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Technical Paper

Stress Generation in Large Pouch Cells Under Cycling and Abuse Conditions

2024-04-09
2024-01-2196
Pouch cells are increasingly popular form factors for the construction of energy storage systems in electric vehicles of all classes. Knowledge of the stress generated by these higher capacity pouch cells is critical to properly design battery modules and packs for both normal and abnormal operation. Existing literature predominantly offers data on smaller pouch cells with capacities of less than 10 Ah, leaving a gap in our understanding of the behavior of these larger cells. This experimental study aimed to bridge this knowledge gap by measuring loads and stresses in constrained 65 Ah pouch cells under both cycling and abuse conditions. To capture the desired responses, a load cell was located within a robust fixture to measure cell stress in real time after the application of a preload of approximately 30 kilograms or 294 N, equivalent to a pressure of 0.063 bar, with a fixed displacement.
Technical Paper

Analysis of overcharge tolerance of aged LMO cells with Examples

2023-09-29
2023-32-0108
The capacity of a lithium-ion battery decreases during cycling. This capacity loss or fade occurs due to several different mechanisms associated with unwanted side reactions that occur in these batteries. The same reactions occur during overcharge and cause electrolyte decomposition, passive film formation, active material dissolution, and other phenomena. As the battery ages the accuracy of state of charge prediction decreases and vulnerability to persistent overcharge increases. Moreover, as the battery ages, its tolerance to such unintended overcharge changes. This tolerance depends on the nature of the history of cycle and calendar aging. A map of this tolerance in the BMS can provide awareness of the factor of safety due to overcharge as battery ages. Signatures of early warning signs of incipient thermal runaway due to overcharge can also be very useful features in a BMS.
Journal Article

A One-Way Coupled Modeling Method to Simulate Battery Pack Thermal Runaway Initiated by an External Impact

2023-04-11
2023-01-0593
There is an ongoing proliferation of electric and electrified vehicles as manufacturers seek to reduce their carbon footprint and meet the carbon reduction targets mandated by governments around the world. An ongoing challenge in electric vehicle design is the efficient and safe design of battery packs. There are significant safety challenges for lithium battery packs relating to thermal runaway, which can be initiated through overheating and internal short from defects or external damage. This work proposes a robust method to couple the mechanical damage in a battery module calculated from a dynamic model with a thermal model of the battery that includes heating from electro-chemical sources as well as Arrhenius reactions from the battery cells. The authors identify the main sources of thermal runaway initiation and propagation in an impact scenario simulating a vehicle collision. The modeling approach was developed and validated using test data.
Technical Paper

Comparison of Representative Wet and Dry Fire Suppressants to Retard Fire Propagation in Lithium-Ion Modules Initiated by Overcharge Abuse

2023-04-11
2023-01-0520
Overcharging lithium-ion batteries is a failure mode that is observed if the battery management system (BMS) or battery charger fails to stop the charging process as intended. Overcharging can easily lead to thermal runaway in a battery. In this paper, nickel manganese cobalt (NMC) battery modules from the Chevrolet Bolt, lithium manganese oxide (LMO) battery modules from the Chevrolet Volt, and lithium iron phosphate (LFP) battery modules from a hybrid transit bus were overcharged. The battery abuse and emissions tests were designed to intentionally drive the three different battery chemistries into thermal runaway while measuring battery temperatures, battery voltages, gaseous emissions, and feedback from volatile organic compound (VOC) sensors. Overcharging a battery can cause lithium plating and other exothermic reactions that will lead to thermal runaway.
Journal Article

A Comparative Study of Lithium-Ion Cathode Chemistry Correlations with Emissions Initiated by Nail Penetration Abuse in the Presence of an Immersive Coolant

2022-03-29
2022-01-0707
Internal short-circuit in cells/batteries is a phenomenon where there is direct electrical contact between the positive and negative electrodes leading to thermal runaway. The nail penetration tests were used to simulate an internal short circuit within the battery, where a conductive nail was used to pierce the battery cell separator membrane which provided direct electrical contact between the positive and negative electrodes. The batteries tested during this work were common batteries used in existing automotive applications, and they included a nickel manganese cobalt (NMC) battery from a Chevrolet Bolt, a lithium manganese oxide (LMO) battery from a Chevrolet Volt, and a lithium iron phosphate (LFP) battery in a hybrid transit bus. The battery abuse and emissions tests were designed to intentionally drive the three different battery chemistries into thermal runaway while measuring battery temperatures, battery voltages and gaseous emissions.
Journal Article

A Comparative Study of Lithium-Ion Cathode Chemistry Correlations with Emissions Initiated by Nail Penetration Abuse in the Presence of an Immersive Coolant

2022-03-29
2022-01-0715
Internal short-circuit in cells/batteries is a phenomenon where there is direct electrical contact between the positive and negative electrodes leading to thermal runaway. The nail penetration tests were used to simulate an internal short circuit within the battery, where a conductive nail was used to pierce the battery cell separator membrane which provided direct electrical contact between the positive and negative electrodes. The batteries tested during this work were common batteries used in existing automotive applications, and they included a nickel manganese cobalt (NMC) battery from a Chevrolet Bolt, a lithium manganese oxide (LMO) battery from a Chevrolet Volt, and a lithium iron phosphate (LFP) battery in a hybrid transit bus. The battery abuse and emissions tests were designed to intentionally drive the three different battery chemistries into thermal runaway while measuring battery temperatures, battery voltages and gaseous emissions.
Technical Paper

Light Duty Vehicle Life Cycle Analysis

2021-04-06
2021-01-0789
The short-term future direction of the automotive transportation sector is uncertain. Many governments and environmental localities around the world are proposing internal combustion engine (ICE) bans and enacting large subsidy programs for zero-tailpipe emissions vehicles powered by batteries or fuel-cells. Such policies can be effective in driving the consumer towards specific powertrains. The reason for such aggressive change is to reduce the sector’s carbon footprint. However, it is not clear if these proposals will reduce greenhouse gas (GHG) emissions. Emissions from raw material extraction, manufacturing, and power generation are shadowed by the focus on reducing the reliance on fossil fuel use. Emissions from non-tailpipe sources should also be considered before pushing for a rapid change to powertrains. Life-cycle analysis (LCA) can assess the GHG emissions produced before, during and after the life of a vehicle in a cradle-to-grave analysis.
Technical Paper

A Comprehensive Numerical Approach to Predict Thermal Runaway in Li-Ion Battery Packs

2021-04-06
2021-01-0748
With the increasing level of electrification of on-road, off-road and stationary applications, use of larger lithium-ion battery packs has become essential. These packs require large capital investments on the order of millions of dollars and pose a significant risk of self-annihilation without rigorous safety evaluation and management. Testing these larger battery packs to validate design changes can be cost prohibitive. A reliable numerical simulation tool to predict battery thermal runaway under various abuse scenarios is essential to engineer safety into the battery pack design stage. A comprehensive testing & simulation workflow has been established to calibrate and validate the numerical modeling approach with the test data for each of the individual sub model - electrochemical, internal short circuit and thermal abuse model. A four-equation thermal abuse model was built and validated for lithium-ion 21700 form factor cylindrical cells using NCA cathodes.
Technical Paper

Development of an In-Situ Diagnostic to Detect Lithium Plating in Commercial Automotive Battery Cells

2021-04-06
2021-01-0749
Lithium plating refers to the phenomenon where lithium metal is deposited onto the surface of the anode instead of being intercalated into the carbon sites of the graphite. The lithium metal will cover a portion of the surface area of the anode, which blocks intercalation sites and increases charge gradients. Lithium plating most often occurs when charging the battery at low ambient temperatures or at a high current rate, but lithium plating formation has also been linked to solid electrolyte interface (SEI) growth towards the later stages of life. Lithium plating may significantly reduce a battery cell’s performance in terms of charge capacity, and if severe enough, the lithium metal may form a bridge across the separator of the cell, leading to short circuits and potential safety concerns. The internal research performed by Southwest Research Institute explored how to create a battery model to detect the formation of lithium plating in real time.
Technical Paper

Modeling and Predicting Mechanically Induced Internal Short Circuits in Lithium Ion Battery Packs

2021-04-06
2021-01-0750
As advances in electrification continue within the vehicle industry, improving the front-end design process and managing the safety aspects of lithium-ion batteries is increasingly important. Structural damage to lithium-ion batteries can cause internal short circuit, leading to a large energy release that can lead to fire and thermal runaway that propagates throughout the battery pack. Southwest Research Institute has developed a mechanical model that can accurately predict mechanically-induced damage to lithium-ion battery cells and battery packs. This model also predicts whether the external damage will cause an internal short-circuit. This modeling process was illustrated using 21700 cylindrical cells with NCA cathode chemistry. High-speed impact tests were used to calibrate a single cell model, which was then scaled to a 12-cell battery module. This model was then used to accurately predict the outcome of an impact test on a 72-cell battery module.
Technical Paper

In-Situ Measurement of Component Efficiency in Connected and Automated Hybrid-Electric Vehicles

2020-04-14
2020-01-1284
Connected and automated driving technology is known to improve real-world vehicle efficiency by considering information about the vehicle’s environment such as traffic conditions, traffic lights or road grade. This study shows how the powertrain of a hybrid-electric vehicle realizes those efficiency benefits by developing methods to directly measure real-time transient power losses of the vehicle’s powertrain components through chassis-dynamometer testing. This study is a follow-on to SAE Technical Paper 2019-01-0116, Test Methodology to Quantify and Analyze Energy Consumption of Connected and Automated Vehicles [1], to understand the sources of efficiency gains resulting from connected and automated vehicle driving. A 2017 Toyota Prius Prime was instrumented to collect power measurements throughout its powertrain and driven over a specific driving schedule on a chassis dynamometer.
Journal Article

Automated Driving Impediments

2016-09-27
2016-01-8007
Since the turn of the millennium, automated vehicle technology has matured at an exponential rate, evolving from research largely funded and motivated by military and agricultural needs to a near-production market focused on everyday driving on public roads. Research and development has been conducted by a variety of entities ranging from universities to automotive manufacturers to technology firms demonstrating capabilities in both highway and urban environments. While this technology continues to show promise, corner cases, or situations outside the average driving environment, have emerged highlighting scenarios that impede the realization of full automation anywhere, anytime. This paper will review several of these corner cases and research deficiencies that need to be addressed for automated driving systems to be broadly deployed and trusted.
Technical Paper

Deploying Connected VehicleSM using the FDOT SunGuide® Software: Technology Leadership Brief

2012-10-08
2012-01-9016
The State of Florida initiated the SunGuide® Advanced Traffic Management System (ATMS) software development program in October 2003; that software is deployed in over 15 Traffic Management Centers (TMCs) throughout the major cities in Florida. One of SunGuide's biggest strengths is a software architecture that allows for short development times for new functionality. This paper describes the system design, implementation, and lessons learned from the development of the SunGuide Connected Vehicle Subsystem (CVS). The SunGuide CVS receives real-time speed, location, and heading data from instrumented vehicles and uses that data in a manner similar to its use of traffic detector data to provide information to the TMC. In addition to the vehicle providing data to the TMC, the TMC may create and publish Traveler Advisory Messages to the vehicle as part of the SunGuide Event Management response plans.
Technical Paper

Accessory Electrification in Class 8 Tractors

2006-04-03
2006-01-0215
Fuel costs to operate large trucks have risen substantially in the last few years and, based on petroleum supply/demand curves, that trend is expected to continue for the foreseeable future. Non-propulsion or parasitic loads in a large truck account for a significant percentage of overall engine load, leading to reductions in overall vehicle fuel economy. Electrification of parasitic loads offers a way of minimizing non-propulsion engine loads, using the full motive force of the engine for propulsion and maximizing vehicle fuel economy. This paper covers the integration and testing of electrified accessories, powered by a fuel cell auxiliary power unit (APU) in a Class 8 tractor. It is a continuation of the efforts initially published in SAE paper 2005-01-0016.
Technical Paper

Comparative Abuse Testing of 36 V and 12 V Battery Designs

2006-04-03
2006-01-1272
Comparative abuse tests were performed on commercially available 12 V and 36 V battery designs. Four methods were chosen from SAE J2464 standard, Electrical Vehicle Battery Abuse Testing, March 1999, and modified to apply them to typical-sized automotive batteries. The four tests included a Penetration Test, Crush Test, Radiant Heat Test, and Short Circuit Test. Both the 12 V and 36 V batteries showed minimal reactions to the tests, and there was no significant difference between results of the two designs with respect to the abuse tests performed. It should be stressed however, that this project was limited in scope and was not intended to be a thorough investigation in the batteries safety hazards.
Technical Paper

Life-Cycle Cost Sensitivity to Battery-Pack Voltage of an HEV

2000-04-02
2000-01-1556
A detailed component performance, ratings, and cost study was conducted on series and parallel hybrid electric vehicle (HEV) configurations for several battery pack and main electric traction motor voltages while meeting stringent Partnership for a New Generation of Vehicles (PNGV) power delivery requirements. A computer simulation calculated maximum current and voltage for each component as well as power and fuel consumption. These values defined the peak power ratings for each HEV drive system's electric components: batteries, battery cables, boost converter, generator, rectifier, motor, and inverter. To identify a superior configuration or voltage level, life cycle costs were calculated based on the components required to execute simulated drive schedules. These life cycle costs include the initial manufacturing cost of components, fuel cost, and battery replacement cost over the vehicle life.
Technical Paper

Analysis For A Parallel Four-Wheel Propane Electric Hybrid Vehicle

1999-08-17
1999-01-2907
This paper analyzes the hybridization of a conventionally powered light duty front wheel drive pick up truck by adding an electric motor driven rear axle. Also studied are the effects of using propane fuel instead of gasoline. This hybrid powertrain configuration can be described as a parallel hybrid electric vehicle. Supervisory power management control has been developed to best determine the proportion of load to be provided by the engine and/or electric motor. To perform these analyses, a simulation tool (computer model of the powertrain components) was developed using MATLAB/SIMULINK'. The models account for the thermal and mechanical efficiencies of the components and are designed to develop control strategies for meeting road loads with improved fuel economy and reduced emissions. Results of this study have shown that fuel economy can be improved and emissions reduced using commercially available components (motor, rear axle, and lead acid batteries).
Technical Paper

Preparation and Testing of an Electric Competition Vehicle

1991-08-01
911684
A Dodge Omni electric car was prepared for competition in an electric “stock car” 2-hour endurance event: the inaugural Solar and Electric 500 Race, April 7, 1991. This entry utilized a series-wound, direct-current 21-hp electric motor controlled by an SCR frequency and pulse width modulator. Two types of lead-acid batteries were evaluated and the final configuration was a set of 16 (6-volt each) deep-cycle units. Preparation involved weight and friction reduction; suspension modification; load, charge and temperature instrumentaltion; and electrical interlock and collision safety systems. Vehicle testing totalled 15 hours of operation. Ranges observed in testing with the final configuration were from 30 to 52 miles for loads of 175 to 90 amperes. These were nearly constant, continuous discharge cycles. The track qualifying speed (64mph) was near the 68 mph record set by the DEMI Honda at the event on the one-mile track.
Technical Paper

The Development of Techniques to Measure Vehicle Spray on Wet Roads

1974-02-01
740526
Several techniques have been developed to measure the relative amount of splash and spray produced by vehicles when driven on wet roads at highway speeds under controlled conditions. This paper discusses considerations in the development of measurement techniques such as those utilizing photographs, a photometer, densitometer, spraymeter, and spray collector. The development of each technique is described. Some test data utilizing the photometer and densitometer techniques are presented in a comparison of two different trucks run on two different road surfaces with new and worn tires, fully loaded and unloaded, and under light and heavy road moisture conditions.
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