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Because of the more hostile environment in the compression ignition engine compared to the spark ignition engine, development and application of CI engine in-cylinder diagnostic methods have lagged those for SI engines. However, with more stringent federally mandated particulate and NOx standards which will go into effect in 1991 and 1994, the need for detailed information on the combustion processes in the cylinder is vital to controlling tailpipe emissions. The present paper contains a summary of the state-of-the-art techniques for determining in-situ species concentrations and profiles; particle concentrations, profiles, and size distributions; and temperature fields. Optical and physical probing methods, total cylinder dumping methods, and optical diagnostics applied for use in CI engine combustion chambers are discussed.

Combustion characteristics of an L-head engine combustion chamber have been examined using ionization probes and piezioelectric pressure transducers. The method describes how pressure rise rates, peak pressures, mean effective pressures, and flame arrival times were recorded. The flame arrival times were then used to find the position and shape of the flame front as a function of time. The influence of spark plug location on the above parameters was then examined for two different combustion chamber shapes.

Particle mass and size distribution measurements have been made on the exhaust of an Onan prechamber diesel engine. Seven fuels were examined: no. 1 and no. 2 diesel fuel, 40 and 50 cetane number secondary reference fuels, and no. 2 diesel fuel doped with three different concentrations of Lubrizol 565, a barium-based smoke suppressant. The no. 1 and no. 2 diesel fuels and the 50 cetane number reference fuels produced very similar emissions with emission indices in the range 0.3-1.3 mg (gm-fuel)-1 and volume mean diameters between .09 and 0.15 μm. The 40 cetane number reference fuel produced both smaller emission indices, 0.2 to 0.8 mg (gm-fuel)-1, and particle diameters, 0.03 to 0.09 μm. These reductions were apparently related to the longer ignition delay period of the 40 cetane number fuel, which allowed better mixing of the fuel and air prior to combustion.

An adaptive control system which determines the optimum system parameters based on the engine response to changes in those parameters, has been tested as an ignition timing control system on several gaseous fueled engines. The changes in the MBT timing for speed, load, air-fuel ratio, and fuel type were explored. The ability of the control system to correct the timing for these parameters was demonstrated. An air-fuel ratio control based on the same technique is also discussed.

Diesel particles carry charges ranging from 1-5 units of elementary charge per particle. The charge is bipolar, i.e., there are approximately equal numbers of positively and negatively charged particles. The charge distribution with respect to size follows a high temperature, Boltzmann equilibrium relationship. The first part of this paper describes charge measurements made on diesel particles emitted by three different diesel engines, and postulates a charging mechanism. The second part of the paper is an examination of how this natural charge may be used to collect particles from the exhaust. The charge level produced by combustion is only slightly lower than the charge level produced by the corona discharge in a conventional electrostatic precipitator. Thus, a simple electrostatic precipitator without a corona section will collect diesel particles affectively.

This paper describes the performance and emissions of a hydrogen-fueled, spark-ignited engine. An electronic control device, designed to provide the engine with a timed injection of the fuel, is shown to give high mean effective pressures and high efficiencies. The oxides of nitrogen from the exhaust gases have been analyzed and the mechanism for their formation is reviewed. The paper further describes an experiment with traces of hydrocarbons added to the hydrogen in an attempt to explain any additional phenomena that may be taking place during the combustion, such as “prompt NO” which is known to occur in hydrocarbon flames only. As it turns out, such additions have a negligible effect on the NOx formation in the region investigated.

Measurements of particle concentrations in one cylinder of a 1982 5.7 liter GM V-8 diesel engine have been made using a unique total cylinder sampling system. The first part of the paper is devoted to an examination of the performance of the sampling system. The role of blowoff and nucleation in the formation of sample artifacts is discussed. The remainder of the paper is devoted to the results of a study of the formation and removal of carbon particles during diesel engine combustion. Several operating conditions have been examined. The influence of injection timing, load, EGR, and oxygen addition on particle formation and removal has been investigated. The concentrations of volatile and nonvolatile particulate matter have been measured as a function of crankangle position. Particle formation begins 1-5 crankangle degrees (CAD) after the start of combustion.

In-cylinder and exhaust soot mass measurements have been made on a single-cylinder conversion of a 4-cylinder, 2.8 1, high-swirl, direct-injection diesel engine using a sampling system which allows dumping, diluting, quenching, and collecting the entire contents of the cylinder on a time scale o£ about 1 ms. Experiments have been performed at engine speeds of 1,000 and 1,500, and equivalence ratios, ϕ, of 0.4 and 0.7. Soot mass first appears shortly after top dead center and reaches a peak between 15 and 30 crankangle degrees after top dead center (CAD ATDC). After reaching its peak value, soot concentration decreases with increasing crankangle and approaches exhaust levels by 40-60 CAD ATDC. The time lag between the start of combustion and the first appearance of soot increases with ϕ and ranges from 0.2 to 1 ms. The initial rate of soot formation ranges from 0.26 to 0.30 mg ms−1 and varies little with speed or ϕ.

The formation of particles in the combustion chamber of a direct injection diesel engine has been studied with the use of the Total Cylinder Sampling Method. With this method, nearly the entire contents of the cylinder of an operating diesel engine can be quickly removed at various times during the combustion process. The particle mass and size distributions present in the sample can then be analyzed. If quenching of the combustion process is quick and complete, the resulting samples are representative of the particle mass and size distributions present in the cylinder near the time sampling begins. This paper discusses the effect of injection timing and piston bowl shape on the particle formation and oxidation. Example size distribution measurements are also shown. The particle concentrations in the cylinder were measured for three different injection timings with the standard piston installed in the engine.

The formation of NO2 in the cylinder of a diesel engine has been investigated using a total cylinder sampling technique and a simple kinetic model. Exhaust measurements of NO2 as a function of equivalence ratio and as function of time after engine start were made. Samples obtained by total cylinder sampling from an operating direct injection diesel engine showed NO2/NO ratios of 25 to 50%. This is much higher than the 1 to 3% which was measured in the exhaust. Simulations of the sampling process indicate that conversion of NO to NO2 is at least partially responsible for the high NO2/NO measurements. However, the processes which produce the NO to NO2 conversion during the sampling also occur during normal combustion. This may lead to high NO2 concentrations during the combustion cycle which are then lowered during the expansion to the measured exhaust concentrations.

Vibration signals from diesel engines were analyzed for the purpose of isolating signals relating to injection or combustion which could be used to time the engines. Nonintrusive sensors, magnetically attached to the engine, were used to obtain these vibration signals. Components believed to be associated with combustion or fuel injection were electronically isolated from the remaining engine noise, and subsequently processed to produce specific timing signals. Digital data acquisition and averaging methods were used, coupled with computerized frequency analysis. The signals were experimentally correlated with the combustion process over a wide range of injection timing. The electronic processing system developed provides a real time digital measure of the timing. Data on the accuracy and correlation of experimental measurements will be presented.

This paper describes an examination of the origin of the response of a real-time exhaust particle sensor. The sensor works by detecting the net electrical charge carried by diesel exhaust particles emitted during exhaust blow-down. The distribution of charge on these particles has been measured using an electrical mobility analysis system. The results show that the exhaust particles are highly charged and that their charge distributions are nearly symmetrical. The sensor signal results from a slight departure from this symmetry. The results suggest that most of the charge on the exhaust particles results from bipolar charging by flame ions during combustion, but that the net charge detected by the sensor results from surface interactions which some of the larger particles undergo during exhaust blowdown.

Two types of in-cylinder optical probes were applied to a single cylinder CFR engine to detect knocking combustion. The first probe was integrated directly into the engine spark plug to monitor the radiation from burned gas in the combustion process. The second was built into a steel body and installed near the end gas region of the combustion chamber. It measured the radiant emission from the end gas in which knock originates. The measurements were centered in the near infrared region because thermal radiation from the combustion products was believed to be the main source of radiation from a spark ignition engine. As a result, ordinary photo detectors can be applied to the system to reduce its cost and complexity. It was found that the measured luminous intensity was strongly dependent upon the location of the optical sensor.

One of the more objectionable aspects of the use of diesel engines has been the emission of particulate matter. A literature review of combustion flames, theoretical calculations and dilution tunnel experiments have been performed to elucidate the chemical and physical processes involved in the formation of diesel particulate matter. A comparative dilution tunnel study of diluted and undiluted total particulate data provided evidence supporting calculations that indicate hydro-carbon condensation should occur in the tunnel at low exhaust temperatures. The sample collection system for the measurement of total particulate matter and soluble sulfate in particulate matter on the EPA 13 mode cycle is presented. A method to correct for hydrocarbon interferences in the EPA barium chloranilate method for the determination of sulfate in particulate matter is discussed.

Formation of pollutants from diesel combustion and methods for their control have been reviewed. Of these methods, fuel injection rate and timing were selected for a parametric study relative to total particulate, soluble organic fraction (SOF), sulfates, solids and NO and NO2 emissions from a heavy-duty, turbocharged, after-cooled, direct-injection (DI) diesel. Chemical analyses of the SOF were performed at selected engine conditions to determine the effects of injection rate and timing on each of the eight chemical subfractions comprising the SOF. Biological character of the SOF was determined using the Ames Salmonella/microsome bioassay.

A diesel exhaust sampling system was specially designed to measure and collect emissions from a ceramic wall-flow particulate trap during periods of controlled electric regeneration with the exhaust emissions bypassing the trap. This resulted in the regeneration emissions being independent of those produced during either baseline (no control) or trap (exhaust filtration) sampling conditions. This system provided data regarding the physical, chemical, and biological character of regeneration emissions relative to baseline and trap emissions. Selected emission levels measured continuously during the regeneration process were also used to define the particle combustion process in the trap core. Variations in hydrocarbons (HC), oxides of nitrogen (NOx), and particulate volume concentrations during the regeneration process were used to define four stages of the combustion process: preheat; combustion wave formation; combustion wave propagation; and combustion wave extinction.

The techniques used to characterize the chemical and physical nature of particulates in diesel exhaust emissions are reviewed. The emphasis is on understanding the broader aspects of the fundamental nature of not only diesel particulates, but particulate systems in general. Consideration is given to the special nature of particulates which make them significant pollutants and to the relative place of the diesel in the formation of man-made particles. The underlying combustion processes leading to carbon and sulfur based particulates are reviewed. The important variables in steps of the combustion processes which lead to particulate formation are considered, as well as major fuel and engine factors. Collection methods are examined with examples given from current diesel dilution techniques. Probes, sampling lines, and instrumentation are considered.

Particle formation, growth, coagulation and combustion in the cylinder of an indirect injection passenger car type diesel engine have been studied using a system which allows the cylinder contents to be rapidly expelled through a blowdown port, diluted, and collected in a sample bag for subsequent analysis. Characteristic blowdown times were about 0.5 ms. Samples were analyzed using a condensation nuclei counter to determine particle number concentrations and an electrical aerosol analyzer to determine particle volume concentrations in the 0.01 to 1.0 μm diameter range. Measurements were made with the engine operating at 1000 rpm and an equivalence ratio of 0.32. Peak particle number concentration in the cylinder 13 times the exhaust level, and peak particle volume (or mass) concentration in the cylinder 3 times the exhaust level were observed. These results suggest that significant particle coagulation and oxidation occur during the expansion stroke.