(Ce, Zr)O2 Solid Solutions for Three-Way Catalysts
It has been recently shown that (Ce, Zr)O2 mixed oxides provide improved catalytic performances compared to pure CeO2. Cerium oxide is the active Oxygen Storage Capacity (OSC) component in three way catalysts. However, higher performances, including OSC enhancement, can be achieved with thermally stable solid solutions of Ce and Zr oxides. In the present paper, we describe the structure and the advantages of Ce rich (Ce, Zr)O2 solid solutions and the improved catalytic properties of these materials when used in association with platinum. Various analytical techniques were used including thermo-reduction methods, OSC measurements, surface area measurements, XRD, HRTEM, XPS, and XANES/EXAFS.
(Nano) Particles from 2-S Scooters: SOF / INSOF; Improvements of Aftertreatment; Toxicity
Limited and non-regulated emissions of scooters were analysed during several annual research programs of the Swiss Federal Office of Environment (BAFU) *). Small scooters, which are very much used in the congested centers of several cities, are a remarkable source of air pollution. Therefore every effort to reduce the emissions is an important contribution to improve the air quality in urban centers. In the present work detailed investigations of particle emissions of different 2-stroke scooters with direct injection and with carburettor were performed. The nanoparticulate emissions were measured by means of SMPS, (CPC) and NanoMet. Also the particle mass emission (PM) was measured with the same method as for Diesel engines. Extensive analyses of PM-residuum for SOF/INSOF, PAH and toxicity equivalence (TEQ), were carried out in an international project network. Particle mass emission (PM) of 2-S Scooters consists mostly of SOF.
09 AVL Lean Burn Systems CCBR and CBR Light for Fuel Economy and Emission Optimization on 4-Stroke Engines
The CBR  (Controlled Burn Rate) is a port deactivation concept developed by AVL and is already applied in series production cars. The benefit of this concept is the low engine-out emission (CO, HC and NOx) and good fuel economy. By creating turbulent kinetic energy at the correct time and place in the combustion chamber a rapid and stable combustion occurs which allows to run the engine well above a Lambda Excess Air Ratio of 1.5. The CBR system features two different intake ports, one charge motion port and one filling port. Additionally a device for port-deactivation (slider, butterfly) is applied. At part load points and lower engine speeds the filling port is switched off. The CBR concept was now evoluted for compact engines as CCBR - with carburetor and as CBR Light - for engines with electronic fuel injection. CCBR stands for Carbureted Controlled Burn Rate.
0D Modeling of Real-Driving NOx Emissions for a Diesel Passenger Vehicle
NOx emissions from diesel passenger vehicles affect the atmospheric environment. It is difficult to evaluate the NOx emissions influenced by environmental conditions such as humidity and temperature, traffic conditions, driving patterns, etc. In the authors’ previous study, real-driving experiments were performed on city and highway routes using a diesel passenger car with only an exhaust gas recirculation system. A statistical prediction model of NOx emissions was considered for simple estimations in the real world using instantaneous vehicle data measured by the portable emissions measurement system and global positioning system. The prediction model consisted of explanatory variables, such as velocity, acceleration, road gradient, and position of transmission gear. Using the explanatory variables, NOx emissions on the city and highway routes was well predicted using a diesel vehicle without NOx reduction devices.
0D/3D Simulations of Combustion in Gasoline Engines Operated with Multiple Spark Plug Technology
A simulation method is presented for the analysis of combustion in spark ignition (SI) engines operated at elevated exhaust gas recirculation (EGR) level and employing multiple spark plug technology. The modeling is based on a zero-dimensional (0D) stochastic reactor model for SI engines (SI-SRM). The model is built on a probability density function (PDF) approach for turbulent reactive flows that enables for detailed chemistry consideration. Calculations were carried out for one, two, and three spark plugs. Capability of the SI-SRM to simulate engines with multiple spark plug (multiple ignitions) systems has been verified by comparison to the results from a three-dimensional (3D) computational fluid dynamics (CFD) model. Numerical simulations were carried for part load operating points with 12.5%, 20%, and 25% of EGR. At high load, the engine was operated at knock limit with 0%, and 20% of EGR and different inlet valve closure timing.
1.9-Liter Four-Cylinder HCCI Engine Operation with Exhaust Gas Recirculation
We present the effect of EGR, at a set fuel flow rate and intake temperature, on the operating parameters of timing of combustion, duration of combustion, power output, thermal efficiency, and NOx emission; which is remarkably low. We find that addition of EGR at constant inlet temperature and constant fuel flow rate has little effect on HCCI parameter of start of combustion (SOC). However, burn duration is highly dependent on the amount of EGR inducted. The experimental setup at UC Berkeley uses a 1.9-liter 4-cylinder diesel engine with a compression ratio of 18.8:1 (offered on a 1995 VW Passat TDI). The engine was converted to run in HCCI mode by addition of an 18kW air pre-heater installed in the intake system. Pressure traces were obtained using four water-cooled quartz pressure transducers, which replaced the Diesel fuel injectors. Gaseous fuel (propane or butane) flowed steadily into the intake manifold.
1000-Hour Durability Evaluation of a Prototype 2007 Diesel Engine with Aftertreatment Using B20 Biodiesel Fuel
A prototype 2007 ISL Cummins diesel engine equipped with a diesel oxidation catalyst (DOC), diesel particle filter (DPF), variable geometry turbocharger (VGT), and cooled exhaust gas recirculation (EGR) was tested at Southwest Research Institute (SwRI) under a high-load accelerated durability cycle for 1000 hours with B20 soy-based biodiesel blends and ultra-low sulfur diesel (ULSD) fuel to determine the impact of B20 on engine durability, performance, emissions, and fuel consumption. At the completion of the 1000-hour test, a thorough engine teardown evaluation of the overhead, power transfer, cylinder, cooling, lube, air handling, gaskets, aftertreatment, and fuel system parts was performed. The engine operated successfully with no biodiesel-related failures. Results indicate that engine performance was essentially the same when tested at 125 and 1000 hours of accumulated durability operation.
1997 Propane Vehicle Challenge Design Strategy -University of Waterloo
The conversion design strategy, and emissions and performance results for a dedicated propane, vapour injected, 1995 Dodge Dakota truck are reported. Data is obtained from the University of Waterloo entry in the 1997 Propane Vehicle Challenge. A key feature of the design strategy is its focus on testing and emissions while preserving low engine speed power for drivability. Major changes to the Dakota truck included the following: installation of a custom shaped fuel tank, inclusion of a fuel temperature control module, addition of a vaporizer and a fuel delivery metering unit, installation of a custom vapour distribution manifold, addition of an equivalence ratio electronic controller, inclusion of a wide range oxygen sensor, addition of an exhaust gas recirculation cooler and installation of thermal insulation on the exhaust system. A competition provided natural gas catalyst was used.
1D Fluid Dynamic Modeling of Unsteady Reacting Flows in the Exhaust System with Catalytic Converter for S.I. Engines
This paper deals with some recent advances in the field of 1D fluid dynamic modeling of unsteady reacting flows in complex s.i. engine pipe-systems, involving a catalytic converter. In particular, a numerical simulation code has been developed to allow the simulation of chemical reactions occurring in the catalyst, in order to predict the chemical specie concentration in the exhaust gas from the cylinder to the tailpipe outlet, passing through the catalytic converter. The composition of the exhaust gas, discharged by the cylinder and then flowing towards the converter, is calculated by means of a thermodynamic two-zone combustion model, including emission sub-models. The catalytic converter can be simulated by means of a 1D fluid dynamic and chemical approach, considering the laminar flow in each tiny channel of the substrate.
1D Model of a Copper Exchanged Small Pore Zeolite Catalyst Based on Transient SCR Protocol
Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.
1D Modelling of Reactive Fluid Dynamics, Cold Start Behavior of Exhaust Systems
The introduction of more stringent standards for engine emissions requires a steady development of exhaust gas aftertreatment in addition to an optimized cylinder combustion. The reduction of the cold start phase can help significantly to lower cycle emissions. With the goal of optimizing the overall emission performance this study presents a comprehensive simulation approach. A well established 1D gas dynamics and engine simulation model is extended by three key features. These are models for combustion and pollutant production in the cylinder, models for the pollutant conversion in a catalyst, and a general species transport model. This allows to consider an arbitrary number of chemical species and reactions in the entire system.
1D Thermo-Fluid Dynamic Modelling of a S.I. Engine Exhaust System for the Prediction of Warm-Up and Emission Conversion during a NEDC Cycle
This work describes an experimental and numerical investigation of the thermal transient of i.c. engine exhaust systems. A prototype of exhaust system has been investigated during a NEDC cycle in two different configurations. Firstly an uncoated catalyst has been adopted to consider only the effect of the gas-wall heat transfer. The measurements have been repeated on the same exhaust system equipped with a coated catalyst to point out the contribution of the chemical reactions to the thermal transient of the system. The measured values have been compared to the predicted results carried out with a 1D thermo fluid dynamic code, developed in-house to account for the thermal transient of the system and the chemical reactions occurring in the catalyst.
1D Unsteady Flows with Chemical Reactions in the Exhaust Duct-System of S.I. Engines: Predictions and Experiments
This paper describes some recent advances of the research work concerning the 1D fluid dynamic modeling of unsteady reacting flows in s.i. engine pipe-systems, including pre-catalysts and main catalysts. The numerical model GASDYN developed in previous work has been further enhanced to enable the simulation of the catalyst. The main chemical reactions occurring in the wash-coat have been accounted in the model, considering the mass transfer between gas and solid phase. The oxidation of CO, C3H6, C3H8, H2 and reduction of NO, the steam-reforming reactions of C3H6, C3H8, the water-gas shift reaction of CO have been considered. Moreover, an oxygen-storage sub-model has been introduced, to account for the behavior of Cerium oxides. A detailed thermal model of the converter takes into account the heat released by the exothermic reactions as a source term in the heat transfer equations. The influence of the insulating mat is accounted.
2-D Internal EGR Distribution Measurements in an Engine by Laser-Induced Fluorescence
A novel diagnostic technique named a “Tracer-Producing LIF technique” which enables 2-dimensional measurement of an internal EGR within an engine cylinder, has been developed. The main feature of this technique is the utilization of a fuel additive that does not itself emit an LIF signal by irradiation of UV-light but whose combustion products radiate strong LIF emissions by UV-light irradiation. Internal EGR behaviors can be measured by observing LIF images that are excited by a UV-laser sheet. Firstly, principles of this technique were confirmed and fuel additives were selected. Then, the “Tracer-Producing LIF technique” was applied to an optically accessible single-cylinder gasoline engine in which the entire pent-roof area can be observed from the side of the engine. The internal EGR behaviors were measured through the entire engine cycle, from intake to exhaust.
21 Development of a Small Displacement Gasoline Direct Injection Engine
We have developed a small-displacement gasoline direct-injection engine (1.3L). Gasoline direct-injection engines rely on ultra-lean stratified combustion to deliver significantly better fuel economy, and are already used in many practical applications. When gasoline direct-injection is applied to a small-displacement engine, however, the amount of wall wetting of fuel on the piston surface will increase because the traveled length of the fuel spray is short. This may result in problems such as smoke production, high emissions of unburned HC, and poor combustion efficiency.
25cc HCCI Engine Fuelled with DEE
This paper describes the set-up and testing of a single cylinder 25cc, air cooled, 4-stroke Spark Ignition (SI) engine converted to run in Homogeneous Charge Compression Ignition (HCCI) mode with the aid of various combustion control systems. The combustion control systems were investigated regarding their effects on combustion stability and heat release phasing. Engine operation was compared with unique findings from previous work done on a very small 2-stroke HCCI engine. HCCI engine operation was possible between 1000 - 4000 rpm when using Diethyl Ether (DEE) as the test fuel. Maximum operational fuel-air equivalence ratio (Φ) was 0.75 when operating without Exhaust Gas Recirculation (EGR). This relatively high equivalence ratio was attainable due to thermal gradients induced by the high surface area to volume ratio of the small engine combustion chamber, resulting in high chamber heat transfer.
2D Residual Gas Visualization in an Optical Direct Injection Spark Ignition Engine with IR Laser Absorption
The spatial distribution of internal exhaust gas recirculation (EGR) is evaluated in an optically accessible direct injection spark ignition engine using near infrared laser absorption to visualize the distribution of the H2O molecule. The obtained overall internal exhaust gas recirculation compares well to gas-exchange cycle calculations and the spatial distributions are consistent with those measured with inverse LIF. The experimental procedures described in this report are designed to be simple and rapidly implemented without the need to resort to unusual optical components. The necessary spectral data of the selected absorption line is obtained from the HITEMP database and is validated with prior experiments carried out in a reference cell. Laser speckle in the images is effectively reduced using a ballistic diffuser.
3D Modeling Applied to the Development of a DI Diesel Engine: Effect of Piston Bowl Shape
Multidimensional computations are carried out to aid in the development of a direct injection Diesel engine. Intake, compression, injection and combustion processes are calculated for a turbo-charged direct injection Diesel engine with a single intake valve. The effects of engine speed and engine load, as well as the influence of exhaust gas recirculation are compared to experimental measurements. The influence of piston bowl shape is investigated. Three dimensional calculations are performed using a mesh built from the complete CAD definition of the engine, intake port, cylinder and piston bowl. The injection characteristics are found to be of primary importance in the control of the combustion process. At a given injection set, piston bowl shape can be optimized for fluid dynamic and combustion.
3D Simulations And Experimental Validation of High EGR - PHCCI Combustion
The present work addresses the possibility to correctly simulate Partial Homogeneous Charge Compression Ignition (PHCCI) combustion, obtained by the application of EGR up to 60% without using detailed kinetic models. In particular, the laminar and turbulent time characteristic model has been analyzed and improved. The study illustrates the prediction capabilities that can be achieved with such an approach. The paper reports the results obtained from the simulation of a single cylinder research engine and a four-cylinder diesel engine to verify the validity of the proposed method independently of engine geometry and configuration. All numerical results are compared with experimental pressure traces and rates of heat release, as well as with NOx and soot emissions over a wide range of operating conditions. With the modified characteristic time model, realistic simulations of engine combustion up to EGR values of about 60% have been obtained for both engines.