Search Results

This paper provides an overview of the dual EGO sensor method for OBD-II catalyst efficiency monitoring. The processes governing the relationship between catalyst oxygen storage, HC conversion efficiency, and rear EGO sensor response are reviewed in detail. A simple physical model relating catalyst oxygen storage capacity and rear EGO sensor response is constructed and used in conjunction with experimental data to provide additional insight into the operation of the catalyst monitor. The effect that the catalyst washcoat formulation has in determining the relationship between catalyst oxygen storage capacity and HC conversion efficiency and its impact on the catalyst monitor is also investigated. Lastly, the effects of catalyst failure mode, fuel sulfur, and the fuel additive MMT on the catalyst monitor's ability to properly diagnose catalyst function are discussed.

A study was performed on a lean NOx trap in which the loading of a ceria-containing mixed oxide in the washcoat was varied. After a mild stabilization of the traps, the time required to purge the NOx trap generally increased with increasing amount of mixed oxide. The purge NOx release also increased with increasing mixed oxide level but was greatly diminished after thermal aging. The sulfur tolerance of the NOx trap improved as the mixed oxide content was increased from 0% to 37%. The sample with 0% mixed oxide was more difficult to desulfate than the other samples due to poor water-gas-shift capability. After thermal aging, the NOx reduction efficiency on a 60 second lean/5 second rich cycle was highest for the samples with 0% to 37% mixed oxide at evaluation temperatures of 400°C to 500°C.