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Abstract The ASTM D130 was first issued in 1922 as a tentative standard for the detection of corrosive sulfur in gasoline. A clean copper strip was immersed in a sample of gasoline for three hours at 50°C with any corrosion or discoloration taken to indicate the presence of corrosive sulfur. Since that time, the method has undergone many revisions and has been applied to many petroleum products. Today, the ASTM D130 standard is the leading method used to determine the corrosiveness of various fuels, lubricants, and other hydrocarbon-based solutions to copper. The end-of-test strips are ranked using the ASTM Copper Strip Corrosion Standard Adjunct, a colored reproduction of copper strips characteristic of various degrees of sulfur-induced tarnish and corrosion, first introduced in 1954. This pragmatic approach to assessing potential corrosion concerns with copper hardware has served various industries well for a century.

The experience accumulated with a prototype 1000 HP diesel electric tractor since 1969 is described. The new 1500 HP V220 diesel electric tractors are described along with some of the initial operation of these two units. Experience with the initial 1000 HP unit and the two 1500 HP tractors confirm the necessity of additional testing and experimentation to refine the design to get greater productivity with reduced operator fatigue. The unpredictability of the load and operating surface are major problems that present a real challenge to the engineer.

The Body Division of the Automotive Corrosion and Prevention Committee of SAE (ACAP) concluded that an automotive body corrosion survey for public consumption was needed. The committee proceeded to develop a survey methodology and conducted an initial survey in the Detroit area. Similar surveys can be conducted at regular biyearly intervals for comparison to track the results of industry wide improvements in corrosion protection. Over two hundred 1980 and 1981 model year vehicles were surveyed covering a wide range of domestic models and some foreign models. Twenty six panel or partial panel categories were developed and evaluated for a closed car parking lot survey. Each panel was checked for perforation, blistering and surface rust.

This paper deals with some recent advances in the field of 1D fluid dynamic modeling of unsteady reacting flows in complex s.i. engine pipe-systems, involving a catalytic converter. In particular, a numerical simulation code has been developed to allow the simulation of chemical reactions occurring in the catalyst, in order to predict the chemical specie concentration in the exhaust gas from the cylinder to the tailpipe outlet, passing through the catalytic converter. The composition of the exhaust gas, discharged by the cylinder and then flowing towards the converter, is calculated by means of a thermodynamic two-zone combustion model, including emission sub-models. The catalytic converter can be simulated by means of a 1D fluid dynamic and chemical approach, considering the laminar flow in each tiny channel of the substrate.

The fuel consumption and emissions of diesel engines is strongly influenced by the injection rate pattern, which influences the in-cylinder mixing and combustion process. Knowing the exact injection rate is mandatory for an optimal diesel combustion development. The short injection time of no more than some milliseconds prevents a direct flow rate measurement. However, the injection rate is deduced from the pressure change caused by injecting into a fuel reservoir or pipe. In an ideal case, the pressure increase in a fuel pipe correlates with the flow rate. Unfortunately, real measurement devices show measurement inaccuracies and errors, caused by non-ideal geometrical shapes as well as variable fuel temperature and fuel properties along the measurement pipe. To analyze the thermal effect onto the measurement results, an available rate measurement device is extended with a flexible heating system as well as multiple pressure and temperature sensors.

Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.

This paper describes the development and application of the 1D thermo-fluid dynamic research code GASDYN to the simulation of a Lamborghini 12 cylinder, V 60°, 6.2 L automotive S.I. engine. The model has been adopted to carry out an integrated simulation (thermodynamic, fluid dynamic and chemical) of the engine coupled to its intake and exhaust manifolds, in order to predict not only the wave motion in the ducts and its influence on the cylinder gas exchange process, but also the in-cylinder combustion process and the pollutant emission concentration along the exhaust system. The gas composition in the exhaust pipe system is dictated by the cylinder discharge process, after the calculation of the combustion via a thermodynamic multi-zone model, based on a “fractal geometry” approach.

This paper describes some recent advances of the research work concerning the 1D fluid dynamic modeling of unsteady reacting flows in s.i. engine pipe-systems, including pre-catalysts and main catalysts. The numerical model GASDYN developed in previous work has been further enhanced to enable the simulation of the catalyst. The main chemical reactions occurring in the wash-coat have been accounted in the model, considering the mass transfer between gas and solid phase. The oxidation of CO, C3H6, C3H8, H2 and reduction of NO, the steam-reforming reactions of C3H6, C3H8, the water-gas shift reaction of CO have been considered. Moreover, an oxygen-storage sub-model has been introduced, to account for the behavior of Cerium oxides. A detailed thermal model of the converter takes into account the heat released by the exothermic reactions as a source term in the heat transfer equations. The influence of the insulating mat is accounted.

2-Butanone (C4H8O) is a promising alternative fuel candidate as a pure as well as a blend component for substitution in standard gasoline fuels. It can be produced by the dehydrogenation of 2-butanol. To describe 2-butanone's basic combustion behaviour, it is important to investigate key physical properties such as the laminar burning velocity. The laminar burning velocity serves on the one hand side as a parameter to validate detailed chemical kinetic models. On the other hand, especially for engine simulations, various combustion models have been introduced, which rely on the laminar burning velocity as the physical quantity describing the progress of chemical reactions, diffusion, and heat conduction. Hence, well validated models for the prediction of laminar burning velocities are needed. New experimental laminar burning velocity data, acquired in a high pressure spherical combustion vessel, are presented for 1 atm and 5 bar at temperatures of 373 K and 423 K.

To measure the fuel vapor concentration in an unsteady evaporating spray injected into nitrogen atmosphere, the exciplex-forming method, which produces spectrally separated fluorescence from the liquid and vapor phase, was applied in this study. Two experiments were conducted to investigate the qualitative and quantitative applicability of the technique in a high temperature and high pressure atmosphere during the fuel injection period. One is to examine the thermal decomposition of TMPD dopant at a high temperature and a high pressure nitrogen atmosphere during a short period of time. The other is to calibrate the relationship between fluorescence intensity and vapor concentration of TMPD at different vapor temperatures. And then, the qualitative measurement of fuel vapor concentration distributions in diesel sprays was made by applying the technique.

The two-dimensional distribution of a soot cloud in an unsteady spray flame in a rapid compression machine(RCM) was visualized using the laser sheet scattering technique. A 40 mm x 50 mm cross section on the flame axis was illuminated by a thin laser sheet from a single pulsed Nd:YAG laser(wavelength 532 nm). Scattered light from soot particles was taken by a CCD camera via a high speed gated image intensifier. The temporal variation of the scattered light images were presented with the injection pressure as a parameter. The results showed that scattered light was intense near the periphery of the flame tip and that the scattered light becomes weaker significantly and disappears fast after the end of injection as injection pressure is increased. This technique was also applied to the visualization of the two-dimensional distribution of liquid droplets in the non-evaporating spray to correlate it with the soot concentration distribution.

The present study compares the NVH performance of three different materials used on cam covers in automobiles, Aluminum (Al), Magnesium (Mg) and Thermoplastic (TP). The cam cover design used for this comparison was the 2004 Nissan Maxima 3.5L production cam cover which is made of a thermoplastic (TP). The Al and Mg covers for this study were created by sandcast, due to time constraints, via laser scanning techniques using the 2004 Nissan Maxima 3.5L production thermoplastic cover design. Note that sand-cast covers generally provide a less quiet sound field than the standard casting method. The Nissan production cover comes with a production baffle made of a similar material as the cover. Testing was conducted with and without the production baffle for all covers. The study was conducted for the production boundary condition of a non-isolated cover and a Freudenberg-NOK (FNGP) partially isolated cover. Isolated bolt assemblies using elastomeric grommets were used to isolate the cover.

This paper describes a new concept for a Ford GT instrument panel (IP) based on structural magnesium components, which resulted in what may be the industry's first structural IP (primary load path). Two US-patent applications are ongoing. Design criteria included cost, corrosion protection, crashworthiness assessments, noise vibration harshness (NVH) performance, and durability. Die casting requirements included feasibility for production, coating strategy and assembly constraints. The magnesium die-cast crosscar beam, radio box and console top help meet the vehicle weight target. The casting components use an AM60 alloy that has the necessary elongation properties required for crashworthiness. The resulting IP design has many unique features and the flexibility present in die-casting that would not be possible using conventional steel stampings and assembly techniques.

The High Voltage Power Distribution Unit (PDU) is constructed of magnesium in support of Fuel Cell Electric Vehicle (FCEV) weight reduction efforts. The PDU distributes and controls a nominal 75 kilowatts of power generated by the Fuel Cell, the primary source of High Voltage power, to all the vehicle loads and accessories. The constraints imposed on the design of the PDU resulted in a component highly susceptible to general and galvanic corrosion. Corrosion abatement was the focus of the PDU redesign. This paper describes the redesign efforts undertaken by Ford personnel to improve the part robustness and corrosion resistance.

Various techniques are constantly being devised to accelerate model generation leading to shorter product development cycle. This work proposes and implements a reduced synthetic gas bench (SGB) test protocol for a commercial Pt-Pd diesel oxidation catalyst (DOC) that can be used to develop global reaction kinetics. The kinetics thus developed were implemented in a 1D model to predict DOC emissions accurately over a wide operating window. Hydrocarbons (HCs) in the exhaust were categorized as Propylene (C3H6) representing partially oxidized hydrocarbons and n-Decane (C10H22) representing unburnt fuel. Test protocols were defined using the order of inhibition of the various species present in the exhaust, namely, CO, NOx (NO+NO2) and HC for the specific reaction under consideration. The oxidation reactions for CO and HCs were found to be inhibited competitively by CO and HCs; both the NOx species inhibited these reactions to the same extent.

To effectively utilize larger trucks (85 ton and up), open-pit mines and quarries need a larger front-end loader with high reliability and performance. This paper describes the design approach and tests carried out to design 21 cubic yard 580 PAY® loader to meet these requirements. Long fatigue life of structures was obtained by use of full penetration welds. New concept for power control was designed to effectively distribute power between hydraulics and drive train. Spring applied - pressure released brakes were designed into the axle. Tests were carried out in our laboratory and proving grounds to determine performance and reliability.

This study focuses on variable amplitude loadings applied to automotive chassis parts experiencing carmaker’s specific proving grounds. They are measured with respect to time at the wheel centres and composed of the six forces and torques at each wheel, within the standard vehicle reference frame. In the scope of high cycle fatigue, the loadings considered are supposedly acting under the structure yield stress. Among the loadings encountered during the vehicle lifetime, two classes stand out: Driven Road: loads measured during the vehicle manoeuvre; Random Road: loads mainly coming from the road asperity. To separate both effects, a frequency decomposition method is proposed before applying any lifetime assessment methods. The usual Rainflow counting method is applied to the Driven Road signal. These loadings, depending on the vehicle dynamics, are time-correlated. Thus, the load spectra is set only thanks to the vehicle accelerations time-measurement.

Increased torque values passing from engine to transmission have, increasingly become a problem regarding shaft misalignment. Engineers are restricted with regard to applying ISO standards when investigating bearing life cycles as they tend only to cover normal [radial thrust] load conditions. Depending on the application, the need has arisen for numerical models to determine reduction in normal life cycles due to abnormal running conditions. The Simulia Finite Element package Abaqus v6.7 provides trends in the deformations, contact pressures and their respective distribution. It was found the most efficient profile, with regards to a uniform contact pressure, under both radial and misaligned conditions is the toroidal profile.

The urea Selective Catalytic Reduction (SCR) exhaust system has been proved to be the reliable aftertreatment device with the capability of reducing tail pipe NOx emission by 75% to 90%, HC by 50% and Particulate Matter (PM) by 30%. Constrained by increasingly stringent packaging envelope, flow mixing in front of substrate is becoming one of the major concerns to achieve ideal performance of higher NOx conversion and lower ammonia (NH3) slip. Three dimensional CFD simulations are performed in current study to investigate flow mixing phenomenon in a SCR system. First, for a traditional tube injector with single or multiple nozzles, the effects of mass flow rates of injected NH3 and exhaust gas on flow mixing and pressure loss are investigated. Then, a concept of ring shape injector with multiple nozzles are initiated and built for 3-D CFD simulations. The comparisons of flow mixing index and injection pressure are made between two type injectors.

The main objective of the current paper was to investigate the fluid flow and pressure loss characteristics of DPF substrates with asymmetric channels utilizing 3-D Computational Fluid Dynamics (CFD) methods. The ratio of inlet to outlet channel width is 1.2. First, CFD results of velocity and static pressure distributions inside the inlet and outlet channels are discussed for the baseline case with both forward and reversed exhaust flow. Results were also compared with the regular DPF of same cell structure and wall material properties. It was found that asymmetrical channel design has higher pressure loss. The lowest pressure loss was found for the asymmetrical channel design with smaller inlet channels. Then, the effects of DPF length and filter wall permeability on pressure loss, flow and pressure distributions were investigated.