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Previous work of the authors' group has shown that biodiesel fuels as a replacement for conventional diesel fuel in engine combustion can reduce PM level dramatically while lowering some other regulated emissions as well. It has shown that these fuels have the potential to increase the overall engine performance due to their lower sulphur and/or aromatics content compared with standard diesel fuels. This paper presents a study on a single cylinder naturally aspirated direct injection (DI) diesel engine, equipped with a pump-line-nozzle injection system, operating with varied biodiesel fuel blends (0%, 25%, and 50% of RME by volume) with ultra low sulphur diesel fuel (ULSD). The detailed analysis of the measurement data shows that the ignition delay and exhaust emissions are affected by the proportion of biodiesel due to the effect of different physical and chemical properties of the two fuels.

The major characteristics of the combustion in Homogeneous Charge Compression Ignition (HCCI) engines, irrespective of the technological strategy used to enable the ‘controlled auto-ignition’, are that the mixture of fuel and air is preferably premixed and largely homogeneous. Ignition tends to take place simultaneously at multiple points and there is no bulk flame propagation as in conventional spark-ignition (SI) engines. This paper presents an experimental study of flame development in an optical engine operating in HCCI combustion mode. High resolution and high-speed charge coupled device (CCD) cameras were used to take images of the flame during the combustion process. Fuels include gasoline, natural gas (NG) and hydrogen addition to NG all at stoichiometric conditions, permitting the investigation of combustion development for each fuel. The flame imaging data was supplemented by simultaneously recorded in-cylinder pressure data.

There is an increasing recognition of injector deposit (ID) formation in fuel injection equipment as direct injection spark ignition (DISI) engine technologies advance to meet increasingly stringent emission legislation and fuel economy requirements. While it is known that the phenomena of ID in DISI engines can be influenced by changes in fuel composition, including increasing usage of aliphatic alcohols and additive chemistries to enhance fuel performance, there is however still a great deal of uncertainty regarding the physical and chemical structure of these deposits, and the mechanisms of deposit formation. In this study, a mechanical cracking sample preparation technique was developed to assess the deposits across DISI injectors fuelled with gasoline and blends of 85% ethanol (E85).

The new fuel, 2, 5-dimenthylfuran, known as DMF, captured worldwide attention since the discovery of its new production method. As a potential bio-fuel, DMF is competitive to gasoline in many areas, such as energy density, combustion efficiency and emissions. However, little work has been performed on its unconventional combustion mode. In this work, high speed imaging and thermal investigation are carried out to study DMF and gasoline dual-injection on a single cylinder, direct injection spark ignition optical engine. This dual-injection strategy combines direct injection (DI) and port fuel injection (PFI) simultaneously which means two different fuels can blend in the cylinder with any ratio. It provides a flexible way to use bio-fuels with gasoline. DMF DI with gasoline PFI and ethanol DI with gasoline PFI are studied under different injection proportions (by volume) and IMEPs.

The application of Homogeneous Charge Compression Ignition (HCCI) combustion to naturally aspirated engines has shown a much reduced usable load range as compared to spark ignition (SI) engines. The approach documented here applies inlet charge boosting to gasoline HCCI operation on an engine configuration that is typical for SI gasoline engines, in conjunction with residual gas trapping. The latter helps to retain the benefits of much reduced requirement for external heating. In the present work, the achievable engine load range is controlled by the level of boost pressure while varying the amount of trapped residual gas. In addition, it was found that there is a maximum amount of boost that can be applied without intake heating for any given amount of trapped residuals. NOx emissions decrease with increasing amounts of trapped residual.

In this research, propane flash boiling sprays discharged from a five-hole gasoline direct injector were studied in a constant volume vessel. The fuel temperature (Tfuel) ranged from 30 °C to 90 °C, and the ambient pressure (Pamb) varied from 0.05 bar to 11.0 bar. Different flash boiling spray behavior compared to that under sub-atmospheric conditions was found at high Pamb. Specifically, at the sub-atmospheric pressures, the individual flashing jets merged into one single jet due to the strong spray collapse. In contrast, at Pamb above 3.0 bar and Tfuel above 50 °C, the spray collapse was mitigated and the flashing jets were separated from each other. Further analyses revealed that the mitigation of spray collapse at high Pamb was ascribed to the suppression of jet expansion. In addition, it was found that the spray structure was much different at similar Rp, indicating that Rp lacked the generality in describing the structure of flash boiling sprays.

For spark ignition (SI) engines, the optimum spark timing is crucial for maximum efficiency. However, as the spark timing is advanced, so the propensity to knock increases, thus compromising efficiency. One method to suppress knock is to use high octane fuel additives. However, the blend ratio of these additives cannot be varied on demand. Therefore, with the advent of aggressive downsizing, new knock mitigation techniques are required. Fortuitously, there are two well-known lower alcohols which exhibit attractive knock mitigation properties: ethanol and methanol. Both not only have high octane ratings, but also result in greater charge-cooling than with gasoline. In the current work, the authors have exploited these attractive properties with the dual-injection, or the dual-fuel concept (gasoline in PFI and fuel additive in DI) using pure ethanol and methanol.

Natural gas has a high auto-ignition temperature, requiring high compression ratios and/or intake charge heating to achieve HCCI (homogeneous charge compression ignition) engine operation. Previous work by the authors has shown that hydrogen addition improves combustion stability in various difficult combustion conditions. It is shown here that hydrogen, together with residual gas trapping, helps also in lowering the intake temperature required for HCCI. It has been argued in literature that the addition of hydrogen advances the start of combustion in the cylinder. This would translate into the lowering of the minimum intake temperature required for auto-ignition to occur during the compression stroke. The experimental results of this work show that, with hydrogen replacing part of the fuel, a decrease in intake air temperature requirement is observed for a range of engine loads, with larger reductions in temperature noted at lower loads.

With boosted HCCI operation on gasoline using residual gas trapping, the amount of residuals was found to be of importance in determining the boundaries of stable combustion at various boost pressures. This paper represents a development of this approach by concentrating on the effects of inlet valve events on the parameters of boosted HCCI combustion with residual gas trapping. It was found that an optimum inlet valve timing could be found in order to minimize NOx emissions. When the valve timing is significantly advanced or retarded away from this optimum, NOx emissions increase due to the richer air / fuel ratios required for stable combustion. These richer conditions are necessary as a result of either the trapped residual gases becoming cooled in early backflow or because of lowering of the effective compression ratio. The paper also examines the feasibility of using inlet valve timing as a method of controlling the combustion phasing for boosted HCCI with residual gas trapping.

Biodiesel is an oxygenated alternative fuel made from vegetable oils and animal fats via transesterification and the feedstock of biodiesel is diverse and varies between the local agriculture and market scenarios. Use of various feedstock for biodiesel production result in variations in the fuel properties of biodiesel. In this study, biodiesels produced from a variety of real world feedstock was examined to assess the performance and emissions in a light-duty engine. The objective was to understand the impact of biodiesel properties on engine performances and emissions. A group of six biodiesels produced from the most common feedstock blended with zero-sulphur diesel in 10%, 30% and 60% by volume are selected for the study. All the biodiesel blends were tested on a light-duty, twin-turbocharged common rail V6 engine. Their gaseous emissions (NOx, THC, CO and CO2) and smoke number were measured for the study.

Ethanol has long been regarded as the optimal gasoline-alternative biofuel for spark-ignition (SI) engines. It is used widely in Latin and North America and is increasingly accepted as an attractive option across Europe. Nevertheless, its low energy density requires a high rate of manufacture; in areas which are deficient of arable land, such rates might prove problematic. Therefore, fuels with higher calorific values, such as butanol or 2,5-dimethylfuran (DMF) deserve consideration; a similar yield to ethanol, in theory, would require much less land. This report addresses the suitability of DMF, to meet the needs as a biofuel substitute for gasoline in SI engines, using ethanol as the biofuel benchmark. Specific attention is given to the sensitivity of DMF to various engine control parameters: combustion phasing (ignition timing), injection timing, relative air-fuel ratio and valve timing (intake and exhaust).

Ethanol fuel blends with gasoline for spark ignition (SI) internal combustion engines are widely used on account of their advantages in terms of fuel economy and emissions reduction potential. The focus of this paper is to study the effects of these blends on combustion characteristics such as in-cylinder pressure profiles, gas-phase emissions (e.g., unburned hydrocarbons, NOx) and particulates (e.g., particulate matter and particle number) using both measurement campaigns and digital engineering workflows. Nineteen load-speed operating points in a 1L 3-cylinder GDI SI engine were measured and modelled. The measurements for in-cylinder pressure and emissions were repeated at each operating point for three types of fuel: gasoline (E0, 0% by volume of ethanol blend), E10 (10 % by volume of ethanol blend) and E20 (20% by volume of ethanol blend).

This paper presents the findings of theoretical and practical studies of an exhaust-gas reforming process, as applied to hydrocarbon fuels. It is shown that hydrogen-containing gaseous reformed fuels can be produced by the interaction of hot combustion products and an n-heptane feedstock in a small-scale catalytic reforming reactor. Predicted and observed reformed fuel chemical compositions were found to correlate well at the lower reactor space velocities tested, where chemical equilibrium conditions can be closely approached. Under these conditions, respective hydrogen and carbon monoxide yields of around 32 and 20 volume per cent were obtained. Under certain conditions, it was found that carbon solids were deposited on the reforming catalyst. Measures taken to avoid this problem included changes in the reforming oxidant to fuel ratio, and the addition of excess steam to the oxidant composition.

Gasoline and diesel, the two fuels with very different characteristics and with wide availability for conventional engine use, were blended as a HCCI engine fuel. Gasoline, with high volatility, easy vaporization and mixture formation, is used to form the homogeneous charge. Diesel fuel which has good ignitability and fast combustion at the conditions predominating in the HCCI environment, is used to dominate the auto-ignition and restrain the knocking combustion. It is expected that these two different fuels with opposite but complementary properties can be used to reach a good compromise in HCCI combustion. Experiments, conducted with moderate compression ratios (CR) and using two modes of HCCI control, i.e. intake heating with CR 15.0 and negative valve overlap (NVO) with CR 10.4, yielded results that prove this expectation.

Combustion behaviour and emissions characteristics of different blending ratios of diesel and gasoline fuels (Dieseline) were investigated in a light-duty 4-cylinder compression-ignition (CI) engine operating on partially premixed compression ignition (PPCI) mode. Experiments show that increasing volatility and reducing cetane number of fuels can help promote PPCI and consequently reduce particulate matter (PM) emissions while oxides of nitrogen (NOx) emissions reduction depends on the engine load. Three different blends, 0% (G0), 20% (G20) and 50% (G50) of gasoline mixed with diesel by volume, were studied and results were compared to the diesel-baseline with the same combustion phasing for all experiments. Engine speed was fixed at 1800rpm, while the engine load was varied from 1.38 to 7.85 bar BMEP with the exhaust gas recirculation (EGR) application.

Injection pressure oscillations are proven to determine considerable deviations from the expected mass flow rate, leading to the jet velocities non-uniformity, which in turn implies the uneven spatial distribution of A/F ratio. Furthermore, once the injector is triggered, these oscillations might lead the rail pressure to experience a decreasing stage, to the detriment of spray penetration length, radial propagation and jet break-up timing. This has urged the research community to develop models predicting injection-induced pressure fluctuations within the rail. Additionally, several devices have been designed to minimize and eliminate such fluctuations. However, despite the wide literature dealing with the injection-induced pressure oscillations, many aspects remain still unclear. Moreover, the compulsory compliance with environmental regulations has shifted focus onto alternative fuels, which represent a promising pathway for sustainable vehicle mobility.

It is known that the levels of hydrocarbon (HC) emissions from Homogeneous Charge Compression Ignition (HCCI) engines are relatively higher than that of Spark-Ignition (SI) engines because of the lower combustion temperature. In order to improve understanding of the mechanisms and products of HCCI combustion in comparison with SI combustion, a quantitative analysis of individual hydrocarbons in the C1 - C6 range emitted in the exhaust gases of gasoline direct injection V6 engine operating in SI and HCCI modes with cam profile switching has been carried out using gas chromatography - mass spectrometry (GCMS) apparatus attached on-line to engine exhaust. In this study, with a GC run time of 20 minutes all aliphatic and olefinic hydrocarbon species in the range C1 to C6 are resolved.

Dieseline combustion as a concept combines the advantages of gasoline and diesel by offline or online blending the two fuels. Dieseline has become an attractive new compression ignition combustion concept in recent years and furthermore an approach to a full-boiling-range fuel. High speed imaging with near-parallel backlit light was used to investigate the spray characteristics of dieseline and pure fuels with a common rail diesel injection system in a constant volume vessel. The results were acquired at different blend ratios, and at different temperatures and back pressures at an injection pressure of 100MPa. The penetrations and the evaporation states were compared with those of gasoline and diesel. The spray profile was analyzed in both area and shape with statistical methods. The effect of gasoline percentage on the evaporation in the fuel spray was evaluated.

In the present work, the partial oxidation of diesel (US07), rapeseed methyl ester (RME) and low temperature Fischer - Tropsch synthetic diesel (SD), almost 100% paraffinic, was investigated for the purpose of hydrogen and intermediate hydrocarbon species production over a prototype reforming catalyst, for the potential use in hydrocarbon selective catalytic reduction (HC-SCR) of nitrogen oxide (NOx) emissions from diesel engines. The presence of small amounts of hydrogen can substantially improve the effectiveness of hydrocarbons in the selective reduction of NOx over lean NOx catalysts, particularly at low temperatures (150-350°C). In this study, the partial oxidation reactor was operating at the same input power (kW), based on the calorific values of the fed fuel. Hydrogen production was as high as 19%, from the partial oxidation of SD fuel, and dropped to 17% and 14% for RME and US07 diesel, respectively.

Research studies show that 2-methylfuran (MF) is a promising gasoline alternative regarding its positive effect on engine performance and emissions. Before using pure MF in spark ignition engines, it is more likely to be used in a low-level blended form in gasoline. An experimental research study was carried out to investigate the impacts of low-level MF content in gasoline (volumetric 10% MF in blend) on direct-injection spark-ignition (DISI) engine combustion behavior and emissions. The tests were conducted on a single-cylinder spray-guided DISI research engine at an engine speed of 1500 rpm under stoichiometric conditions. The engine loads of 3.5 ~ 8.5 bar IMEP were tested and gasoline-optimized spark timing was used. Furthermore, the effects of spark timing, exhaust gas recirculation (EGR) and valve overlap on NOx emissions were tested.