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One of the most critical elements in engineering a hydrogen fuel cell vehicle is the design of the on-board hydrogen storage system. Because the current compressed-gas hydrogen storage technology has several key challenges, including cost, volume and capacity, materials-based storage technologies are being evaluated as an alternative approach. These materials-based hydrogen storage technologies include metal hydrides, chemical hydrides, and adsorbent materials, all of which have drawbacks of their own. To optimize the engineering of storage systems based on these materials, it is critical to understand the impacts these systems will have on the overall vehicle system performance and what trade-offs between the hydrogen storage systems and the vehicle systems might exist that allow these alternative storage approaches to be viable.

With the introduction of more fuel cell electric vehicles (FCEVs) on U.S. roadways, especially in California, the need for available hydrogen refueling stations is growing. While funding from the California Energy Commission is helping to solve this problem, solutions need to be developed and implemented to help reduce the time to commission a hydrogen station. The current practice of hydrogen station acceptance can take months because each vehicle manufacturer conducts their own testing and evaluation. This process is not practical or sufficient to support the timely development of a hydrogen fueling station network. To address this issue, as part of the Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) Project Sandia National Laboratories and the National Renewable Energy Laboratory along with a team of stakeholders and contractor Powertech Labs has developed the Hydrogen Station Equipment Performance (HyStEP) Device.

Biodiesel (i.e., mono-alkyl esters of long chain fatty acids derived from vegetable oils and animal fats) is a renewable diesel fuel providing life-cycle greenhouse gas emission reductions relative to petroleum-derived diesel. With the expectation that there would be widespread use of biodiesel as a substitute for ultra-low sulfur diesel (ULSD), there have been many studies looking into the effects of biodiesel on engine and aftertreatment, particularly its compatibility to the current aftertreatment technologies. The objective of this study was to generate experimental data to measure the effectiveness of a current technology diesel oxidation catalysts (DOC) to oxidize soy-based biodiesel at various blend levels with ULSD. Biodiesel blends from 0 to 100% were evaluated on an engine using a conventional DOC.

The project objective was to generate experimental data to evaluate the impact of metals doped B20 on DPF ash loading and performance compared to that of conventional petrodiesel. Accelerated ash loading was conducted on two DPFs – one exposed to regular diesel fuel and the other to B20 containing metal dopants equivalent to 4 ppm B100 total metals (currently total metals are limited to 10 ppm in ASTM D6751, the standard for B100). Periodic performance evaluations were conducted on the DPFs at 10 g/L ash loading intervals. After the evaluations at 30 g/L, the DPF was cleaned with a commercial DPF cleaning machine and another round of DPF evaluations were conducted. A comparison of the effect of ash loading with the two fuels and DPF cleaning is presented. The metals doped B20 fuel resulted in ash that was similar to that deposited when exposed to ULSD (lube oil ash) and exhibited similar ash cleaning removal efficiency.

This project’s objective was to generate experimental data to evaluate the impact of metals doped B20 on diesel particle filter (DPF) ash loading and performance compared to that of conventional petrodiesel. The effect of metals doped B20 vs. conventional diesel on a DPF was quantified in a laboratory controlled accelerated ash loading study. The ash loading was conducted on two DPFs – one using ULSD fuel and the other on B20 containing metals dopants equivalent to 4 ppm B100 total metals. Engine oil consumption and B20 metals levels were accelerated by a factor of 5, with DPFs loaded to 30 g/L of ash. Details of the ash loading experiment and on-engine DPF performance evaluations are presented in the companion paper (Part I). The DPFs were cleaned, and ash samples were taken from the cleaned material. X-ray Fluorescence (XRF), X-Ray Photoelectron Spectroscopy (XPS) and X-Ray Diffraction (XRD) were conducted on the ash samples.

Emissions of six 32 passenger transit buses were characterized using one of the West Virginia University (WVU) Transportable Heavy Duty Emissions Testing Laboratories, and the fixed base chassis dynamometer at the Colorado Institute for Fuels and High Altitude Engine Research (CIFER). Three of the buses were powered with 1997 ISB 5.9 liter Cummins diesel engines, and three were powered with the 1997 5.9 liter Cummins natural gas (NG) counterpart. The NG engines were LEV certified. Objectives were to contrast the emissions performance of the diesel and NG units, and to compare results from the two laboratories. Both laboratories found that oxides of nitrogen and particulate matter (PM) emissions were substantially lower for the natural gas buses than for the diesel buses. It was observed that by varying the rapidity of pedal movement during accelerations in the Central Business District cycle (CBD), CO and PM emissions from the diesel buses could be varied by a factor of three or more.

We have designed and tested a prototype dish/Stirling hybrid-receiver combustion system. The system consists of a pre-mixed natural-gas burner heating a pin-finned sodium heat pipe. The design emphasizes simplicity, low cost, and ruggedness. Our test was on a 1/6th-scale device, with a nominal firing rate of 18kWt, a power throughput of 13kWt, and a sodium vapor temperature of 750°C. The air/fuel mixture was electrically preheated to 640°C to simulate recuperation. The test rig was instrumented for temperatures, pressures, flow rates, overall leak rate, and exhaust emissions. The data verify our burner and heat-transfer models. Performance and post-test examinations validate our choice of materials and fabrication methods. Based on the 1/6th -scale results, we are designing a full-scale hybrid receiver.

In some studies, a relationship has been observed between increasing ethanol content in gasoline and increased particulate matter (PM) emissions from vehicles equipped with spark ignition engines. The fundamental cause of the PM increase seen for moderate ethanol concentrations is not well understood. Ethanol features a greater heat of vaporization (HOV) than gasoline and also influences vaporization by altering the liquid and vapor composition throughout the distillation process. A droplet vaporization model was developed to explore ethanol’s effect on the evaporation of aromatic compounds known to be PM precursors. The evolving droplet composition is modeled as a distillation process, with non-ideal interactions between oxygenates and hydrocarbons accounted for using UNIFAC group contribution theory. Predicted composition and distillation curves were validated by experiments.

Plug-in hybrid electric vehicle (PHEV) technology may reduce fuel consumption and tailpipe emissions in many medium- and heavy-duty vehicle vocations, including school buses. The true magnitude of these reductions is best assessed by comparative testing over relevant drive cycles. The National Renewable Energy Laboratory (NREL) collected and analyzed real-world school bus drive cycle data, and selected similar standard drive cycles for testing on a chassis dynamometer. NREL tested a first-generation PHEV school bus equipped with a 6.4 L engine and an Enova PHEV drive system comprising a 25-kW/80 kW (continuous/peak) motor and a 370-volt lithium ion battery pack. For a baseline comparison, a Bluebird 7.2 L conventional school bus was also tested. Both vehicles were tested over three different drive cycles to capture a range of driving activity.

Four metrics related to vehicle duty cycle are derived from the energy equation of vehicle motion. Three key application areas are introduced. The first is the ability to quantify the sameness between vehicle duty cycles and the ability to asses a duty cycle's suitability for hybrid vehicle usage. The second area of application allows for the estimation of fuel consumption for a given vehicle over a target duty cycle. The third area of application allows us to predict how non-propulsion fuel use will affect energy use. The paper ends with real-world examples involving actual heavy-duty hybrids.

ARCO has developed diesel fuel called Emission Control Diesel (EC-D) that results in substantially lower exhaust emissions compared to a typical California diesel fuel. EC-D has ultra-low sulfur content, low aromatics, and has a high cetane number. EC-D is produced from typical crude oil using a conventional refining process. Initial engine laboratory tests and vehicle tests indicated that EC-D reduced regulated emissions while maintaining fuel economy, compared to a typical California diesel fuel. Ultra-low sulfur diesel fuels such as EC-D may enable the widespread use of passive catalyzed particulate filters for both new and existing diesel engines. The use of catalyzed particulate filters could allow large reductions of particulate matter emitted from vehicles. A one-year technology validation program is being run to evaluate EC-D and catalyzed particulate filters using diesel vehicles operating in Southern California.

In collaboration with the U.S. Environmental Protection Agency and the U.S. Department of Energy, the National Renewable Energy Laboratory has conducted a national analysis of road grade characteristics experienced by U.S. medium- and heavy-duty trucks on controlled access highways. These characteristics have been developed using TomTom’s commercially available street map and road grade database. Using the TomTom national road grade database, national statistics on road grade and hill distances were generated for the U.S. network of controlled access highways. These statistical distributions were then weighted using data provided by the U.S. Environmental Protection Agency for activity of medium- and heavy-duty trucks on controlled access highways. The national activity-weighted road grade and hill distance distributions were then used as targets for development of a handful of sample grade profiles potentially to be used in the U.S.

Small impurities in the fuel can have a significant impact on the emissions control system performance over the lifetime of the vehicle. Of particular interest in recent studies has been the impact of sodium, potassium, and calcium that can be introduced either through fuel constituents, such as biodiesel, or as lubricant additives. In a collaboration between the National Renewable Energy Laboratory and the Oak Ridge National Laboratory, a series of accelerated aging studies have been performed to understand the potential impact of these metals on the emissions control system. This paper explores the effect of the rate of accelerated aging on the capture of fuel-borne metal impurities in the emission control devices and the subsequent impact on performance. Aging was accelerated by doping the fuel with high levels of the metals of interest. Three separate evaluations were performed, each with a different rate of accelerated aging.

The objective of this research project was to compare the emissions of oxides of nitrogen (NOx) from transit buses on as many as five different fuels and three standard transit duty cycles to establish if there is a real-world biodiesel NOx increase for transit bus duty cycles and engine calibrations. Prior studies have shown that B20 can cause a small but significant increase in NOx emissions for some engines and duty cycles. Six buses spanning engine build years 1998 to 2011 were tested on the National Renewable Energy Laboratory's Renewable Fuels and Lubricants research laboratory's heavy-duty chassis dynamometer with certification diesel, certification B20 blend, low aromatic [California Air Resources Board (CARB)] diesel, low aromatic B20 blend, and B100 fuels over the Manhattan, Orange County and UDDS test cycles.

Tests of ultra-low sulfur diesel blended with soy-biodiesel at 5% and 20% were conducted using a 2002 model year Cummins ISB engine (with exhaust gas recirculation) that had been retrofitted with a passively regenerated catalyzed diesel particulate filter (DPF). Results show that on average, the DPF balance point temperature (BPT) is 45°C and 112°C lower for B20 blends and neat biodiesel, respectively, than for 2007 certification diesel fuel. Biodiesel causes a measurable increase in regeneration rate at a fixed steady-state condition, even at the 5% blending level. The data show no significant differences in NOx emissions for these fuels at the steady-state regeneration conditions, suggesting that differences in soot reactivity are responsible for the observed differences in BPT and regeneration rate.

Testing to investigate biodiesel's impact on the performance of a zeolite-based selective catalytic reduction (SCR) system was conducted. The tests employed a 2004 compliant Cummins ISB with common rail fuel injection, EGR, and variable geometry turbo. This 5.9L, 300HP engine was retrofitted with a Johnson-Matthey DPF + SCR (SCRT™) system. Testing was conducted over eight steady-state engine operating modes which provided a wide range of exhaust temperature and exhaust chemistry conditions. Fuels tested were a 2007 certification quality ultra-low sulfur diesel (ULSD), as well as a soy derived biodiesel in a B20 blend. B20 produced slightly lower catalyst temperatures and higher NO2:NOx ratios relative to ULSD, but no measureable difference in the overall NOx conversion over the SCR system. The dominant variable influencing SCR performance is the catalyst space velocity, which is unchanged with the use of B20.

This research project evaluates fuel consumption results of two Class 8 tractor-trailer combinations platooned together compared to their standalone fuel consumption. A series of ten modified SAE Type II J1321 fuel consumption track tests were performed to document fuel consumption of two platooned vehicles and a control vehicle at varying steady-state speeds, following distances, and gross vehicle weights (GVWs). The steady-state speeds ranged from 55 mph to 70 mph, the following distances ranged from a 20-ft following distance to a 75-ft following distance, and the GVWs were 65K lbs and 80K lbs. All tractors involved had U.S. Environmental Protection Agency (EPA) SmartWay-compliant aerodynamics packages installed, and the trailers were equipped with side skirts. Effects of vehicle speed, following distance, and GVW on fuel consumption were observed and analyzed.

The energy used to air condition an automobile has a significant effect on vehicle fuel economy and tailpipe emissions. If a small reduction in energy use can be applied to many vehicles, the impact on national fuel consumption could be significant. The SCO3 is a new emissions test conducted with the air conditioner (A/C) operating that is part of the Supplemental Federal Test Procedure (SFTP). With the 100% phase-in of the SFTP in 2004 for passenger cars and light light-duty trucks, there is additional motivation to reduce the size of the A/C system. The U.S. Department of Energy's National Renewable Energy Laboratory (NREL) is investigating ways to reduce the amount of energy consumed for automobile climate control. If the peak soak temperature in an automobile can be reduced, the power consumed by the air conditioner may be decreased while passenger comfort is maintained or enhanced. Solar reflective glass is one way to reduce the peak soak temperature.

Engine and flow reactor experiments were conducted to determine the impact of biodiesel relative to ultra-low-sulfur diesel (ULSD) on inhibition of the selective catalytic reduction (SCR) reaction over an Fe-zeolite catalyst. Fe-zeolite SCR catalysts have the ability to adsorb and store unburned hydrocarbons (HC) at temperatures below 300°C. These stored HCs inhibit or block NOx-ammonia reaction sites at low temperatures. Although biodiesel is not a hydrocarbon, similar effects are anticipated for unburned biodiesel and its organic combustion products. Flow reactor experiments indicate that in the absence of exposure to HC or B100, NOx conversion begins at between 100° and 200°C. When exposure to unburned fuel occurs at higher temperatures (250°-400°C), the catalyst is able to adsorb a greater mass of biodiesel than of ULSD. Experiments show that when the catalyst is masked with ULSD, NOx conversion is inhibited until it is heated to 400°C.

Chassis based emissions characterization of heavy-duty vehicles has advanced over the last decade, but the understanding of the effect of test schedule on measured emissions is still poor. However, this is an important issue because the test schedule should closely mimic actual vehicle operation or vocation. A wide variety of test schedules was reviewed and these cycles were classified as cycles or routes and as geometric or realistic. With support from the U.S. Department of Energy Office of Transportation Technologies (DOE/OTT), a GMC box truck with a Caterpillar 3116 engine and a Peterbilt over the road tractor-trailer with a Caterpillar 3406 engine were exercised through a large number of cycles and routes. Test weight for the GMC was 9,980 kg and for the Peterbilt was 19,050 kg. Emissions characterization was performed using a heavy-duty chassis dynamometer, with a full-scale dilution tunnel, analyzers for gaseous emissions, and filters for PM emissions.