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Technical Paper

Stress Generation in Large Pouch Cells Under Cycling and Abuse Conditions

2024-04-09
2024-01-2196
Pouch cells are increasingly popular form factors for the construction of energy storage systems in electric vehicles of all classes. Knowledge of the stress generated by these higher capacity pouch cells is critical to properly design battery modules and packs for both normal and abnormal operation. Existing literature predominantly offers data on smaller pouch cells with capacities of less than 10 Ah, leaving a gap in our understanding of the behavior of these larger cells. This experimental study aimed to bridge this knowledge gap by measuring loads and stresses in constrained 65 Ah pouch cells under both cycling and abuse conditions. To capture the desired responses, a load cell was located within a robust fixture to measure cell stress in real time after the application of a preload of approximately 30 kilograms or 294 N, equivalent to a pressure of 0.063 bar, with a fixed displacement.
Technical Paper

Analysis of overcharge tolerance of aged LMO cells with Examples

2023-09-29
2023-32-0108
The capacity of a lithium-ion battery decreases during cycling. This capacity loss or fade occurs due to several different mechanisms associated with unwanted side reactions that occur in these batteries. The same reactions occur during overcharge and cause electrolyte decomposition, passive film formation, active material dissolution, and other phenomena. As the battery ages the accuracy of state of charge prediction decreases and vulnerability to persistent overcharge increases. Moreover, as the battery ages, its tolerance to such unintended overcharge changes. This tolerance depends on the nature of the history of cycle and calendar aging. A map of this tolerance in the BMS can provide awareness of the factor of safety due to overcharge as battery ages. Signatures of early warning signs of incipient thermal runaway due to overcharge can also be very useful features in a BMS.
Journal Article

A One-Way Coupled Modeling Method to Simulate Battery Pack Thermal Runaway Initiated by an External Impact

2023-04-11
2023-01-0593
There is an ongoing proliferation of electric and electrified vehicles as manufacturers seek to reduce their carbon footprint and meet the carbon reduction targets mandated by governments around the world. An ongoing challenge in electric vehicle design is the efficient and safe design of battery packs. There are significant safety challenges for lithium battery packs relating to thermal runaway, which can be initiated through overheating and internal short from defects or external damage. This work proposes a robust method to couple the mechanical damage in a battery module calculated from a dynamic model with a thermal model of the battery that includes heating from electro-chemical sources as well as Arrhenius reactions from the battery cells. The authors identify the main sources of thermal runaway initiation and propagation in an impact scenario simulating a vehicle collision. The modeling approach was developed and validated using test data.
Technical Paper

Comparison of Representative Wet and Dry Fire Suppressants to Retard Fire Propagation in Lithium-Ion Modules Initiated by Overcharge Abuse

2023-04-11
2023-01-0520
Overcharging lithium-ion batteries is a failure mode that is observed if the battery management system (BMS) or battery charger fails to stop the charging process as intended. Overcharging can easily lead to thermal runaway in a battery. In this paper, nickel manganese cobalt (NMC) battery modules from the Chevrolet Bolt, lithium manganese oxide (LMO) battery modules from the Chevrolet Volt, and lithium iron phosphate (LFP) battery modules from a hybrid transit bus were overcharged. The battery abuse and emissions tests were designed to intentionally drive the three different battery chemistries into thermal runaway while measuring battery temperatures, battery voltages, gaseous emissions, and feedback from volatile organic compound (VOC) sensors. Overcharging a battery can cause lithium plating and other exothermic reactions that will lead to thermal runaway.
Journal Article

A Comparative Study of Lithium-Ion Cathode Chemistry Correlations with Emissions Initiated by Nail Penetration Abuse in the Presence of an Immersive Coolant

2022-03-29
2022-01-0707
Internal short-circuit in cells/batteries is a phenomenon where there is direct electrical contact between the positive and negative electrodes leading to thermal runaway. The nail penetration tests were used to simulate an internal short circuit within the battery, where a conductive nail was used to pierce the battery cell separator membrane which provided direct electrical contact between the positive and negative electrodes. The batteries tested during this work were common batteries used in existing automotive applications, and they included a nickel manganese cobalt (NMC) battery from a Chevrolet Bolt, a lithium manganese oxide (LMO) battery from a Chevrolet Volt, and a lithium iron phosphate (LFP) battery in a hybrid transit bus. The battery abuse and emissions tests were designed to intentionally drive the three different battery chemistries into thermal runaway while measuring battery temperatures, battery voltages and gaseous emissions.
Journal Article

A Comparative Study of Lithium-Ion Cathode Chemistry Correlations with Emissions Initiated by Nail Penetration Abuse in the Presence of an Immersive Coolant

2022-03-29
2022-01-0715
Internal short-circuit in cells/batteries is a phenomenon where there is direct electrical contact between the positive and negative electrodes leading to thermal runaway. The nail penetration tests were used to simulate an internal short circuit within the battery, where a conductive nail was used to pierce the battery cell separator membrane which provided direct electrical contact between the positive and negative electrodes. The batteries tested during this work were common batteries used in existing automotive applications, and they included a nickel manganese cobalt (NMC) battery from a Chevrolet Bolt, a lithium manganese oxide (LMO) battery from a Chevrolet Volt, and a lithium iron phosphate (LFP) battery in a hybrid transit bus. The battery abuse and emissions tests were designed to intentionally drive the three different battery chemistries into thermal runaway while measuring battery temperatures, battery voltages and gaseous emissions.
Technical Paper

Light Duty Vehicle Life Cycle Analysis

2021-04-06
2021-01-0789
The short-term future direction of the automotive transportation sector is uncertain. Many governments and environmental localities around the world are proposing internal combustion engine (ICE) bans and enacting large subsidy programs for zero-tailpipe emissions vehicles powered by batteries or fuel-cells. Such policies can be effective in driving the consumer towards specific powertrains. The reason for such aggressive change is to reduce the sector’s carbon footprint. However, it is not clear if these proposals will reduce greenhouse gas (GHG) emissions. Emissions from raw material extraction, manufacturing, and power generation are shadowed by the focus on reducing the reliance on fossil fuel use. Emissions from non-tailpipe sources should also be considered before pushing for a rapid change to powertrains. Life-cycle analysis (LCA) can assess the GHG emissions produced before, during and after the life of a vehicle in a cradle-to-grave analysis.
Technical Paper

A Comprehensive Numerical Approach to Predict Thermal Runaway in Li-Ion Battery Packs

2021-04-06
2021-01-0748
With the increasing level of electrification of on-road, off-road and stationary applications, use of larger lithium-ion battery packs has become essential. These packs require large capital investments on the order of millions of dollars and pose a significant risk of self-annihilation without rigorous safety evaluation and management. Testing these larger battery packs to validate design changes can be cost prohibitive. A reliable numerical simulation tool to predict battery thermal runaway under various abuse scenarios is essential to engineer safety into the battery pack design stage. A comprehensive testing & simulation workflow has been established to calibrate and validate the numerical modeling approach with the test data for each of the individual sub model - electrochemical, internal short circuit and thermal abuse model. A four-equation thermal abuse model was built and validated for lithium-ion 21700 form factor cylindrical cells using NCA cathodes.
Technical Paper

Development of an In-Situ Diagnostic to Detect Lithium Plating in Commercial Automotive Battery Cells

2021-04-06
2021-01-0749
Lithium plating refers to the phenomenon where lithium metal is deposited onto the surface of the anode instead of being intercalated into the carbon sites of the graphite. The lithium metal will cover a portion of the surface area of the anode, which blocks intercalation sites and increases charge gradients. Lithium plating most often occurs when charging the battery at low ambient temperatures or at a high current rate, but lithium plating formation has also been linked to solid electrolyte interface (SEI) growth towards the later stages of life. Lithium plating may significantly reduce a battery cell’s performance in terms of charge capacity, and if severe enough, the lithium metal may form a bridge across the separator of the cell, leading to short circuits and potential safety concerns. The internal research performed by Southwest Research Institute explored how to create a battery model to detect the formation of lithium plating in real time.
Technical Paper

Modeling and Predicting Mechanically Induced Internal Short Circuits in Lithium Ion Battery Packs

2021-04-06
2021-01-0750
As advances in electrification continue within the vehicle industry, improving the front-end design process and managing the safety aspects of lithium-ion batteries is increasingly important. Structural damage to lithium-ion batteries can cause internal short circuit, leading to a large energy release that can lead to fire and thermal runaway that propagates throughout the battery pack. Southwest Research Institute has developed a mechanical model that can accurately predict mechanically-induced damage to lithium-ion battery cells and battery packs. This model also predicts whether the external damage will cause an internal short-circuit. This modeling process was illustrated using 21700 cylindrical cells with NCA cathode chemistry. High-speed impact tests were used to calibrate a single cell model, which was then scaled to a 12-cell battery module. This model was then used to accurately predict the outcome of an impact test on a 72-cell battery module.
Technical Paper

Vehicle Drive Cycle Fuel Economy Prediction Using Single Cylinder Engine Data

2019-04-02
2019-01-0628
The confluence of fuel economy improvement requirements and increased use of ethanol as a gasoline blend component has led to various studies into the efficiency and performance benefits to be had when using high octane number, high ethanol content fuels in modern engines. As part of a comprehensive study of the autoignition of fuels in both the CFR octane rating engine and a modern, direct injection, turbocharged spark ignited engine, a series of fuel blends were prepared with market relevant ranges of octane numbers and ethanol blends levels. The paper reports on the first part of this study where fuel flow measurements were done on a single cylinder research engine, utilizing a GM LHU combustion system, and then used to predict drive cycle fuel economy. For a range of engine speeds and manifold air pressures, spark timing was adjusted to achieve either the maximum brake torque (MBT) or a matched 50 % mass fraction burnt location.
Technical Paper

In-Situ Measurement of Holistic Powertrain Efficiency in Vehicles

2018-04-03
2018-01-0324
Conventional methods for determining automotive powertrain efficiency include (1) component-level testing, such as engine dynamometer, transmission stand or axle stand testing, (2) simulations based on component level test data and (3) vehicle-level testing, such as chassis dynamometer or on-road testing. This paper focuses on vehicle-level testing to show where energy is lost throughout a complete vehicle powertrain. This approach captures all physical effects of a vehicle driving in real-world conditions, including torque converter lockup strategies, transmission shifting, engine control strategies and inherent mechanical efficiency of the components. A modern rear-wheel drive light duty pickup truck was instrumented and tested on a chassis dynamometer. Power was measured at the engine crankshaft output, the rear driveshaft and at the dynamometer.
Journal Article

HMMWV Axle Testing Methodology to Determine Efficiency Improvements with Superfinished Hypoids

2013-04-08
2013-01-0605
A dynamometer test methodology was developed for evaluation of HMMWV axle efficiency with hypoid gearsets, comparing those having various degrees of superfinish versus new production axles as well as used axles removed at depot maintenance. To ensure real-world applicability, a HMMWV variant vehicle model was created and simulated over a peacetime vehicle duty cycle, which was developed to represent a mission scenario. In addition, tractive effort calculations were then used to determine the maximum input torques. The drive cycle developed above was modified into two different profiles having varying degrees of torque variability to determine if the degree of variability would have a significant influence on efficiency in the transient dynamometer tests. Additionally, steady state efficiency performance is measured at four input pinion speeds from 700-2500 rpm, five input torques from 50 - 400 N⋅m, and two sump temperatures, 80°C and 110°C.
Technical Paper

Fuel Efficiency Effects of Lubricants in Military Vehicles

2010-10-25
2010-01-2180
The US Army is currently seeking to reduce fuel consumption by utilizing fuel efficient lubricants in its ground vehicle fleet. An additional desire is for a lubricant which would consist of an all-season (arctic to desert), fuel efficient, multifunctional Single Common Powertrain Lubricant (SCPL) with extended drain capabilities. To quantify the fuel efficiency impact of a SCPL type fluid in the engine and transmission, current MIL-PRF-46167D arctic engine oil was used in place of MIL-PRF-2104G 15W-40 oil and SAE J1321 Fuel Consumption In-Service testing was conducted. Additionally, synthetic SAE 75W-140 gear oil was evaluated in the axles of the vehicles in place of an SAE J2360 80W-90 oil. The test vehicles used for the study were three M1083A1 5-Ton Cargo vehicles from the Family of Medium Tactical Vehicles (FMTV).
Journal Article

Ethanol Flex-fuel Engine Improvements with Exhaust Gas Recirculation and Hydrogen Enrichment

2009-04-20
2009-01-0140
An investigation was performed to identify the benefits of cooled exhaust gas recirculation (EGR) when applied to a potential ethanol flexible fuelled vehicle (eFFV) engine. The fuels investigated in this study represented the range a flex-fuel engine may be exposed to in the United States; from 85% ethanol/gasoline blend (E85) to regular gasoline. The test engine was a 2.0-L in-line 4 cylinder that was turbocharged and port fuel injected (PFI). Ethanol blended fuels, including E85, have a higher octane rating and produce lower exhaust temperatures compared to gasoline. EGR has also been shown to decrease engine knock tendency and decrease exhaust temperatures. A natural progression was to take advantage of the superior combustion characteristics of E85 (i.e. increase compression ratio), and then employ EGR to maintain performance with gasoline. When EGR alone could not provide the necessary knock margin, hydrogen (H2) was added to simulate an onboard fuel reformer.
Technical Paper

Accessory Electrification in Class 8 Tractors

2006-04-03
2006-01-0215
Fuel costs to operate large trucks have risen substantially in the last few years and, based on petroleum supply/demand curves, that trend is expected to continue for the foreseeable future. Non-propulsion or parasitic loads in a large truck account for a significant percentage of overall engine load, leading to reductions in overall vehicle fuel economy. Electrification of parasitic loads offers a way of minimizing non-propulsion engine loads, using the full motive force of the engine for propulsion and maximizing vehicle fuel economy. This paper covers the integration and testing of electrified accessories, powered by a fuel cell auxiliary power unit (APU) in a Class 8 tractor. It is a continuation of the efforts initially published in SAE paper 2005-01-0016.
Technical Paper

Comparative Abuse Testing of 36 V and 12 V Battery Designs

2006-04-03
2006-01-1272
Comparative abuse tests were performed on commercially available 12 V and 36 V battery designs. Four methods were chosen from SAE J2464 standard, Electrical Vehicle Battery Abuse Testing, March 1999, and modified to apply them to typical-sized automotive batteries. The four tests included a Penetration Test, Crush Test, Radiant Heat Test, and Short Circuit Test. Both the 12 V and 36 V batteries showed minimal reactions to the tests, and there was no significant difference between results of the two designs with respect to the abuse tests performed. It should be stressed however, that this project was limited in scope and was not intended to be a thorough investigation in the batteries safety hazards.
Technical Paper

Life-Cycle Cost Sensitivity to Battery-Pack Voltage of an HEV

2000-04-02
2000-01-1556
A detailed component performance, ratings, and cost study was conducted on series and parallel hybrid electric vehicle (HEV) configurations for several battery pack and main electric traction motor voltages while meeting stringent Partnership for a New Generation of Vehicles (PNGV) power delivery requirements. A computer simulation calculated maximum current and voltage for each component as well as power and fuel consumption. These values defined the peak power ratings for each HEV drive system's electric components: batteries, battery cables, boost converter, generator, rectifier, motor, and inverter. To identify a superior configuration or voltage level, life cycle costs were calculated based on the components required to execute simulated drive schedules. These life cycle costs include the initial manufacturing cost of components, fuel cost, and battery replacement cost over the vehicle life.
Technical Paper

Analysis For A Parallel Four-Wheel Propane Electric Hybrid Vehicle

1999-08-17
1999-01-2907
This paper analyzes the hybridization of a conventionally powered light duty front wheel drive pick up truck by adding an electric motor driven rear axle. Also studied are the effects of using propane fuel instead of gasoline. This hybrid powertrain configuration can be described as a parallel hybrid electric vehicle. Supervisory power management control has been developed to best determine the proportion of load to be provided by the engine and/or electric motor. To perform these analyses, a simulation tool (computer model of the powertrain components) was developed using MATLAB/SIMULINK'. The models account for the thermal and mechanical efficiencies of the components and are designed to develop control strategies for meeting road loads with improved fuel economy and reduced emissions. Results of this study have shown that fuel economy can be improved and emissions reduced using commercially available components (motor, rear axle, and lead acid batteries).
Technical Paper

Design and Testing of an Automatic Tire Inflation System for Drive Axles on Class 8 Tractors

1996-10-01
962213
An Automatic Tire Inflation System (ATIS) specifically designed for commercial use on trailer axles is currently being installed and utilized successfully by trucking companies, the military and owner/operators throughout the U.S. A need exists for an ATIS specifically designed for the drive axles of Class 8 over-the- road tractors. The addition of an ATIS for drive axles will expand automatic tire monitoring capability to all heavily loaded tires of the over-the-road truck/trailer rig. An ATIS for drive axles has been designed, fabricated and tested. Testing and evaluation of the prototype ATIS drive axle system indicates the system can be successfully installed on a typical tractor rig and operated for an extended period without problems. The testing included a 50,000 mile evaluation of the ATIS installed in a laboratory test fixture. The test fixture used stock axle parts and operated at 65 MPH. Environmental testing was conducted at temperatures ranging from -20 to +200 degrees F.
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