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This study investigated neat n-butanol combustion, emissions and thermal efficiency characteristics in a compression ignition (CI) engine by using two fuelling techniques - port fuel injection (PFI) and direct injection (DI). Diesel fuel was used in this research for reference. The engine tests were conducted on a single-cylinder four-stroke DI diesel engine with a compression ratio of 18.2 : 1. An n-Butanol PFI system was installed to study the combustion characteristics of Homogeneous Charge Compression Ignition (HCCI). A common-rail fuel injection system was used to conduct the DI tests with n-butanol and diesel. 90 MPa injection pressure was used for the DI tests. The engine was run at 1500 rpm. The intake boost pressure, engine load, exhaust gas recirculation (EGR) ratio, and DI timing were independently controlled to investigate the engine performance.