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It has been recently shown that (Ce, Zr)O2 mixed oxides provide improved catalytic performances compared to pure CeO2. Cerium oxide is the active Oxygen Storage Capacity (OSC) component in three way catalysts. However, higher performances, including OSC enhancement, can be achieved with thermally stable solid solutions of Ce and Zr oxides. In the present paper, we describe the structure and the advantages of Ce rich (Ce, Zr)O2 solid solutions and the improved catalytic properties of these materials when used in association with platinum. Various analytical techniques were used including thermo-reduction methods, OSC measurements, surface area measurements, XRD, HRTEM, XPS, and XANES/EXAFS.

The objectives of the present work are to investigate the regulated and unregulated (particle) emissions of a classical and modern 2-stroke and a typical 4-stroke scooter with different ethanol blend fuels. There is also comparison of two different ethanol fuels: pure ethanol (E) *) and hydrous ethanol (EH) which contains 3.9% water and is denatured with 1.5% gasoline. Special attention is paid in this research to the hydrous ethanol, since the production costs of hydrous ethanol are much less than those for (dry) ethanol. The vehicles are with carburettor and without catalyst, which represents the most frequent technology in Eastern Asia and offers the information of engine-out emissions. Exhaust emissions measurements have been performed with fuels containing ethanol (E), or hydrous ethanol (EH) in the portion of 5, 10, 15 and 20% by volume. During the test systematical analysis of particle mass (PM) and nano-particles counts (NP) were carried out.

A 10 KWe dual-mode space power system concept has been identified which is based on INEL's Small Externally-fueled Heat Pipe Thermionic Reactor (SEHPTR) concept. This power system will enhance user capabilities by providing reliable electric power and by providing two propulsion systems; electric power for an arc-jet electric propulsion system and direct thrust by heating hydrogen propellant inside the reactor. The low thrust electric thrusters allow efficient station keeping and long-term maneuvering. The direct thrust capability can provide tens of pounds of thrust at a specific impulse of around 730 seconds for maneuvers that must be performed more rapidly. The direct thrust allows the nuclear power system to move a payload from Low Earth Orbit (LEO) to Geosynchronous Earth Orbit (GEO) in less than one month using approximately half the propellant of a cryogenic chemical stage.

A gasoline Road Octane study was conducted by the Coordinating Research Council (CRC) to evaluate the effects of heavy aromatics (C9 and heavier) and ethanol content on Road Octane performance independent of Research Octane Number (RON) and Motor Octane Number (MON). Maximum-throttle and part-throttle Road ON’s were found to be well predicted by equations containing only RON and MON terms. Heavier aromatics were found to have a small adverse effect on both maximum-throttle and part-throttle Road ON independent of its direct effects on RON and MON. The all-car data did not show a significant ethanol-content effect, but eight of the thirty-seven cars did show significant effects for ethanol content.

In this work a detailed model to simulate the transient behavior of catalytic converters is presented. The model is able to predict the unsteady and reacting flows in the exhaust ducts, by solving the system of conservation equations of mass, momentum, energy and transport of reacting chemical species. The en-gine and the intake system have not been included in the simulation, imposing the measured values of mass flow, gas temperature and chemical composition as a boundary condition at the inlet of the exhaust system. A detailed analysis of the diffusion stage triggering is proposed along with simplifications of the physics, finalized to the reduction of the calculation time. Submodels for water condensation and its following evaporation on the monolith surface have been taken into account as well as oxygen storage promoted by ceria oxides.

This paper describes new 2 stroke fuel injected spark ignition outboard motor equipped with unique oxygen sensor feed back control system to assure constantly optimized air/fuel ratio. First, the general concept and the engineering target of commercial model are explained, and then the design and arrangement of oxygen sensor feedback fuel injection control system are described. Common automotive oxygen sensor is utilized in this system, and it is devised to overcome the problems inherent in 2-stroke engines. This paper also describes the controlled combustion system that enhances consistent and stable performance, and improves fuel efficiency. Applying these technologies, 40% less fuel consumption in cruise range was demonstrated by the comparative test with conventional fuel injected 2-stroke model.

Controlled Auto Ignition (CAI), also known as Homogeneous Charge Compression Ignition (HCCI), is one of the most promising combustion technologies to reduce the fuel consumption and NOx emissions. Currently, CAI combustion is constrained at part load operation conditions because of misfire at low load and knocking combustion at high load, and the lack of effective means to control the combustion process. Extending its operating range including high load boundary towards full load and low load boundary towards idle in order to allow the CAI engine to meet the demand of whole vehicle driving cycles, has become one of the key issues facing the industrialisation of CAI/HCCI technology. Furthermore, this combustion mode should be compatible with different fuels, and can switch back to conventional spark ignition operation when necessary. In this paper, the CAI operation is demonstrated on a 2-stroke gasoline direct injection (GDI) engine equipped with a poppet valve train.

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BlueStar Advanced Technology Corporation (BATC) as part of its participation in the USAF/NASA Li Ion Battery Development Consortium has developed a candidate 25-Ah cell for the Mars 2001 Lander. Although the capacity and cycle life requirements for this application are relatively modest, the low temperature performance (−20°C) and pulse discharge requirements (60A) are somewhat more challenging. Geometric requirements within the spacecraft also constrain the cell design leading to a cell with an aspect ratio quite different from those 25-Ah Li ion cells previously developed by BATC. The design of this cell and its compliance with the performance requirements of the mission will be discussed.

The fuel injection in internal combustion engines plays a crucial role in the mixture formation, combustion process and pollutants' emission. Its correct modeling is fundamental to the prediction of an engine performance through a computational fluid dynamics simulation. In the first part of this work a tridimensional numerical simulation of a multi-hole’s injector, using ethanol as fuel, is presented. The numerical simulation results were compared to experimental data from a fuel spray injection bench test in a quiescent vessel. The break up model applied to the simulation was the combined Kelvin-Helmholtz Rayleigh-Taylor, and a sensitivity analysis of the liquid fuel penetration curve, as well on the overall spray shape was performed according to the model constants. Experimental spray images were used to aid the model tuning. The final configuration of the KH-RT model constants that showed best agreement with the measured spray was C3 equal to 0.5, B1, 7 and Cb, 0.

This paper discusses five different methods for measuring the gas stream temperature from a burner using a hydrocarbon fuel, air, and oxygen. Tests were made with a single shielded BeO probe, a bare wire iridium -- 60% rhodium/iridium couple, a tantalum triple shielded platinum -- 10% rhodium/platinum thermocouple, the sodium line reversed technique, and a watercooled total enthalpy probe. The most serviceable system proved to be the bare wire iridium -- 60% rhodium/iridium couple, particularly for carrying out stream surveys where relative, rather than true temperatures, are of primary concern. More study is needed to establish a system for determining the true stream temperature.

Titanium alloy for forging and pure titanium material for exhaust systems have been developed. The forging alloy will be applied to production of lightweight motorcycle frames and the pure titanium will be applied to improve engine performance. The materials have been made inexpensive by the use of off-grade sponge that includes many impurities for production of titanium ingot. Stable characteristics have been obtained by controlling oxygen equivalent after setting the volume of tolerable impurities by considering mechanical properties and production engineering. In spite of low-cost, the material provides the same design strength compared to conventional material, and enables parts production with existing equipment. A review of manufacturing and surface treatment processes indicated a reduction in the price of titanium parts produced with this new material.

As a part of a program jointly supported by the USAF and Canada's Department of National Defense, BlueStar is developing large (50 to 100-Ah)lithium ion cells for aircraft and spacecraft applications. Presently, 20-Ah cells are being developed as the first stage of the scale-up process and the design of these cells involves several tradeoffs related to the specific nature of this application. This paper will present the design of this first generation cell in the context of these tradeoffs as well as presenting the results of the performance and life testing of these cells.

The experimental procedure employed to define the natural modes of vibration of the 747 Shuttle Carrier Aircraft and Space Shuttle Orbiter mated configuration is described. A discussion of test results and comparison to structural analysis results is also included. Random transient signals were used as inputs to electromagnetic shakers to provide excitation to the mated vehicle test configuration. Acceleration signals were processed via the Fast Fourier Transform algorithm. Magnitude and phase transfer functions were formed and processed to produce modal frequencies, damping, and modal displacements.

In 1995, the Naval Research Laboratory (NRL) began a program to investigate whether a 90 Ah dependent pressure vessel (DPV) NiH2 battery pack could be a lower volume replacement for a 90 Ah NiH2 IPV spacecraft battery. Nickel Hydrogen (NiH2) dependent pressure vessel (DPV) battery cells are presumed to offer all the features of the NiH2 IPV battery cell with considerably less volume. To achieve this reduction in volume, the DPV cell utilizes a canteen shaped pressure vessel with reduced thickness wall, flat sides and curved ends. The cells can be packaged similar to prismatic nickel cadmium battery cells. Moreover, like NiCd cells, a fully charged DPV cell must rely upon an adjacent battery cell or structure for support and to maintain pressure vessel integrity. Seventeen 90 Ah NiH2 DPV cells were delivered to NR in 1998 for qualification tests. An eleven-cell half battery pack was manufactured and tested to validate the advantages of the DPV design.

In the course of CRYOSYSTEM phase B (development phase) financed by the European Space Agency, AIR LIQUIDE (France) and Astrium Space Infrastructure (Germany) have developed an optimized design of a −183°C freezer to be used on board the International Space Station for the freezing and storage of biological samples. The CRYOSYSTEM facility consists of the following main elements: - the CRYORACK, an outfitted standard payload rack (ISPR) accommodating up to three identical Vial Freezers - the Vial Freezer, a dewar vessel capable of fast and ultra-rapid freezing, and storing up to approximately 900 vials below −183°C; the dewar is cooled by a Stirling machine producing > 6 W at 90 K. The Vial Freezer is operational while accommodated in the CRYORACK or attached to the Life Science Glovebox (LSG). One CRYORACK will remain permanently on-orbit for several years while four Vial Freezers and two additional CRYORACKs support the cyclic upload/download of samples.

In the frame of the CRYOSYSTEM A-phase study financed by the European Space Agency, AIR LIQUIDE (France) and ORBITAL HYDRAULIC-BREMEN (Germany) have been studying a -183°C freezer to be used on-board the International Space Station for freezing and storing biological samples.