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This paper presents an improvement in the accuracy of NOx sensors at high NOx concentration regions by optimizing the manufacturing process, sensor electrode materials and structure, in order to suppress the deterioration mechanism of sensor electrodes. Though NOx sensors generally consist of Pt/Au alloy based oxygen pump electrodes and Pt/Rh alloy based sensor electrodes, detailed experimental analysis of aged NOx sensors showed changes in the surface composition and morphology of the sensor electrode. The surface of the sensor electrode was covered with Au, which is not originally contained in the electrode, resulting in a diminished active site for NOx detection on the sensor electrode and a decrease in sensor output. Theoretical analysis using CAE with molecular dynamics supported that Au tends to be concentrated on the surface of the sensor electrode.

Mass reduction of parts is growing in importance as a means for reducing CO2 emissions from vehicles.The aim of the present research was to contribute to further mass reduction of pistons by developing a new aluminum casting material with highest level of fatigue strength. This goal was achieved using a development concept of creating a homogeneous structure in which Ti was added to create a fine structure and appropriate quantities of Fe and Mn were added to form a compound that is stable at high temperatures. Stand-alone tests of prototype pistons fabricated using the developed material show that the material is 14% stronger than the conventional material, thereby enabling increases in power and mass reduction.

Newly designed gears are subject to higher loads that demand a steel that is capable of greater pitting resistance. The application of shot peening to gears has been increasing to improve tooth root strength, but pitting resistance had not been necessarily high. This study examines the effect of alloying additions mainly on tempering resistance and the formation of a non-martensitic layer. The developed high Si-Mo type steel shows excellent pitting resistance, even in shot peened gears, as compared to that of conventional steels due to high tempering resistance and the thin, uniform non-martensitic layer. This new steel is of practical use in some multi-speed automatic transmission gears.

A new, free-cutting steel, hereafter referred to as “non-lead-added free-cutting steel”, has been developed with the intention of replacing currently applied lead containing free cutting steel. The ultimate goal of this project is to provide a new lead-free steel grade that will contribute to the removal of environmentally harmful substances from automobile parts. In this project, we have targeted the development of a material that would demonstrate levels of machinability and other mechanical properties equivalent to those of the conventional free-cutting steel to which sulfur (S), lead (Pb) and calcium (Ca) or combinations, thereof have been added. The fine dispersion of sulfide, modified by adding Mg and Ca, is most effective in enhancing the chip breakability that would otherwise deteriorate due to the absence of lead. The practical application of the non-lead-added free-cutting steel has rendered the goal of total removal of lead from special steel products highly obtainable.

In preparation for compliance with California's SULEV standard and Euro STAGE 4 standard, which will take effect in 2002 and 2005, respectively, we have developed a laminated planar oxygen sensor. The developed sensor has the following characteristics: high thermal conductivity and superior dielectric characteristic, due to direct joining of the heater element alumina substrate and the sensor element zirconia electrolyte; low heat stress at temperature rise, due to optimized heater design; superior sensor protection from water droplets, and improved sensor response, due to optimized arrangement of intake holes in the sensor cover. With these characteristics, the developed oxygen sensor can be activated in 10 seconds after cold start. This report describes the technologies we used to develop the early-activation oxygen sensor.

This paper describes the development of alloy cast iron that can be used for the cutting edges of the trimming die of a press die. Usually, a block of tool steel or steel casting is inserted at the cutting edge of the trimming die of a press die. However, we unified the structure part and the cutting-edge part of a press die with alloy cast iron. As it can''t bear as the cutting edge in this state, the cutting edge is processed by flame-hardening. After the flame- hardening, we developed the alloy cast iron so that enough hardness may be obtained by natural air cooling. Thereby, the machining of the installation seat of the cutting edge decreased and the expense of dies has been reduced.

The automobile industry currently faces many challenges which may greatly impact on its foundry operations. One of these challenges, consumers'' demand for greater fuel efficiency, can be met by reducing the weight of castings used in automobiles, and minimizing engineering tolerances. In answer to this particular demand, engine foundries have begun to either produce cylinder blocks or other castings with aluminum rather than cast iron. However, if a reduction in weight (thin wall and near-net shaping) can be realized with cast iron, there would be numerous merits from the perspective of cost and compactness and there would be much more flexibility in automotive parts design.

Two-layered surface materials composed of a thermoplastic olefin elastomer (TPO) skin and a cross-linked polypropylene (PP)foam are increasingly replacing the conventional PVC skin/PVC foam for interior trims. In the past, recycled material obtained by melt-blending TPO skin and PP foam could not be re-used for TPO skin because of its appearance. A new recycling technology using the reaction biaxial extruder with a reaction agent can decompose the network structure of PP foam. As a result, PP foam is dispersed into TPO uniformly and the recycled material has properties and an appearance similar to virgin TPO. These new properties may allow the application of the recycled material as a surface material.

An all aluminum cylinder block with a Metal Matrix Composite (MMC) cylinder bore was developed which made it possible to re-design the base engine for high performance with a bore-to-bore distance as narrow as 5.5mm. The cylinder block is an open deck type and the MMC preform consists of alumina-silica fibers and mulite particles. A laminar flow die cast process was selected to ensure defect-free MMC bore quality. To insure good lubrication, electrochemical machining was applied to the bore surface. By use of radioisotope(RI) measurements, MMC reinforcement was optimized for wear characteristics. Particular attention was paid to use of fuels with high sulfur levels.

This paper presents the numerical simulation method to predict the deactivation process of three-way catalytic converters. Three-way catalytic converter's deactivation typically results from thermal and chemical mechanisms. The major factor of thermal deactivation is the sintering of noble metal particles, which is known to depend on the ageing temperature and the oxygen concentration in the exhaust gas. The chemical deactivation is mainly caused by the poisoning, which has two effects on the catalyst deactivation. One effect is the loss of the catalyst activity, which is expressed by reduced frequency factors of reaction rates. Another effect is the suppression of the noble metal sintering. Poison deposits prevent the noble metal particles from moving in the washcoat, assisted by the reduced thermal loading of reaction heats, which is caused by the loss of the catalyst activity. Modeling these deactivation factors, we propose the rate expression of noble metal sintering.

In contrast to the sensory inspection conventionally performed on the firing bench during final assembly, a technology in which quality inspections are distributed throughout the engine assembly line by using an electric motor to drive the engine, has been developed. Through this process, combustion conditions can be quantitatively tested by component, and leak test conditions can be optimized. Consequently, defects can be detected and their causes identified at an early stage of assembly, thus accelerating the feedback of information to the appropriate process. The result, a level of product quality that is higher than through the conventional means.

New ductile cast iron flywheel integrated with gear and its manufacturing process were developed to reduce the manufacturing steps and cost compared with conventional flywheel around which a steel ring gear is fit. In this process, the ring gear teeth around a cast iron flywheel are formed directly in net shape and free from any defect by the hot form-rolling method, followed by the thermomechanical treatment in a short time. The gear is superior to that made by the conventional hobbing and heat treatment in accuracy, strength and anti-wear property.

The combustion chamber deposit (CCD) forming tendency of gasoline components and detergents were investigated with laboratory tests ad engine dynamometer tests. In the dynamometer tests, the driving conditions under which fuels and detergents influence CCD formation were specified, and the effects of different gasoline components and detergent blends on CCD formation were examined. In the laboratory tests, the CCD forming process was investigated thoroughly [10]. The CCD forming tendency of aromatic compounds in gasoline were dependent not only on physical properties such as molecular weight, but also chemical structure (number or position of the alkyl substituents of aromatic molecules). As for oxygenates, engine dynamometer tests with MTBE blended gasoline yielded less CCD than the test without MTBE. The CCD forming tendency of detergents correlated with the thermal decompositon tendency of the detergent package and the concentration of the main agents.

As a means of effectively incorporating the concept of “life cycle” for reducing the environmental impact of the automobile, we carried out a life cycle inventory study on a part-by-part basis. The targets of our study are the fuel tanks that are made of different materials and manufacturing processes. One is made of steel, and the other is made of plastic, both perform identical functions. Our evaluation study encompasses the period from the manufacturing of the main materials until the disposal of the tanks. The evaluation items consist of the amount of energy consumed and the emissions (of CO2, NOx, SOx, and PM) that are released into the atmosphere. The results show that the plastic tank poses a greater burden in terms of the amount of energy consumed and the CO2 and NOx emitted.

We developed a fastening method to reduce noise levels and fastening work loads. The development was based on research into improved tools and fasteners. This was done in preparation for an increase in elderly worker and female worker population in the Automobile Assembly Shop. The principle of this method is to form female threads inside a straight sleeve by clinching the sleeve around a threaded bolt. We achieved improvements in component material clinching force and a durability for loosening torque compared to conventional bolt and nut methods.

A precise control system for a molten ferrous alloy temperature above 1700 K after the completion of induction melting has been developed in order to produce high quality casting parts for automobiles. In this system, the molten ferrous alloy temperature is measured just one time by a disposable thermocouple after the melting. The system predicts the temperature transition after the measurement using an original thermal model, and adjusts the supplied electric power to the furnace automatically according to the predicted temperature. Using this thermal model, the system has attained control deviations within ±5K under the following temperature controls, and contributed to the quality control of casting parts and the energy-saving during furnace operations. Casting temperature for a cast-steel of 1813 K in a 300 kg capacity high-frequency induction furnace on the “Toyota Vacuum Casting Process”.

In automotive plastic parts, bumpers are rather bigger parts and easy to be detached. And there is growing need to develop bumpers recycling technology. Now we developed the recycling technology for waste painted Super Olefin Polymer (SOP) bumpers from car dealers in production. This technology consists of discriminating from the repair in market by dyeing, and of melting SOP resin and hydrolysis of the paint film which are carried out simultaneously in a twin-screw extruder Reactive Processing System.

A high strength and high toughness new bainitic steel has been developed which shows comparable mechanical properties, fatigue property, and machinability to those of quenched and tempered SAE 5140. The heat treatment of the bainitic steel is aging after hot forging in order to improve ratio of 0.2% proof stress and tensile strength (i.e. yield ratio) and to avoid warpage associated with quenching. The new bainitic steel has been applied to the slender and lightweight lower arms for automotive suspension. As a result, the total production costs in the lower arms have been reduced by nearly 15 percent.

Recently, single action draw with cushion replaces draw with double action presses. In the single action draw, binding fluctuation problem occurs by its structure. We applied an NC cushion to prevent the problem. We compared the cushion force wave with and without an NC cushion. The NC cushion showed effective damping. We studied the binding force control of a side member outer panel. The panel didn't have the formable range of binding. This means the lowest binding force to avoid wrinkling, still had crack problems. We introduce four patterns of binding force control with the NC cushion. As a result, we found the suitable pattern to suppress the surface distortion. Controlling the binding force shows effectiveness as a means of suppressing surface distortions.

We have developed a new torsional damper spring which lowers the torsional rigidity of the clutch disc while retaining its conventional size. The following two items have been adopted in the newly developed spring: 1) A new steel wire which suppresses any core-softening of the element wire through nitriding. 2) A dual-stage shot peening method which uses harder steel shots (rather than conventional shots) in order to obtain an optimal residual stress profile. As a result of evaluating the fatigue characteristics of this spring, it was discovered that its fatigue strength is approximately 35% higher than that of the conventional spring. A clutch disc using this spring was able to absorb rattling noises which conventional clutch discs could not.