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Technical Paper

(Ce, Zr)O2 Solid Solutions for Three-Way Catalysts

1997-02-24
970463
It has been recently shown that (Ce, Zr)O2 mixed oxides provide improved catalytic performances compared to pure CeO2. Cerium oxide is the active Oxygen Storage Capacity (OSC) component in three way catalysts. However, higher performances, including OSC enhancement, can be achieved with thermally stable solid solutions of Ce and Zr oxides. In the present paper, we describe the structure and the advantages of Ce rich (Ce, Zr)O2 solid solutions and the improved catalytic properties of these materials when used in association with platinum. Various analytical techniques were used including thermo-reduction methods, OSC measurements, surface area measurements, XRD, HRTEM, XPS, and XANES/EXAFS.
Technical Paper

(Nano) Particles from 2-S Scooters: SOF / INSOF; Improvements of Aftertreatment; Toxicity

2007-04-16
2007-01-1089
Limited and non-regulated emissions of scooters were analysed during several annual research programs of the Swiss Federal Office of Environment (BAFU) *). Small scooters, which are very much used in the congested centers of several cities, are a remarkable source of air pollution. Therefore every effort to reduce the emissions is an important contribution to improve the air quality in urban centers. In the present work detailed investigations of particle emissions of different 2-stroke scooters with direct injection and with carburettor were performed. The nanoparticulate emissions were measured by means of SMPS, (CPC) and NanoMet. Also the particle mass emission (PM) was measured with the same method as for Diesel engines. Extensive analyses of PM-residuum for SOF/INSOF, PAH and toxicity equivalence (TEQ), were carried out in an international project network. Particle mass emission (PM) of 2-S Scooters consists mostly of SOF.
Collection

0-D and 1-D Modeling and Numerics, 2017

2017-03-28
Papers in the session cover zero-dimensional, one-dimensional, and quasi-dimensional models for simulation of SI and CI engines with respect to: engine breathing, boosting, and acoustics; SI combustion and emissions; CI combustion and emissions; fundamentals of engine thermodynamics; numerical modeling of gas dynamics; thermal management; mechanical and lubrication systems; system level models for controls; and system level models for vehicle fuel economy and emissions predictions.
Collection

0-D and 1-D Modeling and Numerics, 2018

2018-04-03
Papers in the session cover zero-dimensional, one-dimensional, and quasi-dimensional models for simulation of SI and CI engines with respect to: engine breathing, boosting, and acoustics; SI combustion and emissions; CI combustion and emissions; fundamentals of engine thermodynamics; numerical modeling of gas dynamics; thermal management; mechanical and lubrication systems; system level models for controls; and system level models for vehicle fuel economy and emissions predictions.
Technical Paper

09 AVL Lean Burn Systems CCBR and CBR Light for Fuel Economy and Emission Optimization on 4-Stroke Engines

2002-10-29
2002-32-1778
The CBR [1] (Controlled Burn Rate) is a port deactivation concept developed by AVL and is already applied in series production cars. The benefit of this concept is the low engine-out emission (CO, HC and NOx) and good fuel economy. By creating turbulent kinetic energy at the correct time and place in the combustion chamber a rapid and stable combustion occurs which allows to run the engine well above a Lambda Excess Air Ratio of 1.5. The CBR system features two different intake ports, one charge motion port and one filling port. Additionally a device for port-deactivation (slider, butterfly) is applied. At part load points and lower engine speeds the filling port is switched off. The CBR concept was now evoluted for compact engines as CCBR - with carburetor and as CBR Light - for engines with electronic fuel injection. CCBR stands for Carbureted Controlled Burn Rate.
Technical Paper

0D Modeling of Real-Driving NOx Emissions for a Diesel Passenger Vehicle

2018-09-10
2018-01-1761
NOx emissions from diesel passenger vehicles affect the atmospheric environment. It is difficult to evaluate the NOx emissions influenced by environmental conditions such as humidity and temperature, traffic conditions, driving patterns, etc. In the authors’ previous study, real-driving experiments were performed on city and highway routes using a diesel passenger car with only an exhaust gas recirculation system. A statistical prediction model of NOx emissions was considered for simple estimations in the real world using instantaneous vehicle data measured by the portable emissions measurement system and global positioning system. The prediction model consisted of explanatory variables, such as velocity, acceleration, road gradient, and position of transmission gear. Using the explanatory variables, NOx emissions on the city and highway routes was well predicted using a diesel vehicle without NOx reduction devices.
Technical Paper

0D/1D Turbulent Combustion Model Assessment from an Ultra-Lean Spark Ignition Engine

2019-03-25
2019-01-1409
This paper focuses on an assessment of predictive combustion model using a 0D/1D simulation tool under high load, different excess air ratio λ , and different combustion stabilities (based on coefficient of variation of indicated mean effective pressure COVimep). To consider that, crank angle resolved data of experimental pressure of 500 cycles are recorded under engine speed 1000 RPM and 2000 RPM, wide-open throttle, and λ=1.0, 1.42, 1.7, and 2.0. Firstly, model calibration is conducted using 18 cases at 2000 RPM using 500 cycle-averaged in-cylinder pressure to find optimized model constants. Then, the model constants are unchanged for other cases. Next, different cycle-averaged pressure data are used as inputs in the simulation based on the COVimep for studying sensitivity of the turbulent model constants. The simulation is conducted using 1D simulation software GT-Power.
Technical Paper

0D/3D Simulations of Combustion in Gasoline Engines Operated with Multiple Spark Plug Technology

2015-04-14
2015-01-1243
A simulation method is presented for the analysis of combustion in spark ignition (SI) engines operated at elevated exhaust gas recirculation (EGR) level and employing multiple spark plug technology. The modeling is based on a zero-dimensional (0D) stochastic reactor model for SI engines (SI-SRM). The model is built on a probability density function (PDF) approach for turbulent reactive flows that enables for detailed chemistry consideration. Calculations were carried out for one, two, and three spark plugs. Capability of the SI-SRM to simulate engines with multiple spark plug (multiple ignitions) systems has been verified by comparison to the results from a three-dimensional (3D) computational fluid dynamics (CFD) model. Numerical simulations were carried for part load operating points with 12.5%, 20%, and 25% of EGR. At high load, the engine was operated at knock limit with 0%, and 20% of EGR and different inlet valve closure timing.
Technical Paper

1-D Modeling and Experimental Evaluation of Secondary Air Injection System for a Small SI Engine

2013-10-15
2013-32-9091
In order to comply with the existing emission norms of BSIII in India or EURO III and beyond that also, it is not sufficient to use the catalytic converter technology alone over the wide range of engine operating maps. Different studies across the world have proved that the cost, drivability, operating range against AFR, heat dissipation rate characteristics of catalytic converter limit their use in startup and idling conditions. One common way to tackle this condition is to use the Secondary Air Injection (SAI) system. In this system, small amount of air is injected after the exhaust port to initiate the thermal oxidation of gases. The right amount of air injected at the right time and at right location will reduce the emission by 37-90%. In the following study, SI engine vehicle with single cylinder, 160 cc and having carburetor is used as a test vehicle to evaluate the performance of SAI. The SAI system is modeled in AVL BOOST software and validated against the experimental data.
Journal Article

1-D Simulation Study of Divided Exhaust Period for a Highly Downsized Turbocharged SI Engine - Scavenge Valve Optimization

2014-04-01
2014-01-1656
Fuel efficiency and torque performance are two major challenges for highly downsized turbocharged engines. However, the inherent characteristics of the turbocharged SI engine such as negative PMEP, knock sensitivity and poor transient performance significantly limit its maximum potential. Conventional ways of improving the problems above normally concentrate solely on the engine side or turbocharger side leaving the exhaust manifold in between ignored. This paper investigates this neglected area by highlighting a novel means of gas exchange process. Divided Exhaust Period (DEP) is an alternative way of accomplishing the gas exchange process in turbocharged engines. The DEP concept engine features two exhaust valves but with separated function. The blow-down valve acts like a traditional turbocharged exhaust valve to evacuate the first portion of the exhaust gas to the turbine.
Technical Paper

1.9-Liter Four-Cylinder HCCI Engine Operation with Exhaust Gas Recirculation

2001-05-07
2001-01-1894
We present the effect of EGR, at a set fuel flow rate and intake temperature, on the operating parameters of timing of combustion, duration of combustion, power output, thermal efficiency, and NOx emission; which is remarkably low. We find that addition of EGR at constant inlet temperature and constant fuel flow rate has little effect on HCCI parameter of start of combustion (SOC). However, burn duration is highly dependent on the amount of EGR inducted. The experimental setup at UC Berkeley uses a 1.9-liter 4-cylinder diesel engine with a compression ratio of 18.8:1 (offered on a 1995 VW Passat TDI). The engine was converted to run in HCCI mode by addition of an 18kW air pre-heater installed in the intake system. Pressure traces were obtained using four water-cooled quartz pressure transducers, which replaced the Diesel fuel injectors. Gaseous fuel (propane or butane) flowed steadily into the intake manifold.
Technical Paper

100% LPG Long Haul Truck Conversion - Economy and Environmental Benefits

2012-09-24
2012-01-1983
Advanced Vehicle Technologies (AVT), a Ballarat Australia based company, has developed the World's first diesel to 100% LPG conversion for heavy haul trucks. There is no diesel required or utilized on the trucks. The engine is converted with minimal changes into a spark ignition engine with equivalent power and torque of the diesel. The patented technology is now deployed in 2 Mercedes Actros trucks. The power output in engine dynamometer testing exceeds that of the diesel (in excess of 370 kW power and 2700 Nm torque). In on-road application the power curve is matched to the diesel specifications to avoid potential downstream power-train stress. Testing at the Department of Transport Energy & Infrastructure, Regency Park, SA have shown the Euro 3 truck converted to LPG is between Euro 4 and Euro 5 NOx levels, CO2 levels 10% better than diesel on DT80 test and about even with diesel on CUEDC tests.
Journal Article

1000-Hour Durability Evaluation of a Prototype 2007 Diesel Engine with Aftertreatment Using B20 Biodiesel Fuel

2009-11-02
2009-01-2803
A prototype 2007 ISL Cummins diesel engine equipped with a diesel oxidation catalyst (DOC), diesel particle filter (DPF), variable geometry turbocharger (VGT), and cooled exhaust gas recirculation (EGR) was tested at Southwest Research Institute (SwRI) under a high-load accelerated durability cycle for 1000 hours with B20 soy-based biodiesel blends and ultra-low sulfur diesel (ULSD) fuel to determine the impact of B20 on engine durability, performance, emissions, and fuel consumption. At the completion of the 1000-hour test, a thorough engine teardown evaluation of the overhead, power transfer, cylinder, cooling, lube, air handling, gaskets, aftertreatment, and fuel system parts was performed. The engine operated successfully with no biodiesel-related failures. Results indicate that engine performance was essentially the same when tested at 125 and 1000 hours of accumulated durability operation.
Technical Paper

15 Combustion Characteristics of an Improved Design of a Stratified Charge Spark Ignition Engine

2002-10-29
2002-32-1784
The characteristics of the combustion process in an improved design of a novel spark ignition engine studied by means of Computational Fluid Dynamics are presented. The engine is designed to work at low average combustion temperatures to achieve very low NOx emissions. The engine is a two-stroke, two piston in-line engine. The main combustion occurs in four combustion pre-chambers that have an annular shape with a nozzle on the side facing the cylinder. Fuel is directly injected into the pre-chambers by using high-pressure fuel injectors. A progressive burning process is expected to keep the flame inside the pre-chambers while the fast ejection of combustion products should produce effective mixing with the cold air in the cylinder. This fast dilution should guarantee a temperature drop of the combustion products thus reducing the formation of NOx via a thermal path.
Technical Paper

1997 Propane Vehicle Challenge Design Strategy -University of Waterloo

1998-02-23
980491
The conversion design strategy, and emissions and performance results for a dedicated propane, vapour injected, 1995 Dodge Dakota truck are reported. Data is obtained from the University of Waterloo entry in the 1997 Propane Vehicle Challenge. A key feature of the design strategy is its focus on testing and emissions while preserving low engine speed power for drivability. Major changes to the Dakota truck included the following: installation of a custom shaped fuel tank, inclusion of a fuel temperature control module, addition of a vaporizer and a fuel delivery metering unit, installation of a custom vapour distribution manifold, addition of an equivalence ratio electronic controller, inclusion of a wide range oxygen sensor, addition of an exhaust gas recirculation cooler and installation of thermal insulation on the exhaust system. A competition provided natural gas catalyst was used.
Technical Paper

1D Fluid Dynamic Modeling of Unsteady Reacting Flows in the Exhaust System with Catalytic Converter for S.I. Engines

2000-03-06
2000-01-0210
This paper deals with some recent advances in the field of 1D fluid dynamic modeling of unsteady reacting flows in complex s.i. engine pipe-systems, involving a catalytic converter. In particular, a numerical simulation code has been developed to allow the simulation of chemical reactions occurring in the catalyst, in order to predict the chemical specie concentration in the exhaust gas from the cylinder to the tailpipe outlet, passing through the catalytic converter. The composition of the exhaust gas, discharged by the cylinder and then flowing towards the converter, is calculated by means of a thermodynamic two-zone combustion model, including emission sub-models. The catalytic converter can be simulated by means of a 1D fluid dynamic and chemical approach, considering the laminar flow in each tiny channel of the substrate.
Technical Paper

1D Model for Correcting the Rate of Injection Signal Based on Geometry and Temperature Influence

2017-03-28
2017-01-0819
The fuel consumption and emissions of diesel engines is strongly influenced by the injection rate pattern, which influences the in-cylinder mixing and combustion process. Knowing the exact injection rate is mandatory for an optimal diesel combustion development. The short injection time of no more than some milliseconds prevents a direct flow rate measurement. However, the injection rate is deduced from the pressure change caused by injecting into a fuel reservoir or pipe. In an ideal case, the pressure increase in a fuel pipe correlates with the flow rate. Unfortunately, real measurement devices show measurement inaccuracies and errors, caused by non-ideal geometrical shapes as well as variable fuel temperature and fuel properties along the measurement pipe. To analyze the thermal effect onto the measurement results, an available rate measurement device is extended with a flexible heating system as well as multiple pressure and temperature sensors.
Technical Paper

1D Model of a Copper Exchanged Small Pore Zeolite Catalyst Based on Transient SCR Protocol

2013-04-08
2013-01-1578
Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.
Technical Paper

1D Modelling of Reactive Fluid Dynamics, Cold Start Behavior of Exhaust Systems

2006-04-03
2006-01-1544
The introduction of more stringent standards for engine emissions requires a steady development of exhaust gas aftertreatment in addition to an optimized cylinder combustion. The reduction of the cold start phase can help significantly to lower cycle emissions. With the goal of optimizing the overall emission performance this study presents a comprehensive simulation approach. A well established 1D gas dynamics and engine simulation model is extended by three key features. These are models for combustion and pollutant production in the cylinder, models for the pollutant conversion in a catalyst, and a general species transport model. This allows to consider an arbitrary number of chemical species and reactions in the entire system.
Technical Paper

1D Thermo-Fluid Dynamic Modelling of a S.I. Engine Exhaust System for the Prediction of Warm-Up and Emission Conversion during a NEDC Cycle

2005-09-11
2005-24-073
This work describes an experimental and numerical investigation of the thermal transient of i.c. engine exhaust systems. A prototype of exhaust system has been investigated during a NEDC cycle in two different configurations. Firstly an uncoated catalyst has been adopted to consider only the effect of the gas-wall heat transfer. The measurements have been repeated on the same exhaust system equipped with a coated catalyst to point out the contribution of the chemical reactions to the thermal transient of the system. The measured values have been compared to the predicted results carried out with a 1D thermo fluid dynamic code, developed in-house to account for the thermal transient of the system and the chemical reactions occurring in the catalyst.
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