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Technical Paper

Improved Coated Gasoline Particulate Filters for China 7 and US Tier 4 Legislations

2024-04-09
2024-01-2387
The impending emission regulations in both China (CN7) and the United States (Tier 4) are set to impose more stringent emission limits on hydrocarbons (HC), carbon monoxide (CO), nitrogen oxides (NOx), and particulate matter (PM). CN7 places particular emphasis on reducing particulate number (PN) thresholds, while the forthcoming United States Tier 4 legislation is primarily concerned with reducing the allowable particulate matter (PM) to an assumed limit of 0.5 mg/mile. Given the more stringent constraints on both PN and PM emissions, the development of enhanced aftertreatment solutions becomes imperative to comply with these new regulatory demands. Coated Gasoline Particulate Filters (cGPFs) play a pivotal role as essential components for effective PN and PM abatement.
Technical Paper

Advanced Aftertreatment System Meeting Future HD CNVII Legislation

2024-04-09
2024-01-2379
Options for CNVII emission legislation are being widely investigated in a national program organized by China Vehicle Emission Control Center (VECC) since early 2020. It is foreseen that this possibly last legislation in China will have more stringent emission requirements compared to CNVI, including among other changes especially a further reduction of nitrogen oxide (NOx), inclusion of nitrous oxide (N2O) and sub-23 nm particle number (PN). This study investigates the technical feasibility to fulfill a CNVII emission legislation scenario, based on a modified CNVI 8 L engine operating under both cold and hot World Harmonized Transient Cycle (WHTC) and Low Load Cycle (LLC).
Technical Paper

GPF: An Effective Technology to Minimize Two Wheeler (2Wh) Particulate Emission

2024-01-16
2024-26-0140
India is the world’s largest two-wheeler (2Wh) market. With the proportion of its middle class rapidly rising, 2Wh sales and the resulting emissions, are expected to grow exponentially. The decision to leap-frog from BSIV to BSVI emission norms shows India’s commitment to clean up its atmosphere. As of now, the regulation mandates Gaseous Pollutant (CO, HC, NOx) emission limits for all 2Whs and a particulate limit (PM & PN) for 2Whs powered by Direct Injection (DI) engines. Most of the 2Whs manufactured in India are powered by gasoline engines using the Port Fuel Injection (PFI) technology, and hence by definition particulate emission limits do not apply to them. Particulates when inhaled - especially of the ultrafine sizes capable of entering the blood stream - pose a serious health risk. This was the primary motivation to investigate the particulate emission levels of the 2Whs, which as on date, do not come under the purview of BSVI regulation.
Technical Paper

Performance Evaluation Study to Optimize the NOx Conversion Efficiency of SDPF Catalyst for BS6 RDE/OBD2 Engine Application

2024-01-16
2024-26-0161
To meet future emission levels, the automotive industry is trying to reduce tailpipe emissions through both possible pathways, i.e. emission from engines as well as and the development of novel catalytic emission control concepts. The present study will focus on the close coupled SCR on Filter commonly known as SDPF which is a main pathway to reduce NOx along with particulate mass and number for light duty passenger cars and sport utility vehicles for BS 6 RDE/OBD 2 and future legislation like BS-7. The SDPF is a challenging technology as it is critical component in exhaust after treatment system involving in NOx and PM/PN reductions hence careful optimization of this technology is necessary in terms of space velocity requirements, temperature, feed NOx emission levels, particulate mass and ash holding capacities, NH3 storage on the SDPF, and back pressure.
Technical Paper

Sub-23nm Particle Emissions from China6 Gasoline Vehicles over Various Driving Cycles

2023-04-11
2023-01-0395
Sub-23nm particles emission from the light-duty vehicle is widely discussed now and possible to be counted into the next stage emission legislation, such as Euro7. In this article, 16 China6 gasoline vehicles were tested over the WLTC and two surrogate RDE lab cycles for particulate number (PN) emission, the difference between PN23 (particle size >23nm) and PN10 (particle size>10nm) emission was analyzed. Testing results showed that the average PN10 emission increased 59% compared to PN23, which will bring great challenges for those vehicles to meet the future regulation requirement if sub-23nm particle is counted. The sub-23nm particles emission was proportional to the PN23 particles emission and generated mostly from the cold start or the transient engine conditions with rich combustion. Compared to the proposal of Euro 7, PN10 emission from some tested vehicles will need further two orders of magnitude reduction.
Technical Paper

Validation Test on a Light Duty Vehicle Equipped with a GDI Engine to Meet China 6b RDE Regulation for PN

2022-08-30
2022-01-1020
China 6 (CN6) emission legislation for light duty vehicles was published in 2016, which introduced real driving emissions (RDE) requirements for new type-approval content. Nitrogen oxides (NOx) and particle number (PN) of RDE test are required to be monitored and reported from July 2020 in CN6a phase, fulfilled from July 2023 in CN6b phase. To meet the PN limitation of CN6 RDE, the optimized engine combustion and advanced emission control system like gasoline particle filter (GPF) are encouraged. Compared to traditional vehicle platform emission compliance which could be done in lab, much more vehicle development and validation efforts are expected on the open road for RDE compliance. High cost and complexity are expected to conduct a complete validation test matrix covering all the RDE critical boundary conditions on the open road.
Technical Paper

Effect of Engine-Out Soot Emissions and the Frequency of Regeneration on Gasoline Particulate Filter Efficiency

2020-04-14
2020-01-1431
Gasoline particulate filters (GPFs) are an important aftertreatment system that enables gasoline direct injection (GDI) engines to meet current emission standardsn note of GPFs may need to improonont accumulates on the GPF during engine operation. GPFs are often ‘pa during vehicle operation when the exhaust is sufficiently hot and it contains sufficient oxygen. This paper explores the effect that engine-out soot emissions and the frequency of GPF regeneration have on GPF filtration efficiency. Two GPF technologies were tested on two engine dynamometers as well as two production vehicles on a chassis dynamometer. The engines span a wide range of engine-out particle emissions (a range of almost one order of magnitude). The filtration efficiency of the GPFs were measured with a regulation-compliant particle number system (non-volatile particles > 23 nm), as well as with a particle counter with a lower cutoff of 2.5 nm, and with a differential mobility spectrometer.
Journal Article

Catalysts for Post Euro 6 Plug-In Hybrid Electric Vehicles

2020-04-14
2020-01-0354
Due to benefits from the use of electric power, Hybrid Electric Vehicles (HEVs) and Plug-in Hybrid Electric Vehicles (PHEVs) are regarded to be superior over conventional Internal Combustion Engine (ICE) only vehicles in fuel economy and emissions. However, recent studies find out that this is not always true. On certain conditions, hybrid vehicles can be even more polluted. In order to identify these challenges and develop catalysts to meet more stringent emission requirement in the future, e.g. Euro 7, for hybrid application, as a part of our xHEV project, this study includes exclusively extensive investigation on a latest Euro 6d temp Parallel PHEV.
Technical Paper

On-Vehicle Fuel Cut Testing for Gasoline Particulate Filter Applications

2019-04-02
2019-01-0968
With the introduction of a stringent particulate number (PN) limit and real driving emission (RDE) requirements, gasoline particulate filters (GPF) are widely adopted for gasoline engines in Europe and China. The filter collects soot and ash. Like in diesel applications, the collected soot will continuously burn under favorable exhaust conditions. However, at extreme conditions, there could be large amounts of soot build-up, which may induce a highly exothermal event, potentially damaging the filter. Thus, it is important to understand what drives the over-heating in application, and develop counter measures. In this study, an on-vehicle fuel cut (FC) testing procedure was developed. The testing was conducted on two vehicles, one gasoline direct injection (GDI) vehicle and one multiple port injection (MPI) vehicle, with different exhaust systems designs (a close coupled GPF and an under floor GPF) and catalyst coating levels (bare and heavily coated GPFs).
Technical Paper

A Study into the Impact of Engine Oil on Gasoline Particulate Filter Performance through a Real-World Fleet Test

2019-04-02
2019-01-0299
Increasingly stringent vehicle emissions legislation is being introduced throughout the world, regulating the allowed levels of particulate matter emitted from vehicle tailpipes. The regulation may prove challenging for gasoline vehicles equipped with modern gasoline direct injection (GDI) technology, owing to their increased levels of particulate matter production. It is expected that gasoline particulate filters (GPFs) will soon be fitted to most vehicles sold in China and Europe, allowing for carbonaceous particulate matter to be effectively captured. However, GPFs will also capture and accumulate non-combustible inorganic ash within them, mainly derived from engine oil. Studies exist to demonstrate the impact of such ash on GPF and vehicle performance, but these commonly make use of accelerated ash loading methods, which themselves introduce significant variation.
Technical Paper

Acoustic Modeling for Three-Dimensional Lightweight Windshields

2018-04-03
2018-01-0141
In the auto industry, lightweight window designs are drawing more attention for improved gas mileage and reduced exhaust emission. Corning’s Gorilla® Glass used in laminate design enables more than 30% weight reduction compared to conventional soda-lime glass laminates. In addition, Gorilla® Glass hybrid laminates (which are a laminate construction of a thick soda-lime glass outer play, a middle polyvinyl butyral interlayer, and a thin Gorilla Glass inner ply) also show significantly improved toughness due to advanced ion-exchange technology that provides high-surface compression. However, the reduced mass also allows increased transmission of sound waves through the windshield into the vehicle cabin. A system-level measurement approach has always been employed to assess overall vehicle acoustic performance by measuring sound pressure levels (SPL) at the driver’s ears. The measured sound signals are usually a superimposition of a variety of noise sources and transmission paths.
Technical Paper

Impact of European Real-Driving-Emissions Legislation on Exhaust Gas Aftertreatment Systems of Turbocharged Direct Injected Gasoline Vehicles

2017-03-28
2017-01-0924
Recently, the European Union has adopted a new regulation on Real-Driving-Emissions (RDE) and also China is considering RDE implementation into new China 6 legislation. The new RDE regulation is focused on measuring nitrogen oxides (NOx) and particulate number (PN) emissions of both light-duty gasoline and diesel vehicles under real world conditions. A supplemental RDE test procedure was developed for European type approval, which includes on-road testing with cars equipped with portable emission measurement systems (PEMS). This new regulation will significantly affect the engine calibrations and the exhaust gas aftertreatment. In this study the impact of the new RDE regulation on two recent EU 6b certified turbocharged direct injected gasoline vehicles has been investigated. A comparison of several chassis dyno drive cycles with two new defined on-road RDE cycles was performed.
Technical Paper

Next Generation Cordierite Thin Wall DPF for Improved Pressure Drop and Lifetime Pressure Drop Solution

2016-04-05
2016-01-0940
Diesel particulate filters (DPF) have become a standard aftertreatment component for a majority of current on-road/non-road diesel engines used in the US and Europe. The upcoming Stage V emissions regulations in Europe will make DPFs a standard component for emissions reductions for non-road engines. The tightening in NOx emissions standard has resulted in the use of selective catalytic reduction (SCR) technology for NOx reduction and as a result the general trend in engine technology as of today is towards a higher engine-out NOx/PM ratio enabling passive regeneration of the DPF. The novel filter concept discussed in this paper is optimized for low pressure drop, high filtration efficiency, and low thermal mass for optimized regeneration and fast heat-up, therefore reducing CO2 implications for the DPF operation.
Technical Paper

Synthetic Gas Bench (SGB) Tests Simulating Real and Dynamic Driving Conditions: A New and Cost Attractive Method for TWC Evaluation

2015-04-14
2015-01-1066
The introduction of vehicle emission and fuel economy standards (CO2) accelerates the introduction of new platform and powertrain combinations into the market place. All of these combinations will require unique exhaust gas aftertreatment systems that comply with the current emission legislation. The optimization of each unique aftertreatment solution requires the proper application of catalyst technologies at the lowest PGM concentrations. The optimization process needs to be fast, reliable, realistic and cost attractive. It is arguable that performing the aftertreatment optimization on a chassis dynamometer is variable, time consuming and expensive. This work demonstrates how a synthetic gas bench (SGB) can be used to simulate stoichiometric engine emissions and aftertreatment performance. The SGB procedure duplicates the vehicle NEDC engine-out emissions and catalyst heat-up profiles.
Technical Paper

Advanced TWC Technology to Cover Future Emission Legislations

2015-04-14
2015-01-0999
The new emission regulations in Europe, EU 6 will promulgate more realistic driving conditions with more stringent HC, CO, NOx and particulate emissions. This legislation will also include the WLTP (Worldwide harmonized Light vehicles Test Procedure) cycle for CO2 measurements and a new requirement called “Real-Driving-Emissions” (RDE) as well. The RDE requirement is to ensure modern vehicles comply with the legislation under all conditions of normal driving. More robust aftertreatment solutions are needed to meet these new requirements. This work introduces an improved three-way catalyst (TWC) for gasoline engines for these new regulations. It is tested under static and dynamic conditions and on several engines and vehicles with various drive cycles. It offers better thermal stability combined with lower backpressure than former TWC generations.
Journal Article

Applicable Diesel Oxidation Catalyst for Multi-Diesel Exhaust System

2014-04-01
2014-01-1511
The diesel oxidation catalysts (DOC) having high purification performance to the exhaust gas at low temperatures were investigated. In this paper two main technological improvements from conventional DOC are shown. First is forming Pt/Pd composite particles in order to suppress sintering of precious metal under high thermal aging condition. This generating Pt/Pd composite and the effect were exemplified by TEM-EDS and XRD analysis. Second is adjusting electric charge of Pt/Pd surface to reduce interaction between Pt/Pd and carbon monoxide (CO) by modifying the support material components. Adjusting electric charge of Pt/Pd surface by applying new support material could cancel CO poisoning at Pt/Pd surface. Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) studies suggested that improved support material is more suitable for CO oxidation at a low temperature based on the concept.
Technical Paper

Comprehensive Gasoline Exhaust Gas Aftertreatment, an Effective Measure to Minimize the Contribution of Modern Direct Injection Engines to Fine Dust and Soot Emissions?

2014-04-01
2014-01-1513
With the growing awareness about the presence of fine/ultra fine particulates in the ambient air and their negative impact on climate and health, some regions of the world have started to look closer at the contribution of road traffic. Since Gasoline engines, in particular when injecting fuel directly into the combustion chamber, proved to emit relevant numbers of particulates, even hardly visible, the growing share of Gasoline DI engines and their small size of particulate emissions is a concern. To address the same, the EU has already set limits for the particulate number with EU6 from 2015 onwards. The US considers setting challenging limits by particulate mass. Since mass of ultra fine particulates is very low and difficult to measure, experts investigate if a measurement by number might better address the particular concern. The implementation of a coated Particulate Filter enables meeting not only basic demands during traditional emission test cycles.
Journal Article

Vehicular Emissions in Review

2013-04-08
2013-01-0538
This review paper summarizes major developments in vehicular emissions regulations and technologies (light-duty, heavy-duty, gasoline, diesel) in 2012. First, the paper covers the key regulatory developments in the field, including finalized criteria pollutant tightening in California; and in Europe, the development of real-world driving emissions (RDE) standards. The US finalized LD (light-duty) greenhouse gas (GHG) regulation for 2017-25. The paper then gives a brief, high-level overview of key developments in LD and HD engine technology, covering both gasoline and diesel. Marked improvements in engine efficiency are summarized for gasoline and diesel engines to meet both the emerging NOx and GHG regulations. HD engines are just starting to demonstrate 50% brake thermal efficiency. NOx control technologies are then summarized, including SCR (selective catalytic reduction) with ammonia, and hydrocarbon-based approaches.
Technical Paper

Different Properties of Biodiesel in Comparison with Standard Diesel Fuel and their Impact on EURO VI Exhaust Aftertreatment Systems

2012-09-10
2012-01-1733
The use of fatty acid methyl esters (FAME), often referred to as biodiesel, instead of fossil diesel fuel is under consideration in order to increase the share of fuels from renewable sources and to reduce greenhouse gas emissions. In Europe, commercial diesel fuels already contain up to 7% biodiesel. Higher biodiesel blends or the use of pure biodiesel are probable measures to further increase the share of fuels from renewable sources. Due to its different feedstock and refining process, the specification of biodiesel reveals some important distinctions in comparison with standard diesel fuel. The current work aims to discuss the possible implications of biodiesel utilization on the aftertreatment systems of recent heavy-duty diesel (HDD) vehicles compliant with EURO VI legislation. In particular, the effect of biodiesel on heat-up operation, i.e., the increase of the exhaust gas temperature by catalytic combustion of fuel within a diesel oxidation catalyst (DOC), is investigated.
Technical Paper

Catalyst Technologies for Gasoline Engines with Respect to CO2 Reduction

2011-01-19
2011-26-0027
Besides the further reduction of the harmful gaseous emissions (HC, CO and NOx) to reach upcoming emission limits, the discussion on lowering the CO₂ emissions is omnipresent. From engine development point of view further optimization of the stoichiometric-operated gasoline engine as well as the introduction of lean-operated engines are the main development trend. The emission control system can support the engine development by dedicated catalyst technologies as presented in this paper. A new family of TWC technologies offers to tune the catalyst system to the engine performance and the back pressure requirement - which helps to reduce CO₂ emissions. In addition these technologies show improved performance in HC, CO, NOx light-off, and in CO and NOx conversions under dynamic conditions - this again can positively impact the CO₂ emissions as less harsh heating strategies for cold start is required.
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