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Currently, states that are out of compliance with the National Ambient Air Quality Standards must, according to the Clean Air Act Amendments of 1990 (CAAA), develop and implement control strategies that demonstrate specific degrees of reduction in emissions-with the degree of reduction depending upon the severity of the problem. One tool that has been developed to aid regulators in both deciding an appropriate course of action and to demonstrate the desired reductions in mobile emissions is EPA's Mobile 5a emission estimation model. In our study, Mobile 5a has been used to examine the effects of regulatory strategies, as applied to the Northeast United States, on vehicle emissions under worst-case ozone-forming conditions.

A set of experiments was performed to investigate the effects of relative air-fuel ratio, inlet boost pressure, and compression ratio on engine knock behavior. Selected operating conditions were also examined with simulated hydrogen rich fuel reformate added to the gasoline-air intake mixture. For each operating condition knock limited spark advance was found for a range of octane numbers (ON) for two fuel types: primary reference fuels (PRFs), and toluene reference fuels (TRFs). A smaller set of experiments was also performed with unleaded test gasolines. A combustion phasing parameter based on the timing of 50% mass fraction burned, termed “combustion retard”, was used as it correlates well to engine performance. The combustion retard required to just avoid knock increases with relative air-fuel ratio for PRFs and decreases with air-fuel ratio for TRFs.

This paper provides an overview of spark-ignition engine unburned hydrocarbon emissions mechanisms, and then uses this framework to relate measured engine-out hydrocarbon emission levels to the processes within the engine from which they result. Typically, spark-ignition engine-out HC levels are 1.5 to 2 percent of the gasoline fuel flow into the engine; about half this amount is unburned fuel and half is partially reacted fuel components. The different mechanisms by which hydrocarbons in the gasoline escape burning during the normal engine combustion process are described and approximately quantified. The in-cylinder oxidation of these HC during the expansion and exhaust processes, the fraction which exit the cylinder, and the fraction oxidized in the exhaust port and manifold are also estimated.

This paper explores the benefits that would be achieved if gasoline marketers produced and offered a higher-octane gasoline to the U.S. consumer market as the standard grade. By raising octane, engine knock constraints are reduced, so that new spark-ignition engines can be designed with higher compression ratios and boost levels. Consequently, engine and vehicle efficiencies are improved thus reducing fuel consumption and greenhouse gas (GHG) emissions for the light-duty vehicle (LDV) fleet over time. The main objective of this paper is to quantify the reduction in fuel consumption and GHG emissions that would result for a given increase in octane number if new vehicles designed to use this higher-octane gasoline are deployed. GT-Power simulations and a literature review are used to determine the relative brake efficiency gain that is possible as compression ratio is increased.

Spark-ignition engine knock was characterized in terms of when during the engine cycle and combustion process knock occurred and its magnitude or intensity. Cylinder pressure data from a large number of successive individual cycles were generated from a single-cylinder engine of hemispherical chamber design over a range of operating conditions where knock occurred in some or all of these cycles. Mean values and distributions of following parameters were quantified: knock occurrence crank angle, knock intensity, combustion rate and the end-gas thermodynamic state. These parameters were determined from the cylinder pressure data on an individual cycle basis using a mass-burn-rate analysis. The effects of engine operating variables on these parameters were studied, and correlations between these parameters were examined.

Gasoline/ethanol fuel blends have significant synergies with Spark Ignited Direct Injected (SI DI) engines. The higher latent heat of vaporization of ethanol increases charge cooling due to fuel evaporation and thus improves knock onset limits and efficiency. Realizing these benefits, however, can be challenging due to the finite time available for fuel evaporation and mixing. A methodology was developed to quantify how much in-cylinder charge cooling takes place in an engine for different gasoline/ethanol blends. Using a turbocharged SI engine with both Port Fuel Injection (PFI) and Direct Injection (DI), knock onset limits were measured for different intake air temperatures for both types of injection and five gasoline/ethanol blends. The superior charge cooling in DI compared to PFI for the same fuel resulted in pushing knock onset limits to higher in-cylinder maximum pressures. Knock onset is used as a diagnostic of charge cooling.

Spark Ignited Direct Injection (SI DI) of fuel extends engine knock limits compared to Port Fuel Injection (PFI) by utilizing the large in-cylinder charge cooling effect due to fuel evaporation. The use of gasoline/ethanol blends in direct injection (DI) is therefore especially advantageous due to the high heat of vaporization of ethanol. In addition to the thermal benefit due to charge cooling, ethanol blends also display superior chemical resistance to autoignition, therefore allowing the further extension of knock limits. Unlike the charge cooling benefit which is realized mostly in SI DI engines, the chemical benefit of ethanol blends exists in Port Fuel Injected (PFI) engines as well. The aim of this study is to separate and quantify the effect of fuel chemistry and charge cooling on knock. Using a turbocharged SI engine with both PFI and DI, knock limits were measured for both injection types and five gasoline-ethanol blends.

This paper assesses the potential improvement of automotive powertrain technologies 25 years into the future. The powertrain types assessed include naturally-aspirated gasoline engines, turbocharged gasoline engines, diesel engines, gasoline-electric hybrids, and various advanced transmissions. Advancements in aerodynamics, vehicle weight reduction and tire rolling friction are also taken into account. The objective of the comparison is the potential of anticipated improvements in these powertrain technologies for reducing petroleum consumption and greenhouse gas emissions at the same level of performance as current vehicles in the U.S.A. The fuel consumption and performance of future vehicles was estimated using a combination of scaling laws and detailed vehicle simulations. The results indicate that there is significant potential for reduction of fuel consumption for all the powertrains examined.

The goal of this paper is to quantitatively assess the implications of congressionally mandated biofuel targets on requirements for ethanol blending, distribution, and usage in spark ignition engines in the U.S. light-duty vehicle fleet. The “blend wall” is a term that refers to the maximum amount of ethanol that can be blended into the gasoline pool without exceeding the legal volumetric blend limit of 10%. Beyond the blend wall, the additional ethanol fuel must be used in higher blends of ethanol like E85. Once the blend wall is reached, the existing fleet of flex fuel vehicles (FFVs) will be required to use E85 for some percentage of vehicle miles traveled (VMT) in order to achieve the Renewable Fuel Standard (RFS) targets.

The effects of combustion chamber and intake valve deposit build-up on the knocking characteristics of a spark ignition engine were studied. A Chrysler 2.2 liter engine was run continuously for 180 hours to build up intake valve and combustion chamber deposits. In the tests reported here, the gasoline used contained a deposit controlling fuel additive. The engines's octane requirement increased by 10 research octane numbers during this extended engine operating period. At approximately 24 hour intervals during these tests, the engine was audibly knock rated to determine its octane requirement. Cylinder pressure data was collected during knocking conditions to investigate the knocking characteristics of each cylinder, and deposit build-up effects on those statistics. Cylinder-to-cylinder variations in knock statistics were studied. Analysis of the data indicated that some 20 to 40 percent of cycles knock before the knock is audibly detected.

Experiments were performed to identify the knock trends of lean hydrocarbon-air mixtures, and such mixtures enhanced with hydrogen (H2) and carbon monoxide (CO). These enhanced mixtures simulated 15% and 30% of the engine's gasoline being reformed in a plasmatron fuel reformer [1]. Knock trends were determined by measuring the octane number (ON) of the primary reference fuel (mixture of isooctane and n-heptane) supplied to the engine that just produced audible knock. Experimental results show that leaner operation does not decrease the knock tendency of an engine under conditions where a fixed output torque is maintained; rather it slightly increases the octane requirement. The knock tendency does decrease with lean operation when the intake pressure is held constant, but engine torque is then reduced.

When hydrogen is added to a gasoline fueled spark ignition engine the lean limit of the engine can be extended. Lean running engines are inherently more efficient and have the potential for significantly lower NOx emissions. In the engine concept examined here, supplemental hydrogen is generated on-board the vehicle by diverting a fraction of the gasoline to a plasmatron where a partial oxidation reaction is initiated with an electrical discharge, producing a plasmatron gas containing primarily hydrogen, carbon monoxide, and nitrogen. Two different gas mixtures were used to simulate the plasmatron output. An ideal plasmatron gas (H2, CO, and N2) was used to represent the output of the theoretically best plasmatron. A typical plasmatron gas (H2, CO, N2, and CO2) was used to represent the current output of the plasmatron. A series of hydrogen addition experiments were also performed to quantify the impact of the non-hydrogen components in the plasmatron gas.

A method to collect and speciate the components of gasoline absorbed in the lubricant oil using gas chromatography has been developed. Samples were collected continuously from the piston skirt, baffle and sump in a Saturn engine. A long (18 hours) test was performed to determine the build up of hydrocarbons in the sump, and a shorter (25 min) test was performed to determine the build up of hydrocarbons in the piston skirt and baffle during engine warm-up. The first experiment showed that the total hydrocarbon concentration in the sump oil reached a steady state of about 1.35% mass fraction after 11 hours of engine operation. The relative concentration of individual fuel hydrocarbon species absorbed in the oil increases exponentially with boiling point. Most of the identified species in the oil consist of the heavy end aromatics. Similar compositions but lower concentrations were found for samples collected from the piston skirt during engine warm-up.

1 Downsizing and turbocharging a spark-ignited engine is becoming an important strategy in the engine industry for improving the efficiency of gasoline engines. Through boosting the air flow, the torque is increased, the engine can thus be downsized, engine friction is reduced in both absolute and relative terms, and engine efficiency is increased. However knock onset with a given octane rating fuel limits both compression ratio and boost levels. This paper explores the operating limits of a turbocharged engine, with various gasoline-ethanol blends, and the interaction between compression ratio, boost levels, and spark retard, to achieve significant increases in maximum engine mean effective pressure and efficiency.

Experiments were carried out to collect in-cylinder pressure data and microphone signals from a single-cylinder test engine using spark timingsbefore, at, and after knock onset for toluene reference fuels. The objective was to gain insight into the phenomena that determine knock onset, detected by an external microphone. In particular, the study examines how the end-gas autoignition process changes as the engine's spark timing is advanced through the borderline knock limit into the engine's knocking regime. Fast Fourier transforms (FFT) and bandpass filtering techniques were used to process the recorded cylinder pressure data to determine knock intensities for each cycle. Two characteristic pressure oscillation frequencies were detected: a peak just above 6 kHz and a range of peaks in the 15-22 kHz range. The microphone data shows that the audible knock signal has the same 6 kHz peak.

The prediction of knock onset in spark-ignition engines requires a chemical model for the autoignition of the hydrocarbon fuel-air mixture, and a description of the unburned end-gas thermal state. Previous studies have shown that a reduced chemistry model developed by Keck et al. adequately predicts the initiation of autoignition. However, the combined effects of heat transfer and compression on the state of the end gas have not been thoroughly investigated. The importance of end-gas heat transfer was studied with the objective of improving the ability of our knock model to predict knock onset over a wide range of engine conditions. This was achieved through changing the thermal environment of the end gas by either varying the inlet air temperature or the coolant temperature. Results show that there is significant heating of the in-cylinder charge during intake and a substantial part of the compression process.

Higher compression ratio and turbocharging, with engine downsizing can enable significant gains in fuel economy but require engine operating conditions that cause engine knock under high load. Engine knock can be avoided by supplying higher-octane fuel under such high load conditions. This study builds on previous MIT papers investigating Octane-On-Demand (OOD) to enable a higher efficiency, higher-boost higher compression-ratio engine. The high-octane fuel for OOD can be obtained through On-Board-Separation (OBS) of alcohol blended gasoline. Fuel from the primary fuel tank filled with commercially available gasoline that contains 10% by volume ethanol (E10) is separated by an organic membrane pervaporation process that produces a 30 to 90% ethanol fuel blend for use when high octane is needed. In addition to previous work, this paper combines modeling of the OBS system with passenger car and medium-duty truck fuel consumption and octane requirements for various driving cycles.

An experimental study was conducted on a spark-ignited direct-injection engine burning fuels with different evaporation and autoignition characteristics. The test engine was a single-cylinder Direct-Injection Stratified-Charge (DISC) engine incorporating a combustion process similar to the Texaco Controlled Combustion System. Two fuels were tested and compared with a baseline gasoline fuel: diesel fuel, and gasoline mixed with an ignition improver. The tests were done at low to medium engine loads. Diesel fuel was found to have similar levels of hydrocarbon (HC) emissions as gasoline but had different characteristics. The optimum timing for diesel fuel was retarded from that for gasoline and combustion variability was much less with diesel than with gasoline. Gasoline with a commercial ignition improver normally used to increase the cetane number of diesel fuel was also tested. The effect of changing the autoignition quality of the fuel depended on the injector used.

The Octane Index (OI) relates a fuel's knocking characteristics to a Primary Reference Fuel (PRF) that exhibits similar knocking characteristics at the same engine conditions. However, since the OI varies substantially with the engine operating conditions, it is typically measured at two standard conditions: the Research and Motor Octane Number (RON and MON) tests. These tests are intended to bracket the knock-limited operating range, and the OI is taken to be a weighted average of RON and MON: OI = K MON + (1-K) RON where K is the weighing factor. When the tests were established, K was approximately 0.5. However, recent tests with modern engines have found that K is now negative, indicating that the RON and MON tests no longer bracket the knock-limited operating conditions. Experiments were performed to measure the OI of different fuels in a modern engine to better understand the role of fuel sensitivity (RON-MON) on knock limits.

Since the advent of the spark ignition engine, the maximum engine efficiency has been knock limited. Knock is a phenomena caused by the rapid autoignition of fuel/air mixture (endgas) ahead of the flame front. The propensity of a fuel to autoignite corresponds to its autoignition chemistry at the local endgas temperature and pressure. Since a fuel blend consists of many components, its autoignition chemistry is very complex. The octane index (OI) simplifies this complex autoignition chemistry by comparing a fuel to a Primary Reference Fuel (PRF), a binary blend of iso-octane and n-heptane. As more iso-octane is added into the blend, the PRF is less likely to autoignite. The OI of a fuel is defined as the volumetric percentage of iso-octane in the PRF blend that exhibits similar knocking characteristics at the same engine conditions.