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Technical Paper

An Optimal Usage of Nox in a Combined Pt/Ceramic Foam and a Wall-Flow Monolith Filter for an Effective Nox-Assisted Diesel Soot Oxidation

2003-03-03
2003-01-0379
For the NOx-assisted diesel soot abatement, the trend of decreasing engine-out NOx emission will become a serious threat unless NOx can effectively be utilised. A filter candidate consisting of Pt-containing ceramic foam and a wall-flow monolith configuration (an optimised catalytic filter) is proposed to employ an optimal usage of NOx. By design this configuration is capable to employ two stages of filtration, namely: deep bed filtration on the foam and surface filtration on the wall-flow monolith. At the same time, two modes of soot oxidation reactions will operate. In Pt/ceramic foam multiple NO oxidation to NO2 and trapped diesel soot oxidation by NO2 take place, while part of NO2 is released as NO2-slip and this NO2-slip is subsequently utilised to oxidise trapped soot on a wall-flow monolith. In laboratory tests, this concept is clearly demonstrated that it outperforms the activity of conventional regenerating trap, based on upstream NO-NO2 conversion.
Technical Paper

Molten Salts Supported on Ceramic Foam in the Potential Application of a Diesel Soot Abatement Technology

2001-03-05
2001-01-0905
The physical state of a heterogeneous soot oxidation catalyst has a big impact on their performance. Contact between soot and solid catalysts is one of the key parameters for soot oxidation. Catalyst formulations based on low eutectic melting points were studied. Formulation based on cesiumsulfate and vanadiumoxide, became active at their melting point of 320-350 °C. Ceramic foam can act as support for the liquid catalyst as well as a deep filter for the soot. Downstream of a small diesel engine a balance temperature of 350 °C was established with an initial trapping efficiency of 40 %. Stable pressure drop over the system was maintained over a period of more than 24 hours.
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