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In this work, a quasi-dimensional, multi-zone combustion model is analytically presented, for the prediction of performance and nitric oxide (NO) emissions of a homogeneous charge spark ignition (SI) engine, fueled with biogas-H2 blends of variable composition. The combustion model is incorporated into a closed cycle simulation code, which is also fully described. Combustion is modeled on the basis of turbulent entrainment theory and flame stretch concepts. In this context, the entrainment speed, by which unburned gas enters the flame region, is simulated by the turbulent burning velocity of a flamelet model. A flame stretch submodel is also included, in order to assess the flame response on the combined effects of curvature, turbulent strain and nonunity Lewis number mixture. As far as the burned gas is concerned, this is treated using a multi-zone thermodynamic formulation, to account for the spatial distribution of temperature and NO concentration inside the burned volume.

In this paper, the results are presented from the analysis of the second stage of an experimental investigation with the aim to provide insight to the cyclic, instantaneous heat transfer phenomena occurring in both the cylinder head and exhaust manifold wall surfaces of a direct injection (DI), air-cooled diesel engine. Results from the first stage of the investigation concerning steady-state engine operation have already been presented by the authors in this series. In this second stage, the mechanism of cyclic heat transfer was investigated during engine transient events, viz. after a sudden change in engine speed and/or load, both for the combustion chamber and exhaust manifold surfaces. The modified experimental installation allowed both long- and short-term signal types to be recorded on a common time reference base during the transient event.

An experimental analysis is carried out to investigate several heat transfer characteristics during the engine cycle, in the combustion chamber and exhaust manifold walls of a direct injection (DI), air-cooled, diesel engine. For this purpose, a novel experimental installation has been developed, which separates the engine transient temperature signals into two groups, namely the long-and the short- term response ones, processing the respective signals in two independent data acquisition systems. Furthermore, a new pre-amplification unit for fast response thermocouples, appropriate heat flux sensors and an innovative, object-oriented, control code for fast data acquisition have been designed and applied. Experimentally obtained cylinder pressure diagrams together with semi-empirical equations for instantaneous heat transfer were used as basis for the calculation of overall heat transfer coefficient.

Despite the improvement in HD Diesel engine out emissions future emission legislation requires significant reduction of both NOx and particulate matter. To accomplish this task various solutions exist involving both internal and external measures. As widely recognized, it will be possibly required to employ both types of measures to meet future emission limits. Towards this direction, it is necessary to reduce NOx further using internal measures. Several solutions exist in that area, but the most feasible ones according to the present status of technical knowledge are EGR, water injection or fuel/water emulsions. These technologies aim to the reduction of both the gas temperature and oxygen concentration inside the combustion chamber that strongly affect NOx formation. However, there remain open points mainly concerning the effectiveness of water addition techniques and penalties related to bsfc and soot emissions.

A heat release analysis of experimental pressure diagrams, appropriate for indirect injection (divided chamber) diesel engines, is developed and used to obtain heat release rate profiles during the combustion process in each combustion chamber. Attention is paid to the correct processing of the data, due to the inherent complexity of the mass interchange between the two combustion chambers. The analysis concerns a turbocharged, indirect injection diesel engine, having a very small pre-chamber and a very narrow connecting passageway, operated at various load and speed conditions, located at the authors' laboratory. An extended experimental work, at steady-state conditions, is conducted on a specially developed test bed configuration of this engine, which is connected to a high-speed data acquisition and processing system.

The model has already been applied on an old technology, naturally aspirated HSDI Diesel engine and on a heavy-duty turbocharged DI one equipped with a high pressure PLN fuel injection system, and the results were satisfying as far as performance and pollutant emissions (Soot and NO) are concerned. Taking into account that the main scope of engine simulation models is to assist engineers and researchers to understand the complex mechanisms involved in diesel engine combustion and pollutants formation and that through the continues engine development, new techniques are implemented, it is obvious that engine simulation models must always be enhanced with new features in order to be kept up-to-date. In this study the model has been modified to take into account the effect of EGR, since the latter one is a measure that will be used more extensively in the future to control NO emissions from turbocharged HDDI Diesel engines.

In the present work, a multi-zone model is presented for the simulation of HCCI engines. This model is an improvement of a previous one developed by the authors. The present model describes the combustion, heat and mass transfer processes for the closed part of the engine cycle, i.e. compression, combustion and expansion. The zones occupy geometrical positions within the engine cylinder and exchange heat and mass throughout the compression and expansion strokes, based on their spatial configuration. Heat exchange is considered between zones and to the cylinder wall. A phenomenological model has been developed to describe mass exchange between zones and the flow of a portion of the in-cylinder mixture in and out of the crevice region. The crevice flow is a new feature and is included in the present model since the crevice regions are considered to contribute to unburned HC emissions. Another new feature is the incorporation of chemical kinetics, based on combustion chemistry reactions.

Simulation models are widely used from research engineers to investigate the combustion mechanism of DI diesel engines. These models can be used, as tools to either comprehend information provided by experimental data or to perform predictions and assist the development process. As widely recognized a valuable source of information for engine performance and emissions studies is the cylinder pressure trace. It can provide after processing information concerning the combustion rate of fuel injected inside the combustion chamber. Often it is also used to calibrate simulation models or even to derive correlations to represent the combustion rate of fuel inside the combustion chamber. The present research team has during the development process of a simulation model for the description of DI diesel engine performance and emissions realized that there exists a serious problem.

The current work uses a method developed by the authors for both combustion irreversibility and working medium availability computations in a high speed, naturally aspirated, four stroke, internal combustion engine cylinder. The objective of the study was to extrapolate already published results of the second-law analysis of diesel engine operation by studying parametrically the effect of main operating parameters such as engine speed of rotation, injection timing, and fuel composition. Extensive experimental data were available for the case of dodecane injection, which were used for the determination of the fuel reaction rate. Computationally, the same reaction rates were used for methane and methanol injection. The production rate of irreversibility during combustion was analytically calculated as a function of the fuel reaction rate with the combined use of first and second-law arguments and a chemical equilibrium hypothesis.

A great deal of research is taking place at the present time in the field of diesel engines, especially regarding the emission of gaseous pollutants and soot. This research is essential for engine manufacturers since it is difficult for diesel engines to meet current standards regarding soot and nitric oxide emissions. The problem will become even more severe when the new legislation will be applicable requiring a 50% reduction of existing levels. Many manufacturers and researchers feel that engines will be difficult to meet this criterion without the use of other techniques such as gas aftertreatment or newly developed fuels (low sulfur content, etc.). The aim of this research is to examine the effect of fuel composition and physical properties on the mechanism of combustion and pollutants formation.