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A 2-D computational model was developed to describe the flow and filtration processes, in a honeycomb structured ceramic diesel particulate trap. This model describes the steady state trap loading, as well as the transient behavior of the flow and filtration processes. The theoretical model includes the effect of a copper fuel additive on trap loading and transient operation. The convective terms were based on a 2-D analytical flow field solution derived from the conservation of mass and momentum equations. The filtration theory incorporated in the time dependent numerical code included the diffusion, inertia, and direct interception mechanisms. Based on a measured upstream particle size distribution, using the filtration theory, the downstream particle size distribution was calculated. The theoretical filtration efficiency, based on particle size distribution, agreed very well (within 1%) with experimental data for a number of different cases.

A 2-D CFD model was developed to describe the heat transfer, and reaction kinetics in a honeycomb structured ceramic diesel particulate trap. This model describes the steady state as well as the transient behavior of the flow and heat transfer during the trap regeneration processes. The trap temperature profile was determined by numerically solving the 2-D unsteady energy equation including the convective, heat conduction and viscous dissipation terms. The convective terms were based on a 2-D analytical flow field solution derived from the conservation of mass and momentum equations (Opris, 1997). The reaction kinetics were described using a discretized first order Arrhenius function. The 2-D term describing the reaction kinetics and particulate matter conservation of mass was added to the energy equation as a source term in order to represent the particulate matter oxidation. The filtration model describes the particulate matter accumulation in the trap.

The prediction of particulate concentrations in dlesel exhaust diluted in a dilution tunnel has been achieved using a computer model. The particulate collection filter temperature, soluble organic fraction (SOF) and solids fraction (SOL) of diesel particulate matter were predicted based on exhaust system and dilution tunnel variables that could be measured on a real-time basis. The SOF was assumed to be formed by adsorption of gaseous hydrocarbons onto the solids fraction. The accuracy of the model was determined by comparison to experimentally measured values. The model was able to predict SOF concentrations within 35%, filter temperatures within 3°G, and particulate (SOF + SOL) concentrations within 25% of measured values. A parametric study was conducted using the developed model; and improved test procedures, dilution tunnel dimensions, and federal testing guidelines were suggested.

Studies have been conducted at Michigan Technological University (MTU) for over twenty years on methods for characterizing and controlling particulate emissions from heavy-duty diesel engines and the resulting effects on regulated and unregulated emissions. During that time, control technologies have developed in response to more stringent EPA standards for diesel emissions. This paper is a review of: 1) modern emission control technologies, 2) emissions sampling and chemical, physical and biological characterization methods and 3) summary results from recent studies conducted at MTU on heavy-duty diesel engines with a trap and an oxidation catalytic converter (OCC) operated on three different fuels. Control technology developments discussed are particulate traps, catalysts, advances in engine design, the application of exhaust gas recirculation (EGR), and modifications of fuel formulations.

An experimental and modeling study was conducted to study the passive regeneration of a catalyzed particulate filter (CPF) by the oxidation of particulate matter (PM) via thermal and Nitrogen dioxide/temperature-assisted means. Emissions data in the exhaust of a John Deere 6.8 liter, turbocharged and after-cooled engine with a low-pressure loop EGR and a diesel oxidation catalyst (DOC) - catalyzed particulate filter (CPF) in the exhaust system was measured and used for this study. A series of experiments was conducted to evaluate the performance of the DOC, CPF and DOC+CPF configurations at various engine speeds and loads.

The goals of this research are to understand the regeneration process in ceramic (Cordierite) monolith traps using a copper fuel additive and to investigate the various conditions that lead to trap regeneration failure. The copper additive lowers the trap regeneration temperature from approximately 500 °C to 375 °C and decreases the time necessary for regeneration. Because of these characteristics, it is important to understand the effect of the additive on regeneration when excessive particulate matter accumulation occurs in the trap. The effects of particulate mass loading on regeneration temperatures and regeneration time were studied for both the controlled (engine operated at full load rated speed) and uncontrolled (trap regeneration initiated at full load rated speed after which the engine was cut to idle) conditions. The trap peak temperatures were higher for the uncontrolled than the controlled regeneration.

Turbocharging, in addition to increasing an engine's power output, can be effectively used to maintain exhaust emission levels while improving fuel economy. This paper presents the emission and performance results obtained from a turbocharged multicylinder spark ignition engine with thermal reactors and exhaust gas recirculation (EGR) operated at steady-state, part-load conditions for four engine speeds. When comparing a turbocharged engine to a larger displacement naturally aspirated engine of equal power output, the emissions expressed in grams per mile were relatively unchanged both with and without EGR. However, turbocharging provided an average of 20% improvement in fuel economy both with and without EGR. When comparing the turbocharged and nonturbocharged versions of the same engine without EGR at a given load and speed, turbocharging increased the hydrocarbon (HC) and carbon monoxide (CO) emissions and decreased oxides of nitrogen (NOx) emissions.

Several sources of variation in quantitative analytical ferrography are investigated. A standard ferrography analysis procedure is developed. Normalization of ferrographic data to account for the amount of oil used to make the ferrograms is discussed. Procedures to minimize the errors involved with calculating three quantitative ferrography parameters: the area covered by the large particles, AL (%/ml of oil), the area covered by the small particles, AS (%/ml of oil) and Area Under the Curve, AUC, (%-mm/ml of oil) are outlined. Ferrographic data are presented which show that the volume and dilution ratio of the oil sample being analyzed have a major effect on the accuracy of the analysis. Several variables which influence the area covered readings of the particle deposit on a ferrogram are discussed. The accuracy of quantitative analytical ferrography is assessed.

Active regeneration experiments were carried out on a production 2007 Cummins 8.9L ISL engine and associated diesel oxidation catalyst (DOC) and catalyzed particulate filter (CPF) aftertreatment system. The effects of SME biodiesel blends were investigated to determine the particulate matter (PM) oxidation reaction rates for active regeneration. The experimental data from this study will also be used to calibrate the MTU-1D CPF model [1]. The experiments covered a range of CPF inlet temperatures using ULSD, B10, and B20 blends of biodiesel. The majority of the tests were performed at a CPF PM loading of 2.2 g/L with in-cylinder dosing, although 4.1 g/L and a post-turbo dosing injector were also investigated. The PM reaction rate was shown to increase with increasing percent biodiesel in the test fuel as well as increasing CPF temperature.

Active regeneration experiments were performed on a Cummins 2007 aftertreatment system by hydrocarbon dosing with injection of diesel fuel downstream of the turbocharger. The main objective was to characterize the thermal oxidation rate as a function of temperature and particulate matter (PM) loading of the catalyzed particulate filter (CPF). Partial regeneration tests were carried out to ensure measureable masses are retained in the CPF in order to model the oxidation kinetics. The CPF was subsequently re-loaded to determine the effects of partial regeneration during post-loading. A methodology for gathering particulate data for analysis and determination of thermal oxidation in a CPF system operating in the engine exhaust was developed. Durations of the active regeneration experiments were estimated using previous active regeneration work by Singh et al. 2006 [1] and were adjusted as the experiments progressed using a lumped oxidation model [2, 3].

An Andersen Impactor was used to collect particulate samples in both the undiluted and diluted exhaust from a Caterpillar 3150 diesel engine operated on the EPA 13-mode cycle. A total of 24 samples were examined using the transmission electron microscope and approximately 300 photomicrographs were taken. The microscope analysis and photomicrographs revealed details concerning the physical characteristics of the particulate and permitted a direct visual comparison of the samples collected. The photomicrographs were used to obtain diameter measurements of the basic individual spherical particles that comprise the much larger aggregates/agglomerates. Nearly 11,000 basic particles were measured and the observed range of diameters was 70-1200 Å. The mean particle diameters in the undiluted and diluted exhaust samples were 479 Å and 436 Å respectively. respectively. A respectively. 436 A respectively.

In 1972 and 1973, the CRC-APRAC Program Group on Diesel Exhaust carried out a fourth program to evaluate techniques for measuring concentration of hydrocarbon in diesel exhaust. The first two programs were conducted in 1967 and 1968. In them, a single cylinder diesel engine was shipped among 13 laboratories and each laboratory measured hydrocarbon emissions by their own method. Agreement among laboratories (instruments) was poor in both programs. The third program was conducted in 1970 at one laboratory on one engine. This time, agreement among instruments was much improved from the earlier programs. The fourth program was conducted to confirm these later results. In it, a multi-cylinder diesel generating set was circulated among 15 participating laboratories, and each laboratory measured exhaust hydrocarbon by methods that complied with SAE Recommended Practice J215, “Continuous Hydrocarbon Analysis of Diesel Exhaust.”

A 2007 Cummins ISL 8.9L direct-injection common rail diesel engine rated at 272 kW (365 hp) was used to load the filter to 2.2 g/L and passively oxidize particulate matter (PM) within a 2007 OEM aftertreatment system consisting of a diesel oxidation catalyst (DOC) and catalyzed particulate filter (CPF). Having a better understanding of the passive NO₂ oxidation kinetics of PM within the CPF allows for reducing the frequency of active regenerations (hydrocarbon injection) and the associated fuel penalties. Being able to model the passive oxidation of accumulated PM in the CPF is critical to creating accurate state estimation strategies. The MTU 1-D CPF model will be used to simulate data collected from this study to examine differences in the PM oxidation kinetics when soy methyl ester (SME) biodiesel is used as the source of fuel for the engine.

The effect of the use of a manganese-copper fuel additive with a Corning EX-47 particulate trap on heavy-duty diesel emissions has been investigated; reductions in total particulate matter (70%), sulfates (65%), and the soluble organic fraction (SOF) (62%) were measured in the diluted (15:1) exhaust and solids were reduced by 94% as measured in the raw exhaust. The use of the additive plus the trap had the same effect on gaseous emissions (hydrocarbons and oxides of nitrogen) as did the trap alone. The use of the additive without the trap had no effect on measured gaseous emissions, although sulfate increased by 20%. Approximately 50% of the metals added to the fuel were calculated to be retained in the engine system. The metals emitted by the engine were collected very efficiently (>97%) by the trap even during regeneration, which occured 180°C lower when the additive was used.

Protocols for sampling and analysis of particulate and gaseous-phase diesel emissions were developed to characterize the chemical and biological effects of using ceramic traps as particulate control devices. A stainless-steel sampler was designed, constructed, and tested with XAD-2 sorbent for the collection of volatile organic compounds (VOC). Raw exhaust levels of TPM and SOF and mutagenicity of the SOF and VOC were all reduced when the traps were used. Hydrocarbon mass balances indicated that some hydrocarbons were not collected by the sampling system and that the proportions of collected SOF and VOC were altered by the use of the traps. SOF hydrocarbons appeared to be derived mainly from engine lubricating oil; VOC hydrocarbons were apparently fuel-derived. There was no apparent effect on SOF mutagenicity due to either sampling time or reexposure of particulate to exhaust gases.

The CRC-APRAC CAPI-1-64 Odor Panel was formed in 1973 to assess an instrumental measurement system for diesel exhaust odor (DOAS) developed under CRC-APRAC CAPE-7-68 by Arthur D. Little, Inc. Four cooperative studies were conducted by nine participating laboratories using common samples. The objectives of these studies were to define the DOAS system variables and to validate and improve the sampling and collection procedures. A fifth study, serving as a review of each analysis step, showed that analysis of common derived odorant samples could be conducted within acceptable limits by the participating laboratories. Three in-house sampling system design and operating parameter studies were conducted simultaneously with the cooperative work. The combined findings from the in-house and cooperative studies led to a tentative recommended procedure for measuring diesel exhaust odor.

Methods available for measuring hydrocarbons in diesel exhaust were evaluated by the CRC-APRAC Program Group on Diesel Exhaust Composition during 1967-1970. Early tests showed distressingly large variations from instrument to instrument and undesirably large variations among repeated measurements by one instrument. Instrument quality and operator competence were better in later tests and agreement among instruments was relatively good and errors within instruments were small. Current techniques appear acceptable for engineering measurements. No further cooperative work is planned by CRC at present, but techniques for measuring hydrocarbons in diesel exhaust will be reappraised periodically.

This is the fourth in a series of tests conducted as a Coordinating Research Council cooperative program to evaluate the measurement methods used to analyze diesel exhaust gas constituents. A multi-cylinder engine was circulated to 15 participants who measured emissions at three engine conditions. All 15 participants measured nitric oxide and carbon monoxide with several laboratories measuring nitric oxide by both NDIR (Non-Dispersive Infrared) and CHEMI (Chemiluminescence). Some participants also measured carbon dioxide, nitrogen dioxide, oxygen, and unknown span gases. The test results are compared with the Phase III cooperative tests which involved simultaneous measurement of emissions by participants. The precision of the results was poorer in Phase IV than Phase III.

Active regeneration experiments were performed on a production diesel aftertreatment system containing a diesel oxidation catalyst and catalyzed particulate filter (CPF) using blends of soy-based biodiesel. The effects of biodiesel on particulate matter oxidation rates in the filter were explored. These experiments are a continuation of the work performed by Chilumukuru et al., in SAE Technical Paper No. 2009-01-1474, which studied the active regeneration characteristics of the same aftertreatment system using ultra-low sulfur diesel fuel. Experiments were conducted using a 10.8 L 2002 Cummins ISM heavy-duty diesel engine. Particulate matter loading of the filter was performed at the rated engine speed of 2100 rpm and 20% of the full engine load of 1120 Nm. At this engine speed and load the passive oxidation rate is low. The 17 L CPF was loaded to a particulate matter level of 2.2 g/L.

This paper reports the test results from the DPF (diesel particulate filter) portion of the DECSE (Diesel Emission Control - Sulfur Effects) Phase 1 test program. The DECSE program is a joint government and industry program to study the impact of diesel fuel sulfur level on aftertreatment devices. A systematic investigation was conducted to study the effects of diesel fuel sulfur level on (1) the emissions performance and (2) the regeneration behavior of a continuously regenerating diesel particulate filter and a catalyzed diesel particulate filter. The tests were conducted on a Caterpillar 3126 engine with nominal fuel sulfur levels of 3 parts per million (ppm), 30 ppm, 150 ppm and 350 ppm.