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Striving for sustainable transportation solutions, hydrogen is often identified as a promising energy carrier and internal combustion engines are seen as a cost effective consumer of hydrogen to facilitate the development of a large-scale hydrogen infrastructure. Driven by efficiency and emissions targets defined by the U.S. Department of Energy, a research team at Argonne National Laboratory has worked on optimizing a spark-ignited direct injection engine for hydrogen. Using direct injection improves volumetric efficiency and provides the opportunity to properly stratify the fuel-air mixture in-cylinder. Collaborative 3D-CFD and experimental efforts have focused on optimizing the mixture stratification and have demonstrated the potential for high engine efficiency with low NOx emissions. Performance of the hydrogen engine is evaluated in this paper over a speed range from 1000 to 3000 RPM and a load range from 1.7 to 14.3 bar BMEP.

In 1990, Roy Douglas developed an analytical method to calculate the global air-to-fuel ratio of a two-stroke engine from exhaust gas emissions. While this method has considerable application to two-stroke engines, it does not permit the calculation of air-to-fuel ratios for oxygenated fuels. This study proposed modifications to the Roy Douglas method such that it can be applied to oxygenated fuels. The ISO #16183 standard, the modified Spindt method, and the Brettschneider method were used to evaluate the modifications to the Roy Douglas method. In addition, a trapped air-to-fuel ratio, appropriate for two-stroke engines, was also modified to incorporate oxygenated fuels. To validate the modified calculation method, tests were performed using a two-stroke carbureted and two-stroke direct injected marine outboard engine over a five-mode marine test cycle running indolene and low level blends of ethanol and iso-butanol fuels.

The pressing need to improve U.S. energy independence and reduce climate forcing fossil fuel emissions continues to motivate the development of high-efficiency internal combustion engines. A recent trend has been to downsize and turbocharge automotive spark-ignited engines coupled with direct fuel injection to improve engine efficiency while maintaining vehicle performance. In-line with recent trends in state-of-the-art engine technology, the focus of this study is lean and EGR dilute combustion in a gasoline direct injection (GDI) engine. The lean and dilute operating limits are defined by combustion stability typically in terms of COVIMEP so experiments were carried out on an automotive size single-cylinder research engine to characterize combustion stability. From a 20,000 cycle sequence analysis, lean operating conditions exhibit binary high- to low-IMEP cycle sequences. This may be because the cycle-to-cycle feedback mechanisms are physically limited to one or two cycles.

The U.S. Renewable Fuel Standard (RFS2) requires an increase in the use of advanced biofuels up to 36 billion gallons by 2022. Longer chain alcohols, in addition to cellulosic ethanol and synthetic biofuels, could be used to meet this demand while adhering to the RFS2 corn-based ethanol limitation. Higher carbon number alcohols can be utilized to improve the energy content, knock resistance, and/or petroleum displacement of gasoline-alcohol blends compared to traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part I of this paper focuses on the development of scenarios by which to compare higher alcohol fuel blends to traditional ethanol blends. It also details the implementation of fuel property prediction methods adapted from literature. Possible combinations of eight alcohols mixed with a gasoline blendstock were calculated and the properties of the theoretical fuel blends were predicted.

Higher carbon number alcohols offer an opportunity to meet the Renewable Fuel Standard (RFS2) and improve the energy content, petroleum displacement, and/or knock resistance of gasoline-alcohol blends from traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part II of this paper builds upon the alcohol selection, fuel implementation scenarios, criteria target values, and property prediction methodologies detailed in Part I. For each scenario, optimization schemes include maximizing energy content, knock resistance, or petroleum displacement. Optimum blend composition is very sensitive to energy content, knock resistance, vapor pressure, and oxygen content criteria target values. Iso-propanol is favored in both scenarios' suitable blends because of its high RON value.

Using natural gas in an internal combustion engine (ICE) is emerging as a promising way to improve thermal efficiency and reduce exhaust emissions. In the development of such engine platforms, computational fluid dynamics (CFD) plays a fundamental role in the optimization of geometries and operating parameters. One of the most relevant issues in the simulation of direct injection (DI) gaseous processes is the accurate prediction of the gas jet evolution. The simulation of the injection process for a gaseous fuel does not require complex modeling, nevertheless properly describing high-pressure gas jets remains a challenging task. At the exit of the nozzle, the injected gas is under-expanded, the flow becomes supersonic and shocks occur due to compressibility effects. These phenomena lead to challenging computational requirements resulting from high grid resolution and low computational time-steps.

Early in 2007 President Bush announced in his State of the Union Address a plan to off-set 20% of gasoline with alternative fuels in the next ten years. Ethanol, due to its excellent fuel properties for example, high octane number, renewable character, etc., appears to be a favorable alternative fuel from an engine perspective. Replacing gasoline with ethanol without any additional measures results in unacceptable disadvantages mainly in terms of vehicle range. This paper summarizes combustion studies performed with gasoline as well as blends of gasoline and ethanol. These tests were performed on a modern, 4-cylinder spark ignition engine with direct fuel injection and exhaust gas recirculation. To evaluate the influence of blending on the combustion behavior the engine was operated on the base gasoline calibration. Cylinder pressure data taken during the testing allowed for detailed analysis of rates of heat release and combustion stability.

Dual-fuel combustion using port-injection of low reactivity fuel combined with direct injection of a higher reactivity fuel, otherwise known as Reactivity Controlled Compression Ignition (RCCI), has been shown as a method to achieve high efficiency combustion with moderate peak pressure rise rates, low engine-out soot and NOx emissions. A key requirement for extending to high-load operation is reduce the reactivity of the premixed charge prior to the diesel injection. One way to accomplish this is to use a very low reactivity fuel such as natural gas. In this work, experimental testing was conducted on a 13L multi-cylinder heavy-duty diesel engine modified to operate using RCCI combustion with port injection of natural gas and direct injection of diesel fuel. Natural gas/diesel RCCI engine operation is compared over the EPA Heavy-Duty 13 mode supplemental emissions test with and without EGR.

Low temperature combustion through in-cylinder blending of fuels with different reactivity offers the potential to improve engine efficiency while yielding low engine-out NOx and soot emissions. A Navistar MaxxForce 13 heavy-duty compression ignition engine was modified to run with two separate fuel systems, aiming to utilize fuel reactivity to demonstrate a technical path towards high engine efficiency. The dual-fuel engine has a geometric compression ratio of 14 and uses sequential, multi-port-injection of a low reactivity fuel in combination with in-cylinder direct injection of diesel. Through control of in-cylinder charge reactivity and reactivity stratification, the engine combustion process can be tailored towards high efficiency and low engine-out emissions. Engine testing was conducted at 1200 rpm over a load sweep.

The potential exists to displace a portion of the petroleum diesel demand with butanol and positively impact engine-out particulate matter. As a preliminary investigation, 20% and 40% by volume blends of butanol with ultra low sulfur diesel fuel were operated in a 1999 Mercedes Benz C220 turbo diesel vehicle (Euro III compliant). Cold and hot start urban as well as highway drive cycle tests were performed for the two blends of butanol and compared to diesel fuel. In addition, 35 MPH and 55 MPH steady-state tests were conducted under varying road loads for the two fuel blends. Exhaust gas emissions, fuel consumption, and intake and exhaust temperatures were acquired for each test condition. Filter smoke numbers were also acquired during the steady-state tests. The results showed that for the urban drive cycle, both total hydrocarbon (THC) and carbon monoxide (CO) emissions increased as larger quantities of butanol were added to the diesel fuel.

Previous studies have shown that fuels with higher laminar flame speed also have increased tolerance to EGR dilution. In this work, the effects of fuel laminar flame speed on both lean and EGR dilute spark ignition combustion stability were examined. Fuels blends of pure components (iso-octane, n-heptane, toluene, ethanol, and methanol) were derived at two levels of laminar flame speed. Each fuel blend was tested in a single-cylinder spark-ignition engine under both lean-out and EGR dilution sweeps until the coefficient of variance of indicated mean effective pressure increased above thresholds of 3% and 5%. The relative importance of fuel laminar flame speed to changes to engine design parameters (spark ignition energy, tumble ratio, and port vs. direct injection) was also assessed.

Turbocharged gasoline direct injection (GDI) engines are quickly becoming more prominent in light-duty automotive applications because of their potential improvements in efficiency and fuel economy. While EGR dilute and lean operation serve as potential pathways to further improve efficiencies and emissions in GDI engines, they also pose challenges for stable engine operation. Tests were performed on a single-cylinder research engine that is representative of current automotive-style GDI engines. Baseline cases were performed under steady-state operating conditions where combustion phasing and dilution were varied to determine the effects on indicated efficiency and combustion stability. Sensitivity studies were then carried out by introducing binary low-high perturbation of spark timing and injection duration on a cycle-by-cycle basis under EGR dilute and lean operation to determine dominant feedback mechanisms.

This paper reports on research activities aiming to improve the efficiency of direct injected, hydrogen powered internal combustion engines. In a recent major change in the experimental setup the hydrogen single cylinder research engine at Argonne National Laboratory was upgraded to a new engine geometry providing increased compression ratio and a longer piston stroke compared to its predecessor. The higher compression ratio and the more advantageous volume to surface ratio of the combustion chamber are both intended to improve the overall efficiency of the experimental setup. Additionally, a new series of faster acting, piezo-activated injectors is used with the new engine providing increased flexibility for the optimization of DI injection strategies. This study focuses on the comparison of experimental data of the baseline versus the improved single cylinder research engine for similar engine operating conditions.

This paper reviews and summarizes recent developments in hydrogen (H2) powered engine and vehicle research. Following an overview of mixture formation strategies, general trade-offs when operating engines on hydrogen are analyzed and highlights regarding accomplishments in efficiency improvement and emissions reduction are presented. These include estimates of efficiency potential of direct-injection hydrogen engines based on single-cylinder research engine data, fuel economy and emissions results of hydrogen powered passenger cars and pickup trucks as well as the impact and potential of hydrogen/methane blended operation.

Stricter CO2 and emissions regulations are pushing spark ignition engines more and more towards downsizing, enabled through direct injection and turbocharging. The advantages which come with direct injection, such as increased charge density and an elevated knock resistance, are even more pronounced when using low carbon number alcohols instead of gasoline. This is mainly due to the higher heat of vaporization and the lower air-to-fuel ratio of light alcohols such as methanol, ethanol and butanol. These alcohols are also attractive alternatives to gasoline because they can be produced from renewable resources. Because they are liquid, they can be easily stored in a vehicle. In this respect, the performance and engine-out emissions (NOx, CO, HC and PM) of methanol, ethanol and butanol were examined on a 4 cylinder 2.4 DI production engine and are compared with those on neat gasoline.

Biologically derived isobutanol, a four carbon alcohol, has an energy density closer to that of gasoline and has potential to increase biofuel quantities beyond the current ethanol blend wall. When blended at 16 vol% (iB16), it has identical energy and oxygen content of 10 vol% ethanol (E10). Engine dynamometer emissions tests were conducted on two open-loop electronic fuel-injected marine outboard engines of both two-stroke and four-stroke designs using indolene certification fuel (non-oxygenated), iB16 and E10 fuels. Total particulate emissions were quantified using Sohxlet extraction to determine the amount of elemental and organic carbon. Data indicates a reduction in overall total particulate matter relative to indolene certification fuel with similar trends between iB16 and E10. Gaseous and PM emissions suggest that iB16, relative to E10, could be promising for increasing the use of renewable fuels in recreational marine engines and fuel systems.

The high octane rating and more plentiful domestic supply of natural gas make it an excellent alternative to gasoline. Recent studies have shown that using natural gas in dual fuel engines provides one possible strategy for leveraging the advantages of both natural gas and gasoline. In particular, such engines been able to improve overall engine efficiencies and load capacity when they leverage direct injection of the natural gas fuel. While the benefits of these engine concepts are still being explored, differences in fuel composition, combustion process and in-cylinder mixing could lead to dramatically different emissions which can substantially impact the effectiveness of the engine’s exhaust aftertreatment system. In order to explore this topic, this study examined the variations in speciated hydrocarbon emissions which occur for different fuel blends of E10 and compressed natural gas and for different fuel injection strategies on a spark-ignition engine.

This study evaluates iso-butanol as a pathway to introduce higher levels of alternative fuels for recreational marine engine applications compared to ethanol. Butanol, a 4-carbon alcohol, has an energy density closer to gasoline than ethanol. Isobutanol at 16 vol% blend level in gasoline (iB16) exhibits energy content as well as oxygen content identical to E10. Tests with these two blends, as well as indolene as a reference fuel, were conducted on a Mercury 90 HP, 4-stroke outboard engine featuring computer controlled sequential multi-port Electronic Fuel Injection (EFI). The test matrix included full load curves as well as the 5-mode steady-state marine engine test cycle. Analysis of the full load tests suggests that equal full load performance is achieved across the engine speed band regardless of fuel at a 15-20°C increase in exhaust gas temperatures for the alcohol blends compared to indolene.

Dual-fuel combustion using liquid fuels with differing reactivity has been shown to achieve low-temperature combustion with moderate peak pressure rise rates, low soot and NOx emissions, and high indicated efficiency. Varying fractions of gasoline-type and diesel-type fuels enable operation across a range of low- and mid-load operating conditions. Expanding the operating range to cover the full operating range of a heavy-duty diesel engine, while maintaining the efficiency and emissions benefits, is a key objective. With dissimilar properties of the two utilized fuels lying at the heart of the dual-fuel concept, a tool for enabling this load range expansion is altering the properties of the two test fuels - this study focuses on altering the reactivity of the diesel fuel component. Tests were conducted on a 13L six-cylinder heavy-duty diesel engine modified to run dual-fuel combustion with port gasoline injection to supplement the direct diesel injection.

Dual-fuel combustion using port-injected gasoline with a direct diesel injection has been shown to achieve low-temperature combustion with moderate peak pressure rise rates, low engine-out soot and NOx emissions, and high indicated thermal efficiency. A key requirement for extending high-load operation is moderating the reactivity of the premixed charge prior to the diesel injection. Reducing compression ratio, in conjunction with a higher expansion ratio using alternative valve timings, decreases compressed charge reactivity while maintain a high expansion ratio for maximum work extraction. Experimental testing was conducted on a 13L multi-cylinder heavy-duty diesel engine modified to operate dual-fuel combustion with port gasoline injection to supplement the direct diesel injection. The engine employs intake variable valve actuation (VVA) for early (EIVC) or late (LIVC) intake valve closing to yield reduced effective compression ratio.