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Polylactide (PLA), which is one of the most important biocompatible polyesters that are derived from annually renewable biomass such as corn and sugar beets, has attracted much attention for automotive parts application. The manufacturing method of PLA is the ring-opening polymerization of the dimeric cyclic ester of lactic acid, lactide. For the PLA composites including stereocomplexed with L- and D-PLA, we developed the unit processes such as fermentation, separation, lactide conversion, and polymerization. We investigated D-lactic acid fermentation with a view to obtaining the strains capable of producing D-lactic acid, and through catalyst screening test for polycondensation and depolymerization reactions, we got a new method which shortens the whole reaction time of lactide synthesis step. Poly(d-lactide) is obtained from the ring-opening polymerization of d-lactide. Also we investigated several catalysts and polymerization conditions.

This paper describes how to meet LEVII ULEV70 emission standards and minimize fuel consumption with the combined NOx after-treatment (LNT+SCR) system for diesel vehicles. Through analysis of LNT's functionality and characteristics in a LNT+SCR combined after-treatment system, allowed a new control strategy to be established, different from the existing LNT-only system. In the 200°C or higher condition where SCR can provide the most stable NOx conversion efficiency, rich regeneration of LNT was optimized to minimize LNT deterioration and fuel consumption. Optimized mapping between rapid heat up strategy and raw NOx reduction maximized LNT's NOx conversion efficiency during the intervals when it is not possible for SCR to purify NOx This study used bench aged catalysts which were equivalent to 150K full useful life.

The Eco-driving indicator is a colored lamp on a cluster to lead a driver to smoothen acceleration of a vehicle. Informed by the indicator, a driver learns how deep to push a gas pedal for a better fuel economy. The Eco-driving guide system outputs a vehicle fuel efficient state by the Eco-driving indicator. It is based on BSFC map, engine torque map, A/T shift pattern data, engine operation status and transmission operating status. With the Eco-driving guide system, vehicle fuel efficiency can be improved by 4∼26%.

A technical approach to reduce NOx and to minimize the fuel consumption caused by the DeNOx aftertreatment system was introduced. The NEDC mode test of the HMC (Hyundai Motor Company) DeNOx system was done with a Euro 5 vehicle (ETW (Equivalent Test Weight) = 1,810 kg, 143 kW, 430 N⋅m), which resulted in that the Euro 6 legislation standards were met. The NOx and HC emissions were, respectively, measured to be 0.059 g/km and 0.087 g/km with the hydrothermal-aged catalysts, and CO₂ was increased by ≺ 4%.

A new exhaust system has been developed to cope with post-SULEV (Super Ultra-Low Emissions Vehicle) regulation by newly designed hardware of exhaust system. This paper will describe the various new technologies used for achieving the post-SULEV standards, such as Conicat (cone-type metal catalyst), dual-wall pipe, pipe-type metal catalyst, ultra thin wall monolith and HC trap system for the improvement of catalyst light-off time. The tested data on 2.0L SULEV vehicle indicate that Conicat(cone-type metal catalyst) and HC trap (hydrocarbon absorbing catalyst) have more positive characteristics, and are expected to show the enhanced HC reduction performance with the optimization of emission system.

Urea-SCR system consisted of combined deNOx catalysts with wide range of temperature window, injector, sensor and injection controller. Synthetic gas activity test and NOx conversion efficiency test on the engine bench were carried out to evaluate and improve the performance of this system. To better suit the application of the urea-SCR system without engine modification, temperature of catalyst and engine RPM were used as input data to control amounts of urea aqueous solution that reacts with NOx. We concentrated on designing types of deNOx catalysts and controlling amounts of urea solution under different driving conditions to achieve higher NOx reduction and wider temperature window. Designed urea-SCR system showed substantial NOx reduction performance and relatively wide temperature window under different driving conditions.

Emission of carbon dioxide from mobile sources seriously concerned to solve greenhouse effect and high price of gasoline in some countries have resulted in the development of lean-burn concept engine. In spite of many studies on the lean deNOx catalyst, we have no clear solution to obtain high fuel economy and high efficiency of NOx conversion in lean-burn application. This paper describes applicability and problems of NOx adsorber system to partial lean-burn vehicle, the development of three-way catalyst with improvement of washcoat technology based on three-way catalyst used for gasoline application, and comparison test results of evaluations is synthesized gas activity test, Federal Test Procedure (FTP) test, etc. This study shows improved three-way catalysts in partial lean- burn vehicle have max. 89% of NOx conversion in FTP without adding rich spike and regeneration functions to engine management system.

This study suggests new types of catalysts that show low hydrogen sulfide emission without scavenger such as NiO. Hydrogen sulfide can be reduced by changing the physicochemical properties of washcoat components. Synthesized gas activity tests were performed to investigate the effect of modified washcoat on hydrogen sulfide formation and catalytic activity. BET surface area tests, X- ray diffraction tests, and gas chromatography tests were also carried out to examine the characteristics of catalysts. Preparation methods for catalysts were focused on minimizing the adsorption of sulfur species on catalysts. The first approach is heat treatment of cerium oxide to reduce adsorption sites for sulfur compounds. But this leads to deterioration of CO and NOx conversion efficiencies. The second one is adding new types of promoters that increase thermal durability and dynamic oxygen storing function of cerium oxide.

This paper describes the development of THC reduction technologies compliant with SULEV regulations. Technologies embodied by the developmental work include improvement of fuel spay atomization, quick warm-up through coolant control shut off, and acceleration of fuel atomization for the fast rise of cylinder head temp inside the water jacket as well as the improvement of combustion state. The technologies likewise entail reduced HC while operating in lean A/F condition during engine warm-up with the cold lean-burn technology, individual cylinder A/F control for improvement of catalytic converting efficiency, aftertreatment such as thin-wall catalyst, HC absorber and EHC and etc., through vehicle application evaluation in cold start. We carried out an experimental as well as a practical study against SULEV regulations, and the feasibility of adopting these items in vehicle was likewise investigated.

The new concept oxidation for diesel engine has been developed. It has been designed to use under circumstances of the "dry condition" of exhausted emission, which indicates low soluble organics and high dry soot concentration under high exhaust gas temperature. For the reliability and performance of catalysts in dry condition, several design concepts were established. First of all, extremely low sulfate formation on catalyst at high temperature conditions, and an improved soluble organic burning characteristics was required. A minimization of deposition of the particulate component, especially sulfate, was obtained from the adjustment of washcoat loading and material property. Six different types of catalysts have been prepared and tested in a laboratory. Diesel vehicle test showed the possibility that soluble organic could be removed mostly with minimal sulfate formation.

The shape of unit cell of catalytic converter has great influence on the conversion efficiency and pressure drop characteristics. Therefore, the properties of design parameters of catalyst monolith were analyzed and the parameters of various cell shapes of catalyst were compared. Also, the numerical study of a three dimensional compressible flow in a Close-coupled Catalyst Converter (CCC) system was performed to investigate the flow characteristics and the flow distribution of exhaust gases. Unsteady flow analysis shows that severe interferences of each pulsating exhaust gas flow as well as geometric factors (junction, mixing pipe, cell shape etc.) influence greatly on the flow uniformity and flow characteristic in substrate. The results can be applied for the catalytic converter design.

The theory and the computer software to analyze the behaviour of moving mechanism(Hood, Tail Gate and Trunk Lid) equiped with the gas lifters or the torsion bars has been developed to figure out what will be the dynamic behaviour of moving mechanism at the design stage. The developed computer software gives the approximated calculation of load-angle characteristics, the velocity, the acceleration and the total opening time so that the designer makes the optimum decision on the location and the strength of panel to which the gas lifters or the torsion bars are mounted.