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An On-Board Distillation System (OBDS) was developed to extract, from gasoline, a highly volatile crank fuel that allows the reduction of startup fuel enrichment and significant spark retard during cold starts and warm-up. This OBDS was installed on a 2001 Lincoln Navigator to explore the emissions reductions possible on a large vehicle with a large-displacement engine. The fuel and spark calibration of the PCM were modified to exploit the benefits of the OBDS startup fuel. Three series of tests were performed: (1) measurement of the OBDS fuel composition and distillation curve per ASTM D86, (2) measurement of real-time cold start (20 °C) tailpipe hydrocarbon emissions for the first 20 seconds of engine operation, and (3) FTP drive cycles at 20 °C with engine-out and tailpipe emissions of gas-phase species measured each second. Baseline tests were performed using stock PCM calibrations and certification gasoline.

As natural gas engines are designed to operate leaner and with increased boost pressure, durability of the spark plugs becomes problematic. Among the various new ignition devices that have been considered to solve some of the problems facing spark plugs, railplugs appear to hold clear advantages in some areas. There are two types of railplugs: coaxial rail and parallel rail. This paper reports the results of an experimental study of various parameters that affect the performance of parallel railplugs. Their performance was quantified by the distance that the arc traveled along the rails from the initiation point. Travel along the rails is thought to be an important performance metric because rail-travel limits excessive local wear and produces a distributed ignition source which can potentially reduce mixture inhomogeneity induced ignition problems.

A survey of the CNG compositions within NGV driving range of Houston was performed. It was found that the statistics for the Texas CNGs were very similar to those from a previous national survey Based upon the present survey results, two extremes of CNG composition were chosen for a study of the effects of composition on emissions, fuel economy, and driveability. Two other CNG compositions were also included to provide for comparisons with the recently completed Auto/Oil Air Quality Improvement Research Program (AQIRP) and to extend the AQIRP database. One of the vehicles used in the AQIRP study was also used in the present investigation. Correlations were investigated for the relationships between the CNG composition and tailpipe emissions, fuel economy, and driveability.

In premixed turbulent combustion models, two mechanisms have been used to explain the increase in the flame speed due to the turbulence. The newer explanation considers the full range of turbulence scales which wrinkle the flame front so as to increase the flame front area and, thus, the flame propagation speed. The fractal combustion model is an example of this concept. The older mechanism assumes that turbulence enables the penetration of unburned mixtures across the flame front via entrainment into the burned mixture zone. The entrainment combustion or eddy burning model is an example of this mechanism. The results of experimental studies of combustion regimes and the flame structures in SI engines has confirmed that most combustion takes place at the wrinkled flame front with additional combustion taking place in the form of flame fingers or peninsulas.

EmiSense Technologies, LLC (www.emisense.com) is commercializing its electronic particulate matter (PM) sensor that is based on technology developed at the University of Texas at Austin (UT). To demonstrate the capability of this sensor for real-time PM measurements and on board diagnostics (OBD) for failure detection of diesel particle filters (DPF), independent measurements were performed to characterize the engine PM emissions and to compare with the PM sensor response. Computational fluid dynamics (CFD) modeling was performed to characterize the hydrodynamics of the sensor's housing and to develop an improved PM sensor housing with reproducible hydrodynamics and an internal baffle to minimize orientation effects. PM sensors with the improved housing were evaluated in the truck exhaust of a heavy duty (HD) diesel engine tested on-road and on a chassis dynamometer at the University of California, Riverside (UCR) using their Mobile Emissions Laboratory (MEL).

Condensation of fuel vapor on the cold surfaces within the combustion chamber is investigated as a possible mechanism for increased HC emissions from SI engines during cold start. A one-dimensional, transient, mass diffusion analysis is used to examine the condensation of single-species fuels on the surfaces of the combustion chamber as the pressure within the cylinder rises during compression and combustion, and re-vaporization during expansion, blowdown, and exhaust. The effects of wall temperature, fuel volatility, and engine load and speed on this mechanism are also discussed. This analysis shows that low-volatility fuel components can condense on the surfaces of the combustion chamber when the surface temperatures are sufficiently low. This condensed fuel may re-vaporize during the power and exhaust strokes, or it may remain in the combustion chamber until surface temperatures rise, perhaps tens of seconds later.

The University of Texas Ethanol Vehicle Challenge team focused upon cold start/driveability, fuel economy, and emissions reduction for our 1999 Ethanol Vehicle Challenge entry. We replaced or coated all fuel system components that were not ethanol compatible. We used the stock PCM for all control functions except control of a novel cold-start system our team designed. The primary modifications for improved emissions control involved ceramic coating of the exhaust manifolds, use of close-coupled ethanol-specific catalysts, increased EGR for the operating conditions of the five longest cruises on the FTP, and our cold-start system that eliminates the need to overfuel the engine at the beginning of the FTP. This EGR control scheme should also benefit urban fuel economy. Additionally, we eliminated EGR at high load to improve power density.

Because only the unburned gases in the crevices can contribute to hydrocarbon emissions, a model was developed that can be used to determine the temporal and spatial histories of both burned gas and unburned gas flow into and out of the piston-liner crevices. The burned fraction in the top-land is primarily a function of engine design. Burned gases continue to get packed into the inter-ring volume until well after the end of combustion and the unburned fuel returned to the chamber from this source depends upon both the position of the top ring end gap relative to the spark plug and of the relative positions of the end gaps of the compression rings with respect to each other. Because the rings rotate, and because the fuel that returns to the chamber from the inter-ring crevice dominates the sources between BDC and IVO when conditions are unfavorable to in-cylinder oxidation, these represent two sources of variability in the HC emissions.

A set of algebraic equations has been developed to replace the iterative thermochemical equilibrium subroutine in zero-dimensional and quasidimensional engine modeling codes. These equations allow calculation of the equilibrium composition given only the equivalence ratio and the fuel characteristics, thereby allowing the composition calculations to be performed external to the iterative main loop. This technique results in a decrease of the required computational time by up to a factor of 13, dependent upon the equivalence ratio and the fuel. The predictions of the equilibrium-equivalent code agree with those of a traditional equilibrium code within 2.5% for the four fuels examined (CH4, C3H8, C2H5OH, and i-C8H18) for compression ratios between 5 and 12:1, intake manifold pressures between 50 and 100 kPa, and equivalence ratios from 0.5 to 1.5. A technique for including constrained equilibrium to account for freezing of CO oxidation during the expansion stroke is also presented.

Trucks operating in inter-modal (drayage) operation in and around port and rail terminals, are responsible for a large proportion of the emissions of NOX, which are problematic for the air quality of the Houston and Dallas/Ft. Worth metro areas. A standard test cycle, called the Texas Dray Truck Cycle, was developed to represent the operation of heavy-duty diesel trucks in dray operations. The test cycle reflects the substantial time spent at idle (~45%) and the high intensity of the on-road portions. This test cycle was then used in the SAE J1321 test protocol to evaluate the effect on fuel consumption and NOX emissions of retrofitting dray trucks with light-weight, low-rolling resistance wide-single tires. In on-track testing, a reduction in fuel consumption of 8.7% was seen, and NOX emissions were reduced by 3.8% with the wide single tires compared to the conventional tires.

Lean mixture combustion might be an important feature in the next generation of SI engines, while diluents (internal and external EGR) have already played a key role in the reductions of emissions and fuel consumption. Lean burn modeling is even more important for engine modeling tools which are sometimes used for new engine development. The effect of flame strain on flame speed is believed to be significant, especially under lean mixture conditions. Current quasi-dimensional engine models usually do not include flame strain effects and tend to predict burn rate which is too high under lean burn conditions. An attempt was made to model flame strain effects in quasi-dimensional SI engine models. The Ford model GESIM (stands for General Engine SIMulation) was used as the platform. A new strain rate model was developed with the Lewis number effect included.

A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested at constant engine speed (2000 rpm) over a range of loads. Engine-out and tailpipe emissions of gas phase species were measured each second. This allowed examination of the engine-out emissions for late and early injection. Seven fuels were used for these tests: five blended fuels and two pure hydrocarbon fuels. These seven fuels can be divided into groups for examination of the effects of volatility, MTBE, and structure (an aromatic versus an i-alkane). Correlations between the fuel properties and their effects on emissions are presented. Use of steady state tests rather than driving cycles to examine fuel effects on emissions eliminates the complications resulting from accelerations, decelerations, and changes of injection timing but care had to be taken to account for the periodic regenerations of the lean NOx trap/catalyst.

A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested over the Federal Test Procedure (FTP) driving cycle. Speciated engine-out hydrocarbon emissions were measured. Seven fuels were used for these tests: five blended fuels and two pure hydrocarbon fuels. One of the blended fuels was CARB Phase 2 reformulated gasoline which was used as the reference fuel. The remaining four blended fuels were made from refinery components to meet specified distillation profiles. The pure hydrocarbon fuels were iso-octane and toluene - an alkane and an aromatic with essentially identical boiling points. The five blended fuels can be grouped to examine the effects of fuel volatility and MTBE. Additionally, correlations were sought between the fuel properties and the Specific Reactivity, the exhaust “toxics”, and the pass-through of unburned fuel species.

The effects of fuel properties on the emissions of a production vehicle with a gasoline direct injection engine operating over the Federal Test Procedure (FTP) cycle were investigated. The vehicle used was a 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine. Engine-out and tailpipe FTP emissions for six fuels and a California Phase 2 RFG reference fuel are presented. Four of the test fuels were blended from refinery components to meet specified distillation profiles. The remaining test fuels were iso-octane and toluene, an iso-alkane and an aromatic with essentially the same boiling point (at atmospheric pressure) that is near the T50 point for the blended fuels. Statistically significant effects, at the 95% confidence level, of the fuels on tailpipe emissions were found. Correlations were sought between the properties of the five blends and the Emissions Indices for engine-out hydrocarbons and NOx and for tailpipe particulates.

Piston wetting can be isolated from the other sources of HC emissions from DISI engines by operating the engine predominantly on a gaseous fuel and using an injector probe to impact a small amount of liquid fuel on the piston top. This results in a marked increase in HC emissions. In a previous study, we used a variety of pure liquid hydrocarbon fuels to examine the influence of fuel volatility and structure on the HC emissions due to piston wetting. It was shown that the HC emissions correspond to the Leidenfrost effect: fuels with very low boiling points yield high HCs and those with a boiling point near or above the piston temperature produce much lower HCs. All of these prior tests of fuel effects were performed at a single operating condition: the Ford World Wide Mapping Point (WWMP). In the present study, the effects of load and engine speed are examined.

A fiber optic instrumented spark plug was used to make time-resolved measurements of the fuel vapor concentration history near the spark gap in a four-valve DISI engine. Four different bulk flow were investigated. Several early and late injection timings were examined. The fuel concentration at the spark gap was correlated with IMEP. Emissions of CO, HCs, and NOx were related to the type of bulk flow. For both early and late injection the CoVs of fuel concentration were generally lowest for the weakest bulk flow which resulted in a stable stratification. Strong bulk flows convected the inhomogeneities through the measurement area near the spark plug resulting in both large intracycle and cycle-to-cycle variation in equivalence ratio at the time of ignition.

A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested at constant engine speed (2000 rpm) over a range of loads. Engine-out and tailpipe emissions of gas phase species were measured each second. This allowed examination of the engine-out emissions for late and early injection. Regeneration of the lean NOx trap/catalyst was also examined, as was the efficiency of NOx reduction. NOx stored in the trap/catalyst is released at the leading edge of regenerations, such that the tailpipe NOx is higher than the engine-out NOx for a brief period. The efficiency of NOx reduction was <50% for the lowest loads examined. As the load increased, the efficiency of NOx reduction decreased to near 0% due to excessive catalyst temperatures. Loads sufficiently high to require a rich mixture produce high NOx reduction efficiencies, but in this case the NOx reduction occurs via the three-way catalysts on this vehicle.

We have examined the influence of piston wetting on the size distribution and mass of particulate matter (PM) emissions in a SI engine using several different fuels. Piston wetting was isolated as a source of PM emissions by injecting known amounts of liquid fuel onto the piston top using an injector probe. The engine was run predominantly on propane with approximately 10% of the fuel injected as liquid onto the piston. The liquid fuels were chosen to examine the effects of fuel volatility and molecular structure on the PM emissions. A nephelometer was used to characterize the PM emissions. Mass measurements from the nephelometer were compared with gravimetric filter measurements, and particulate size measurements were compared with scanning electron microscope (SEM) photos of particulates captured on filters. The engine was run at 1500 rpm at the Ford world-wide mapping point with an overall equivalence ratio of 0.9.

An electronic particulate matter sensor (EPMS) developed at the University of Texas was used to characterize exhaust gases from a single-cylinder diesel engine and a light-duty diesel vehicle. Measurements were made during transient tip-in events with multiple sensor configurations in the single-cylinder engine. The sensor was operated in two modes: one with the electric field energized, and the other with no electric field present. In each mode, different characteristic signals were produced in response to a tip-in event, highlighting the two primary mechanisms of sensor operation. The sensor responded to both the natural charge of the particulate matter (PM) emitted from the engine, and was also found to create a signal by charging neutral particles. The characteristics of the two mechanisms of operation are discussed as well as their implications on the placement and operation of the sensor.

A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested via a variety of driving cycles using California Phase 2 reformulated gasoline. A comparable PFI vehicle was also evaluated. The standard driving cycles examined were the Federal Test Procedure (FTP), Highway Fuel Economy Test, US06, simulated SC03, Japanese 10-15, New York City Cycle, and European ECE+EDU. Engine-out and tailpipe emissions of gas phase species were measured each second. Hydrocarbon speciations were performed for each phase of the FTP for both the engine-out and tailpipe emissions. Tailpipe particulate mass emissions were also measured. The results are analyzed to identify the emissions challenges facing the DISI engine and the factors that contribute to the particulates, NOx, and hydrocarbon emissions problems of the DISI engine.