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It has been recently shown that (Ce, Zr)O2 mixed oxides provide improved catalytic performances compared to pure CeO2. Cerium oxide is the active Oxygen Storage Capacity (OSC) component in three way catalysts. However, higher performances, including OSC enhancement, can be achieved with thermally stable solid solutions of Ce and Zr oxides. In the present paper, we describe the structure and the advantages of Ce rich (Ce, Zr)O2 solid solutions and the improved catalytic properties of these materials when used in association with platinum. Various analytical techniques were used including thermo-reduction methods, OSC measurements, surface area measurements, XRD, HRTEM, XPS, and XANES/EXAFS.

Limited and non-regulated emissions of scooters were analysed during several annual research programs of the Swiss Federal Office of Environment (BAFU) *). Small scooters, which are very much used in the congested centers of several cities, are a remarkable source of air pollution. Therefore every effort to reduce the emissions is an important contribution to improve the air quality in urban centers. In the present work detailed investigations of particle emissions of different 2-stroke scooters with direct injection and with carburettor were performed. The nanoparticulate emissions were measured by means of SMPS, (CPC) and NanoMet. Also the particle mass emission (PM) was measured with the same method as for Diesel engines. Extensive analyses of PM-residuum for SOF/INSOF, PAH and toxicity equivalence (TEQ), were carried out in an international project network. Particle mass emission (PM) of 2-S Scooters consists mostly of SOF.

The objectives of the present work are to investigate the regulated and unregulated (particle) emissions of a classical and modern 2-stroke and a typical 4-stroke scooter with different ethanol blend fuels. There is also comparison of two different ethanol fuels: pure ethanol (E) *) and hydrous ethanol (EH) which contains 3.9% water and is denatured with 1.5% gasoline. Special attention is paid in this research to the hydrous ethanol, since the production costs of hydrous ethanol are much less than those for (dry) ethanol. The vehicles are with carburettor and without catalyst, which represents the most frequent technology in Eastern Asia and offers the information of engine-out emissions. Exhaust emissions measurements have been performed with fuels containing ethanol (E), or hydrous ethanol (EH) in the portion of 5, 10, 15 and 20% by volume. During the test systematical analysis of particle mass (PM) and nano-particles counts (NP) were carried out.

A direct injection system in which fuel was injected through the cylinder wall was developed and detailed investigation was made for the purpose of reducing short-circuit of fuel in 2-stroke engines. As a result of dynamo tests using 430cc single cylinder engine, it was found that the injector was best attached at a location as close to TDC as possible on the rear transfer port side, and that the entire amount of fuel should be injected towards the piston top surface. Emissions were worsened if fuel was injected towards the exhaust port or spark plug. Although the higher injection pressure resulted in large emissions reduction effects, it did not have a significant effect on fuel consumption. When a butterfly exhaust valve, known to be effective against irregular combustion in the light load range, was applied, it was found to lead to further reductions in HC emission and fuel consumption while also improving combustion stability.

The CBR [1] (Controlled Burn Rate) is a port deactivation concept developed by AVL and is already applied in series production cars. The benefit of this concept is the low engine-out emission (CO, HC and NOx) and good fuel economy. By creating turbulent kinetic energy at the correct time and place in the combustion chamber a rapid and stable combustion occurs which allows to run the engine well above a Lambda Excess Air Ratio of 1.5. The CBR system features two different intake ports, one charge motion port and one filling port. Additionally a device for port-deactivation (slider, butterfly) is applied. At part load points and lower engine speeds the filling port is switched off. The CBR concept was now evoluted for compact engines as CCBR - with carburetor and as CBR Light - for engines with electronic fuel injection. CCBR stands for Carbureted Controlled Burn Rate.

NOx emissions from diesel passenger vehicles affect the atmospheric environment. It is difficult to evaluate the NOx emissions influenced by environmental conditions such as humidity and temperature, traffic conditions, driving patterns, etc. In the authors’ previous study, real-driving experiments were performed on city and highway routes using a diesel passenger car with only an exhaust gas recirculation system. A statistical prediction model of NOx emissions was considered for simple estimations in the real world using instantaneous vehicle data measured by the portable emissions measurement system and global positioning system. The prediction model consisted of explanatory variables, such as velocity, acceleration, road gradient, and position of transmission gear. Using the explanatory variables, NOx emissions on the city and highway routes was well predicted using a diesel vehicle without NOx reduction devices.

A simulation method is presented for the analysis of combustion in spark ignition (SI) engines operated at elevated exhaust gas recirculation (EGR) level and employing multiple spark plug technology. The modeling is based on a zero-dimensional (0D) stochastic reactor model for SI engines (SI-SRM). The model is built on a probability density function (PDF) approach for turbulent reactive flows that enables for detailed chemistry consideration. Calculations were carried out for one, two, and three spark plugs. Capability of the SI-SRM to simulate engines with multiple spark plug (multiple ignitions) systems has been verified by comparison to the results from a three-dimensional (3D) computational fluid dynamics (CFD) model. Numerical simulations were carried for part load operating points with 12.5%, 20%, and 25% of EGR. At high load, the engine was operated at knock limit with 0%, and 20% of EGR and different inlet valve closure timing.

The road transportation sector is undergoing significant changes, and new green scenarios for sustainable mobility are being proposed. In this context, a diversification of the vehicles’ propulsion, based on electric powertrains and/or alternative fuels and technological improvements of the electric vehicles charging stations, are necessary to reduce greenhouse gas emissions. The adoption of internal combustion engines operating with alternative fuels, like methanol, may represent a viable solution for overcoming the limitations of actual grid connected charging infrastructure, giving the possibility to realize off-grid charging stations. This work aims, therefore, at investigating this last aspect, by evaluating the performance of an internal combustion engine fueled with methanol for stationary applications, in order to fulfill the potential demand of an on off-grid charging station.

We present the effect of EGR, at a set fuel flow rate and intake temperature, on the operating parameters of timing of combustion, duration of combustion, power output, thermal efficiency, and NOx emission; which is remarkably low. We find that addition of EGR at constant inlet temperature and constant fuel flow rate has little effect on HCCI parameter of start of combustion (SOC). However, burn duration is highly dependent on the amount of EGR inducted. The experimental setup at UC Berkeley uses a 1.9-liter 4-cylinder diesel engine with a compression ratio of 18.8:1 (offered on a 1995 VW Passat TDI). The engine was converted to run in HCCI mode by addition of an 18kW air pre-heater installed in the intake system. Pressure traces were obtained using four water-cooled quartz pressure transducers, which replaced the Diesel fuel injectors. Gaseous fuel (propane or butane) flowed steadily into the intake manifold.

An advanced low heat rejection engine concept has successfully completed a 100 hour endurance test. The combustion chamber components were insulated with thermal barrier coatings. The engine components included a titanium piston, titanium headface plate, titanium cylinder liner insert, M2 steel valve guides and monolithic zirconia valve seat inserts. The tribological system was composed of a ceramic chrome oxide coated cylinder liner, chrome carbide coated piston rings and an advanced polyolester class lubricant. The top piston compression ring Included a novel design feature to provide self-cleaning of ring groove lubricant deposits to prevent ring face scuffing. The prototype test engine demonstrated 52 percent reduction in radiator heat rejection with reduced intake air aftercooling and strategic forced oil cooling.

Two Cummins B5.9L engines were fueled with 100% biodiesel in excess of 48 months by the Agricultural Engineering Department at the University of Missouri-Columbia. The engines used to power Dodge pickups. The engine lubricating oil was sampled at 1000 mile intervals for analysis. Statistical analysis of the engine lubricating oil indicated that the wear metal levels in the lubricating oil were normal. A reduction in power was noted when the engines were tested using a chassis dynamometer. The 1991 pickup has been driven 110,451 km and the 1992 pickup has been driven approximately 177,022 km. The pickups averaged 6.9 km/L. Engine fuel efficiency and material compatibility issues are addressed in the paper.

Nine identical 40-ft. transit buses were operated on B20 and diesel for a period of two years - five of the buses operated exclusively on B20 (20% biodiesel blend) and the other four on petroleum diesel. The buses were model year 2000 Orion V equipped with Cummins ISM engines, and all operated on the same bus route. Each bus accumulated about 100,000 miles over the course of the study. B20 buses were compared to the petroleum diesel buses in terms of fuel economy, vehicle maintenance cost, road calls, and emissions. There was no difference between the on-road average fuel economy of the two groups (4.41 mpg) based on the in-use data, however laboratory testing revealed a nearly 2% reduction in fuel economy for the B20 vehicles. Engine and fuel system related maintenance costs were nearly identical for the two groups until the final month of the study.

A prototype 2007 ISL Cummins diesel engine equipped with a diesel oxidation catalyst (DOC), diesel particle filter (DPF), variable geometry turbocharger (VGT), and cooled exhaust gas recirculation (EGR) was tested at Southwest Research Institute (SwRI) under a high-load accelerated durability cycle for 1000 hours with B20 soy-based biodiesel blends and ultra-low sulfur diesel (ULSD) fuel to determine the impact of B20 on engine durability, performance, emissions, and fuel consumption. At the completion of the 1000-hour test, a thorough engine teardown evaluation of the overhead, power transfer, cylinder, cooling, lube, air handling, gaskets, aftertreatment, and fuel system parts was performed. The engine operated successfully with no biodiesel-related failures. Results indicate that engine performance was essentially the same when tested at 125 and 1000 hours of accumulated durability operation.

The characteristics of the combustion process in an improved design of a novel spark ignition engine studied by means of Computational Fluid Dynamics are presented. The engine is designed to work at low average combustion temperatures to achieve very low NOx emissions. The engine is a two-stroke, two piston in-line engine. The main combustion occurs in four combustion pre-chambers that have an annular shape with a nozzle on the side facing the cylinder. Fuel is directly injected into the pre-chambers by using high-pressure fuel injectors. A progressive burning process is expected to keep the flame inside the pre-chambers while the fast ejection of combustion products should produce effective mixing with the cold air in the cylinder. This fast dilution should guarantee a temperature drop of the combustion products thus reducing the formation of NOx via a thermal path.

Direct fuel injection is becoming mandatory in two-stroke S.I. engines, since it prevents one of the major problems of these engines, that is fuel loss from the exhaust port. Another important problem is combustion irregularity at light loads, due to excessive presence of residual gas in the charge, and can be solved by charge stratification. High-pressure liquid fuel injection is able to control the mixing process inside the cylinder for getting either stratified charge at partial loads or quasi-stoichiometric conditions, as it is required at full load. This paper shows the development of this solution for a small engine for moped and light scooter, using numeric and experimental tools. In order to obtain the best charge characteristics at every load and engine speed, different combustion chambers have been conceived and studied, examining the effects of combustion chamber geometry, together with injector position and injection timing

Engines and fuels for transport as well as off-road applications are facing a double challenge: bring local pollution to the level requested by the most stringent city air quality standard reduce CO2 emission in order to minimize the global warming risk. These goals stimulate new developments both of conventional and alternative engines and fuels technologies. New combustion processes known as Controlled Auto-Ignition (CAI™) for gasoline engine and Homogeneous Charge Compression Ignition (HCCI) for Diesel engine are the subject of extensive research world wide and particularly at IFP for various applications such as passenger cars, heavy-duty trucks and buses as well as small engines. Because of the thermo-chemistry of the charge, the thermal NOx formation and the soot production are in principle much lower than in flames typical of conventional engines.

A mobile and dispersed power system is necessary for an advanced technological-industrial society. Today's petroleum-based system discharges waste products and heat and is growing exponentially. Energy resource commitment has already intersected “ultimate” low-cost petroleum supplies in the United States and will do so for the world before 2000; this portends major changes and cost increases. The twenty-first century system for mobile-dispersed power will reflect the energy source selected to replace petroleum-for example, coal, solar insolation, or uranium. It will incorporate a fuel intermediate such as methanol, ammonia, or hydrogen, and a suitably matched “engine.” The complete change will require more than 25 years because of the magnitude, fragmentation, structural gaps, complexity, and variety of the mobile-dispersed power system.

A gasoline Road Octane study was conducted by the Coordinating Research Council (CRC) to evaluate the effects of heavy aromatics (C9 and heavier) and ethanol content on Road Octane performance independent of Research Octane Number (RON) and Motor Octane Number (MON). Maximum-throttle and part-throttle Road ON’s were found to be well predicted by equations containing only RON and MON terms. Heavier aromatics were found to have a small adverse effect on both maximum-throttle and part-throttle Road ON independent of its direct effects on RON and MON. The all-car data did not show a significant ethanol-content effect, but eight of the thirty-seven cars did show significant effects for ethanol content.

The conversion design strategy, and emissions and performance results for a dedicated propane, vapour injected, 1995 Dodge Dakota truck are reported. Data is obtained from the University of Waterloo entry in the 1997 Propane Vehicle Challenge. A key feature of the design strategy is its focus on testing and emissions while preserving low engine speed power for drivability. Major changes to the Dakota truck included the following: installation of a custom shaped fuel tank, inclusion of a fuel temperature control module, addition of a vaporizer and a fuel delivery metering unit, installation of a custom vapour distribution manifold, addition of an equivalence ratio electronic controller, inclusion of a wide range oxygen sensor, addition of an exhaust gas recirculation cooler and installation of thermal insulation on the exhaust system. A competition provided natural gas catalyst was used.

As part of the 1997 Propane Vehicle Challenge, a team of twelve UTEP students converted a 1996 Dodge Grand Caravan with a 3.3 L V6 engine to dedicated Liquefied Petroleum Gas (LPG) operation according to the 1997 Propane Vehicle Challenge (PVC) competition rules (16). The 1997 UTEP team developed an LPG liquid phase port fuel injection (LPP-FI) system for the minivan. The UTEP design strategy combines simplicity and sound engineering practices with the effective use of heat resistant materials to maintain the LPG in the liquid phase at temperatures encountered in the fuel delivery system. The team identified two options for fuel storage with in-tank fuel pumps. The competition vehicle incorporates a five-manifold eight inch diameter Sleegers Engineering LPG tank fitted with a Walbro LPTS in-tank pump system, providing a calculated range of 310 city miles and 438 highway miles.