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Technical Paper

A Total Organic Carbon Analyzer for Space Potable Water Systems

1996-07-01
961570
A Total Organic Carbon (TOC) Analyzer has been developed for a Life Sciences Risk Mitigation Flight Experiment to be conducted on Spacehab and the Russian space station, Mir. Initial launch is scheduled for December 1996 (flight STS-81). The analyzer will be tested on the Orbiter in the Spacehab module, including when the Orbiter is docked at the Mir space station. The analyzer is scheduled to be launched again in May 1997 (STS-84) when it will be transferred to Mir. During both flights the analyzer will measure the quality of recycled and ground-supplied potable water on the space station. Samples will be archived for later return to the ground, where they will be analyzed for comparison to in-flight results. Water test samples of known composition, brought up with the analyzer, also will be used to test its performance in microgravity. Ground-based analyses of duplicates of those test samples will be conducted concurrently with the in-flight analyses.
Technical Paper

Characteristics of Post-Sorbent and High Temperature Catalytic Oxidizer Beds After Long-Term On-Orbit Use

2007-07-09
2007-01-3180
Trace contaminants are produced on-orbit by human metabolic processes and equipment off-gassing. These potentially hazardous contaminants are removed by the Trace Contaminant Control Subassembly (TCCS) in the US segment of the International Space Station (ISS). The TCCS has been operating since February 2001. Analysis of on-orbit telemetry data indicated a slow increase in the TCCS system flow resistance over the five years of operation. Two of the packed beds within the TCCS were replaced to return the TCCS to its nominal operation conditions: the high temperature catalytic oxidizer and the post-sorbent bed. Results from the examination of the returned beds are presented along with a discussion about changes to bed service life.
Journal Article

Chemical Analysis Results for Potable Water Returned from ISS Expeditions 14 and 15

2008-06-29
2008-01-2197
The Johnson Space Center Water and Food Analytical Laboratory (WAFAL) performed detailed ground-based analyses of archival water samples for verification of the chemical quality of the International Space Station (ISS) potable water supplies for Expeditions 14 and 15. During the 12-month duration of both expeditions, the Space Shuttle docked with the ISS on four occasions to continue construction and deliver additional crew and supplies; however, no Shuttle potable water was transferred to the station during Expedition 14. Russian ground-supplied potable water and potable water from regeneration of humidity condensate were both available onboard the ISS for consumption by the Expeditions 14 and 15 crews. A total of 16 chemical archival water samples were collected with U.S. hardware during Expeditions 14 and 15 and returned on Shuttle flights STS-116 (12A.1), STS-117 (13A), STS-118 (13A.1), and STS-120 (10A) in December 2006, and June, August, and November of 2007, respectively.
Technical Paper

Chemical Analysis and Water Recovery Testing of Shuttle-Mir Humidity Condensate

1999-07-12
1999-01-2029
Humidity condensate collected and processed in-flight is an important component of a space station drinking water supply. Water recovery systems in general are designed to handle finite concentrations of specific chemical components. Previous analyses of condensate derived from spacecraft and ground sources showed considerable variation in composition. Consequently, an investigation was conducted to collect condensate on the Shuttle while the vehicle was docked to Mir, and return the condensate to Earth for testing. This scenario emulates an early ISS configuration during a Shuttle docking, because the atmospheres intermix during docking and the condensate composition should reflect that. During the STS-89 and STS-91 flights, a total volume of 50 liters of condensate was collected and returned. Inorganic and organic chemical analyses were performed on aliquots of the fluid.
Technical Paper

Chemical Analysis of ISS Potable Water From Expeditions 8 and 9

2005-07-11
2005-01-2885
With the Shuttle fleet grounded, limited capability exists to resupply in-flight water quality monitoring hardware onboard the International Space Station (ISS). As such, verification of the chemical quality of the potable water supplies on ISS has depended entirely upon the collection, return, and ground-analysis of archival water samples. Despite the loss of Shuttle-transferred water as a water source, the two-man crews during Expedition 8 and Expedition 9 maintained station operations for nearly a year relying solely on the two remaining sources of potable water; reclaimed humidity condensate and Russian-launched ground water. Archival potable water samples were only collected every 3 to 4 months from the systems that regenerate water from condensate (SRV-K) and distribute stored potable water (SVO-ZV).
Technical Paper

Colorimetric-Solid Phase Extraction (C-SPE): In-Flight Methodologies for the Facile Determination of Trace Level Indicators of Water Quality

2008-06-29
2008-01-2201
At present, spacecraft water quality is assessed when samples collected on the International Space Station (ISS) are returned to Earth. Several months, however, may pass between sample collection and analysis, potentially compromising sample integrity by risking degradation. For example, iodine and silver, which are the respective biocides used in the U.S. and Russian spacecraft potable water systems, must be held at levels that prevent bacterial growth, while avoiding adverse effects on crew health. A comparable need exists for the detection of many heavy metals, toxic organic compounds, and microorganisms. Lead, cadmium, and nickel have been found, for instance, in the ISS potable water system at amounts that surpass existent requirements. There have been similar occurrences with hazardous organic compounds like formaldehyde and ethylene glycol. Microorganism counts above acceptable limits have also been reported in a few instances.
Technical Paper

Colorimetric-Solid Phase Extraction Technology for Water Quality Monitoring: Evaluation of C-SPE and Debubbling Methods in Microgravity

2007-07-09
2007-01-3217
Colorimetric-solid phase extraction (C-SPE) is being developed as a method for in-flight monitoring of spacecraft water quality. C-SPE is based on measuring the change in the diffuse reflectance spectrum of indicator disks following exposure to a water sample. Previous microgravity testing has shown that air bubbles suspended in water samples can cause uncertainty in the volume of liquid passed through the disks, leading to errors in the determination of water quality parameter concentrations. We report here the results of a recent series of C-9 microgravity experiments designed to evaluate manual manipulation as a means to collect bubble-free water samples of specified volumes from water sample bags containing up to 47% air. The effectiveness of manual manipulation was verified by comparing the results from C-SPE analyses of silver(I) and iodine performed in-flight using samples collected and debubbled in microgravity to those performed on-ground using bubble-free samples.
Technical Paper

Determination of On-Orbit Cabin Air Loss from the International Space Station (ISS)

2004-07-19
2004-01-2597
The International Space Station (ISS) loses cabin atmosphere mass at some rate. Due to oxygen partial pressures fluctuations from metabolic usage, the total pressure is not a good data source for tracking total pressure loss. Using the nitrogen partial pressure is a good data source to determine the total on-orbit cabin atmosphere loss from the ISS, due to no nitrogen addition or losses. There are several important reasons to know the daily average cabin air loss of the ISS including logistics planning for nitrogen and oxygen. The total average daily cabin atmosphere loss was estimated from January 14 to April 9 of 2003. The total average daily cabin atmosphere loss includes structural leakages, Vozdukh losses, Carbon Dioxide Removal Assembly (CDRA) losses, and other component losses.
Technical Paper

Expanded Capabilities of the Extended Duration Orbiter

1990-07-01
901290
The Space Shuttle Program has recently embarked on a program which will lengthen the on-orbit stay time of the Space Shuttle. In its current configuration, the orbiter is limited to a maximum of 10 days by Environmental Control and Life Support System (ECLSS) consumables, stowage constraints, and the fuel cell reactants. The capabilities of the Extended Duration Orbiter (EDO) will permit longer duration Spacelab, Spacehab, and Commercially Developed Space Facility (CDSF) missions. Additionally, the EDO may be required for Space Station Freedom assembly operations in the late 1990's. Of the National Aeronautics and Space Administration's (NASA) fleet, both Columbia (OV-102) and Endeavour (OV-105) will be modified to accomplish extended missions of up to 16 days. As a logical follow-on, NASA is currently pursuing approval of a 28-day Extended Duration Orbiter program.
Technical Paper

Further Characterization and Multifiltration Treatment of Shuttle Humidity Condensate

1995-07-01
951685
On the International Space Station (ISS), humidity condensate will be collected from the atmosphere and treated by multifiltration to produce potable water for use by the crews. Ground-based development tests have demonstrated that multifiltration beds filled with a series of ion-exchange resins and activated carbons can remove many inorganic and organic contaminants effectively from wastewaters. As a precursor to the use of this technology on the ISS, a demonstration of multifiltration treatment under microgravity conditions was undertaken. On the Space Shuttle, humidity condensate from cabin air is recovered in the atmosphere revitalization system, then stored and periodically vented to space vacuum. A Shuttle Condensate Adsorption Device (SCAD) containing sorbent materials similar to those planned for use on the ISS was developed and flown on STS-68 as a continuation of DSO 317, which was flown initially on STS-45 and STS-47.
Technical Paper

Humidity Condensate Sampling System for Shuttle, Mir and International Space Station

1998-07-13
981764
Archival sampling of potable water and condensate for ground laboratory analysis has been an important part of the Shuttle-Mir program because of coolant leaks and other events on Mir that have affected water quality. We report here the development of and preliminary results from a novel device for single phase humidity condensate collection at system pressures. The sampler consists of a commercial-off-the-shelf Teflon® bladder and a custom reinforced Nomex® restraint that is sized properly to absorb the stress of applied pressures. A plastic Luer-Lock disconnect, with poppet actuated by a mating Luer-Lock fitting, prevents the contents from being spilled during transport. In principle, a sampler of any volume can be designed. The empty mass of the reusable one-liter sampler is only 63 grams. Several designs were pressure tested and found to withstand more than 3 atmospheres well in excess of typical spacecraft water or wastewater system pressures.
Technical Paper

ISS Expeditions 10 & 11 Potable Water Sampling and Chemical Analysis Results

2006-07-17
2006-01-2015
During the twelve month period comprising Expeditions 10 and 11, the chemical quality of the potable water onboard the International Space Station (ISS) was verified through the return and ground analysis of water samples. The two-man Expedition 10 crew relied solely on Russian-provided ground water and reclaimed cabin humidity condensate as their sources of potable water. Collection of archival water samples with U.S. hardware has remained extremely restricted since the Columbia tragedy because of very limited return volume on Russian Soyuz vehicles. As a result only two such samples were collected during Expedition 10 and returned on Soyuz 9. The average return sample volume was only 250 milliliters, which limited the breadth of chemical analysis that could be performed. Despite the Space Shuttle vehicle returning to flight in July 2005, only two potable water samples were collected with U.S. hardware during Expedition 11 and returned on Shuttle flight STS-114 (LF1).
Technical Paper

ISS Potable Water Sampling and Chemical Analysis: Expeditions 6 & 7

2004-07-19
2004-01-2537
Ever since the first crew arrived at the International Space Station (ISS), archival potable water samples have been collected and returned to the ground for detailed chemical analysis in order to verify that the water supplies onboard are suitable for crew consumption. The Columbia tragedy, unfortunately, has had a dramatic impact on continued ISS operations. A major portion of the ISS water supply had previously consisted of Shuttle-transferred water. The other two remaining sources of potable water, i.e., reclaimed humidity condensate and Russian-launched ground water, are together insufficient to maintain 3-person crews. The Expedition 7 crew launched in April of 2003 was, therefore, reduced from three to two persons. Without the Shuttle, resupply of ISS crews and supplies is dependent entirely on Russian launch vehicles (Soyuz and Progress) with severely limited up and down mass.
Technical Paper

ISS Total Organic Carbon Analyzer - 2002 Status

2002-07-15
2002-01-2533
Potable water supplies onboard the International Space Station (ISS) include both reclaimed water from treatment of atmospheric humidity condensate and stored water that is either Shuttle-transferred or ground-supplied. Space station medical operations requirements call for real-time monitoring of key water quality parameters, such as total organic carbon, total inorganic carbon, total carbon, pH, and conductivity, to ensure that crew health is protected from unsafe drinking water. A Total Organic Carbon Analyzer (TOCA) designed to meet these requirements was developed as part of the Crew Health Care System and launched to the ISS in April of 2001. The initial design of the ISS TOCA was previously presented at this conference in 1998. The current design of the instrument includes an improved reagent system and upgraded software to enhance accuracy through the capability to measure organic contamination of the reagents and correct analytical results.
Technical Paper

ISS Total Organic Carbon Analyzer Status Update - 2003

2003-07-07
2003-01-2403
The Crew Health Care System (CHeCS) is responsible for providing environmental monitoring to protect crew health, including in-flight chemical water quality analysis. To meet this objective, Total Organic Carbon Analyzer (TOCA) Serial Number (SN) 1002 was launched to the International Space Station (ISS) in April of 2001 as part of the CHeCS hardware. Since that time it has been used to evaluate the quality of the potable water supplies consisting of reprocessed atmospheric condensate water, Shuttle-transferred water, and ground-supplied water. Potable water is available for crew use from the Service Module System for Regeneration of Water from Condensate (SRV-K) galley hot and warm ports and the Stored Potable Water System (SVO-ZV) port. Potable water samples are periodically collected from each of these ports for in-flight analysis with the TOCA.
Technical Paper

International Space Station (ISS) Airlock Crewlock Depressurization Methods

2004-07-19
2004-01-2594
The International Space Station (ISS) Airlock Crewlock can be depressurized via various methods. The ISS Airlock is divided into two major sections, the Equipment Lock and Crewlock. The Equipment Lock, as the name indicates, contains the equipment to support EVA activities including Extravehicular Maneuvering/Mobility Unit (EMU) maintenance and refurbishment. The Equipment Lock also contains basic life support equipment in order to support denitrogenzation protocols while the Airlock is isolated from the rest of the ISS. The Crewlock is the section of the Airlock that is depressurized to allow for Extravehicular Activity (EVA) crewmembers to exit the ISS for performance of EVAs. As opposed to the Equipment Lock, the Crewlock is quite simple and basically just contains lights and an assembly to provide services, oxygen, coolant, etc, to the EMUs. For operational flexibility, various methods were derived for Crewlock depressurization.
Technical Paper

International Space Station (ISS) Carbon Dioxide Removal Assembly (CDRA) Desiccant/Adsorbent Bed (DAB) Orbital Replacement Unit (ORU) Redesign

2007-07-09
2007-01-3181
The Carbon Dioxide Removal Assembly (CDRA) is a part of the International Space Station (ISS) Environmental Control and Life Support (ECLS) system. The CDRA provides carbon dioxide (CO2) removal from the ISS on-orbit modules. Currently, the CDRA is the secondary removal system on the ISS, with the primary system being the Russian Vozdukh. Within the CDRA are two Desiccant/Adsorbent Beds (DAB), which perform the carbon dioxide removal function. The DAB adsorbent containment approach required improvements with respect to adsorbent containment. These improvements were implemented through a redesign program and have been implemented on units on the ground and returning from orbit. This paper presents a DAB design modification implementation description, a hardware performance comparison between the unmodified and modified DAB configurations, and a description of the modified DAB hardware implementation into the on-orbit CDRA.
Technical Paper

International Space Station (ISS) Environmental Control and Life Support (ECLS) System Overview of Events: February 2006 - 2007

2007-07-09
2007-01-3099
The International Space Station (ISS) continues to mature and operate its life support equipment. Major events occurring between February 2006 and February 2007 are discussed in this paper, as are updates from previously ongoing hardware anomalies. This paper addresses the major ISS operation events over the last year. Impact to overall ISS operations is also discussed.
Technical Paper

International Space Station (ISS) Environmental Control and Life Support (ECLS) System Overview of Events: February 2007-2008

2008-06-29
2008-01-2132
The International Space Station (ISS) continues to mature and operate its life support equipment. Major events occurring between February 2007 and February 2008 are discussed in this paper, as are updates from previously ongoing hardware anomalies. This paper addresses the major ISS operation events over the last year. Impact to overall ISS operations is also discussed.
Technical Paper

International Space Station (ISS) Environmental Control and Life Support (ECLS) System Overview of Events:February 2005 - 2006

2006-07-17
2006-01-2056
The International Space Station (ISS) continues to mature and operate its life support equipment. Major events occurring between February 2005 and February 2006 are discussed in this paper, as are updates from previously ongoing hardware anomalies. This paper addresses the major ISS operation events over the last year. Impact to overall ISS operations is also discussed.
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