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Dielectric barrier discharge (DBD) offers the advantage to excite and dissociate molecules in the exhaust gas stream. Those dissociated and excited species are oxidizing or reducing harmful exhaust gas components. The advantage of a plasma chemical system in comparison to a catalytic measure for exhaust gas treatment is the instantaneous activity at ambient temperature from the starting of the engine. The investigations reviewed in this paper are dealing with the plasma chemical oxidation of hydrocarbons in the exhaust gas stream during cold start conditions. The article concerns the design and development of a plasma-system in order to decrease the hydrocarbon emissions from engine start till catalyst light off. Vehicle results in the New European Driving Cycle show a hydrocarbon conversion of more than 42% in the first 11 seconds from engine start. In this period nearly all types of hydrocarbon were reduced.

In order to reduce engine out CO2 emissions, it is a main subject to find new alternative fuels from renewable sources. For identifying the specification of an optimized fuel for engine combustion, it is essential to understand the details of combustion and pollutant formation. For obtaining a better understanding of the flame behavior, dynamic structure large eddy simulations are a method of choice. In the investigation presented in this paper, an n-heptane spray flame is simulated under engine relevant conditions starting at a pressure of 50 bar and a temperature of 800 K. Measurements are conducted at a high-pressure vessel with the same conditions. Liquid penetration length is measured with Mie-Scatterlight, gaseous penetration length with Shadowgraphy and lift-off length as well as ignition delay with OH*-Radiation. In addition to these global high-speed measurement techniques, detailed spectroscopic laser measurements are conducted at the n-heptane flame.

In this paper different compressor/expander concepts including mechanical superchargers, turbochargers and two-stage charging concepts are analysed with regard to their suitability for fuel cell applications. Special attention is focused on system designs which use the energy of the tail gases for driving the compressor. The net efficiencies of different system concepts at full load were calculated with a simulation model, based on Matlab/Simulink‘ and show, that with a single stage turbocharger in combination with a tail gas burner good efficiencies and high power densities can be obtained at a pressure level of more than 2.5 bar.

In this paper, boosting strategies are investigated for part load operation of typical fuel-cell-systems. The optimal strategy can mainly be obtained by simulation. The boosting strategy is one of the most essential parameters for design and operation of a fuel-cell-system. High pressure ratios enable high power densities, low size and weight. Simultaneously, the demands in humidification and water recovery for today's systems are reduced. But power consumption and design effort of the system increases strongly with the pressure level. Therefore, the main focus must be on the system efficiencies at part load. In addition, certain boundary conditions like the inlet temperature of the fuel-cell stack must be maintained. With high pressure levels the humidification of the intake air before, within or after the compressor is not sufficient to dissipate enough heat. Vaporization during the compression process shows efficiency advantages while the needs in heat dissipation decreases.

An improved plasma reactor has been designed, built and evaluated. It is characterized by a reduced power per area ratio, relative to previous designs, and includes several improvements to run the whole system safely in a car. The new reactor design includes a concentric inner high voltage electrode, a grounded outer electrode, a shielded high-voltage and high temperature resistant electrical connection. A generator controller has been developed for better control of operating conditions as required during the engine cold start phase. The new generator/reactor system was installed in the exhaust pipe of a gasoline direct injection engine. HC emissions could be reduced up to 30 % in the first 40 seconds of a cold start test. In addition to HC treatment the dielectric barrier discharge has also been investigated as a method for regenerating a diesel particulate trap.

Exhaust aftertreatment systems must function sufficiently over the full useful life of a vehicle. In Europe this is currently defined as 160.000 km. With the introduction of Euro 7 it is expected that the required mileage will be extended to 240.000 km. This will then be consistent with the US legislation. In order to quantify the emission impact of exhaust system degradation, an Euro 7 exhaust aftertreatment system is aged by different accelerated approaches: application of the Standard Bench Cycle, the ZDAKW cycle, a novel ash loading method and borderline aging. The results depict the impact of oil ash on the oxygen storage capacity. For tailpipe emissions, the maximum peak temperatures are the dominant aging factor. The cold start performance is effected by both, thermal degradation and ash accumulation. An evaluation of this emission increase requires appropriate benchmarks.

This paper focuses on start-up technology for fuel processing systems with special emphasis on gasoline fueled burners. Initially two different fuel processing systems, an autothermal reformer with preferential oxidation and a steam reformer with membrane, are introduced and their possible starting strategies are discussed. Energy consumption for preheating up to light-off temperature and the start-up time is estimated. Subsequently electrical preheating is compared with start-up burners and the different types of heat generation are rated with respect to the requirements on start-up systems. Preheating power for fuel cell propulsion systems necessarily reaches up to the magnitude of the electrical fuel cell power output. A gasoline fueled burner with thermal combustion has been build-up, which covers the required preheating power.