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A commercially available fuel, E85, a blend of ~85% ethanol and ~15% gasoline, can be a viable substitute for fossil fuels in internal combustion engines in order to achieve a reduction of the greenhouse gas (GHG) emissions. Ethanol is traditionally made of biomass, which makes it a part of the food-feed-fuel competition. New processes that reuse waste products from other industries have recently been developed, making ethanol a renewable and sustainable second-generation fuel. So far, work on E85 has focused on spark ignition (SI) concepts due to high octane rating of this fuel. There is very little research on its application in CI engines. Alcohols are known for low soot particle emissions, which gives them an advantage in the NOx-soot trade-off of the compression ignition (CI) concept.

Fuel effects on ignition delay and low temperature reactions (LTR) during partially premixed combustion (PPC) were analyzed using Design of Experiments (DoE). The test matrix included seventeen mixtures of n-heptane, isooctane, toluene and ethanol covering a broad range of ignition quality and fuel chemistry. Experiments were performed on a light-duty diesel engine at 8 bar IMEPg, 1500 rpm with a variation in combustion phasing, inlet oxygen concentration and injection pressure. A single injection strategy was used and the start of injection and injection duration were adjusted to achieve the desired load and combustion phasing. The experimental data show that fuels with higher Research Octane Number (RON) values generally produced longer ignition delays. In addition, the alcohol content had significantly stronger effect on ignition delay than the aromatic content.

Partially Premixed Combustion, PPC, with 50% Exhaust Gas Recirculation (EGR) at lean combustion conditions λ =1.5, has shown good efficiency and low emissions in a heavy-duty single-cylinder engine. To meet emission requirements in all loads and transient operation, aftertreatment devices are likely needed. Reducing λ to unity, when a three-way catalyst can be applied, extremely low emissions possibility exists for stoichiometric PPC. In this study, the possibility to operate clean PPC from lean condition to stoichiometric equivalence ratio with reasonable efficiency and non-excessive soot emission was investigated. Two EGR rates, 48% and 38% with two fuel rates were determined for 99.5 vol% ethanol in comparison with one gasoline fuel and Swedish diesel fuel (MK1). Engine was operated at 1250 rpm and 1600 bar injection pressure with single injection. Results revealed that efficiency was reduced and soot emission increased from lean PPC to stoichiometric PPC operation.

The current research focus on fuel effects on low temperature reactions (LTR) in Homogeneous Charge Compression Ignition (HCCI) and Partially Premixed Combustion (PPC). LTR result in a first stage of heat release with decreasing reaction rate at increasing temperature. This makes LTR important for the onset of the main combustion. However, auto-ignition is also affected by other parameters and all fuel does not exhibit LTR. Moreover, the LTR does not only depend on fuel type but also on engine conditions. This research aims to understand how fuel composition affects LTR in each type of combustion mode and to determine the relative importance of chemical and physical fuel properties for PPC. For HCCI the chemical properties are expected to dominate over physical properties, since vaporization and mixing are completed far before start of combustion.

This study examines fuel auto-ignitability and shows a method for determining fuel performance for HCCI combustion by doing engine experiments. Previous methods proposed for characterizing HCCI fuel performance were assessed in this study and found not able to predict required compression ratio for HCCI auto-ignition (CRAI) at a set combustion phasing. The previous indices that were studied were the Octane Index (OI), developed by Kalghatgi, and the HCCI Index, developed by Shibata and Urushihara. Fuels with the same OI or HCCI Index were seen to correspond to a wide range of compression ratios in these experiments, so a new way to describe HCCI fuel performance was sought. The Lund-Chevron HCCI Number was developed, using fuel testing in a CFR engine just as for the indices for spark ignition (research octane number and motor octane number, RON and MON) and compression ignition (cetane number, CN).

HCCI combustion can be enabled by many types of liquid and gaseous fuels. When considering what fuels will be most suitable, the emissions also have to be taken into account. This study focuses on the emissions formation originating from different fuel components. A systematic study of over 40 different gasoline surrogate fuels was made. All fuels were studied in a CFR engine running in HCCI operation. Many of the fuels were blended to achieve similar RON's and MON's as gasoline fuels, and the components (n-heptane, iso-octane, toluene, and ethanol) were chosen to represent the most important in gasoline; nparaffins, iso-paraffins, aromatics and oxygenates. The inlet air temperature was varied from 50°C to 150°C to study the effects on the emissions. The compression ratio was adjusted for each operating point to achieve combustion 3 degrees after TDC. The engine was run at an engine speed of 600 rpm, with ambient intake air pressure and with an equivalence ratio of 0.33.

The focus has recently been directed towards the engine out soot from Diesel engines. Running an engine in PPC (Partially Premixed Combustion) mode has a proven tendency of reducing these emissions significantly. In addition to combustion strategy, several studies have suggested that using alcohol fuels aid in reducing soot emissions to ultra-low levels. This study analyzes and compares the characteristics of PM emissions from naphtha gasoline PPC, ethanol PPC, methanol PPC and methanol diffusion combustion in terms of soot mass concentration, number concentration and particle size distribution in a single cylinder Scania D13 engine, while varying the intake O2. Intake temperature and injection pressure sweeps were also conducted. The fuels emitting the highest mass concentration of particles (Micro Soot Sensor) were gasoline and methanol followed by ethanol. The two alcohols tested emitted nucleation mode particles only, whereas gasoline emitted accumulation mode particles as well.

Partially premixed combustion (PPC) is intended to improve fuel efficiency and minimize the engine-out emissions. PPC is known to have the potential to reduce emissions of nitrogen oxides (NOx) and soot, but often at the expense of increased emissions of unburned hydrocarbons (HC) and carbon monoxide (CO). PPC has demonstrated remarkable fuel flexibility and can be operated with a large variety of liquid fuels, ranging from low-octane, high-cetane diesel fuels to high-octane gasolines and alcohols. Several research groups have demonstrated that naphtha fuels provide a beneficial compromise between functional load range and low emissions. To increase the understanding of the influence of individual fuel components typically found in commercial fuels, such as alkenes, aromatics and alcohols, a systematic experimental study of 15 surrogate fuel mixtures of n-heptane, isooctane, toluene and ethanol was performed in a light-duty PPC engine using a design of experiment methodology.

An index to relate fuel properties to HCCI auto-ignition would be valuable to predict the performance of fuels in HCCI engines from their properties and composition. The indices for SI engines, the Research Octane Number (RON) and Motor Octane Number (MON) are known to be insufficient to explain the behavior of oxygenated fuels in an HCCI engine. One way to characterize a fuel is to use the Auto-Ignition Temperature (AIT). The AIT can be extracted from the pressure trace. Another potentially interesting parameter is the amount of Low Temperature Heat Release (LTHR) that is closely connected to the ignition properties of the fuel. A systematic study of fuels consisting of gasoline surrogate components of n-heptane, iso-octane, toluene, and ethanol was made. 21 fuels were prepared with RON values ranging from 67 to 97.

Alternative fuels have been proposed as a means for future energy-secure and environmentally sustainable transportation. This review and benchmarking show that several of the alternative fuels (e.g. methanol, ethanol, higher alcohols, RME, HVO, DME, and biogas/CNG) work well with several different engine concepts such as conventional SI, DICI, and dual fuel, and with the emerging concepts HCCI, RCCI, and PPC. Energy consumption is in most cases similar to that of diesel or gasoline, with the exception of methanol and ethanol that use less energy, especially in SI engines. Tailpipe emissions of CO2 with respect to engine work output (tank-to-output shaft) can be reduced by more than 15% compared to a highly efficient gasoline SI engine, and are the lowest with CNG / lean-burn SI and with alcohols in several engine concepts. Alternative fuels are considered safe and in most cases are associated with reduced risk with respect to cancer and other health and environmental issues.

Gasoline fuels are complex mixtures which consist of more than 200 different hydrocarbon species. In order to decrease the chemical and physical complexity, oxygenated surrogate components were used to enhance the fundamental understanding of partially premixed combustion (PPC). The ignition quality of a fuel is measured by octane number. There are two methods to measure the octane number: research octane number (RON) and motor octane number (MON). In this paper, RON and MON were measured for a matrix of n-heptane, isooctane, toluene, and ethanol (TERF) blends spanning a wide range of octane number between 60.6 and 97. First, regression models were created to derive RON and MON for TERF blends. The models were validated using the standard octane test for 17 TERF blends. Second, three different TERF blends with an ignition delay (ID) of 8 degrees for a specific operating condition were determined using a regression model.