuel-air mixture flowing through the intake valve, as well as the wetting of the intake valve and head in the combustion chamber. Additionally, videos were taken from within the intake port using a borescope to examine liquid fuel distribution in the port. Finally, a simulation study was carried out in order to understand how the various combinations of intake valve lifts and timings affect the flow velocity through the intake valve gap to aid in the interpretation of the videos.

The in-cylinder hydrocarbon (HC) mole fraction was measured on a cycle-resolved basis during simulated starting and warm-up of a port-injected single-cylinder SI research engine on a dynamometer. The measurements were made with a fast-response flame ionization detector with a heated sample line. The primary parameters that influence how rapidly a combustible mixture builds up in the cylinder are the inlet pressure and the amount of fuel injected; engine speed and fuel injection schedule have smaller effects. When a significant amount of liquid fuel is present at the intake port in the starting process, the first substantial firing cycle is often preceded by a cycle with abnormally high in-cylinder HC and low compression pressure. An energy balance analysis suggests that a large amount of liquid vaporization occurs within the cylinder in this cycle.