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A novel Spatially Optimized Diffusion Alloy (SODA) material has been developed and applied to exhaust systems, which are an aggressive environment subject to high temperatures and loads, as well as excessive corrosion. Traditional stainless steels disperse chromium homogeneously throughout the material, with varying amounts ranging from 10% to 20% dependent upon its grade (e.g. 409, 436, 439, 441, and 304). SODA steels, however, offer layered concentrations of chromium, enabling an increased amount along the outer surface for much needed corrosion resistance and aesthetics. This outer layer, typically about 70μm thick, exceeds 20% of chromium concentration locally, but is less than 3% in bulk, offering selective placement of the chromium to minimize its overall usage. Since this layer is metallurgically bonded, it cannot delaminate or separate from its core, enabling durable protection throughout manufacturing processes and full useful life.

The purpose of this work was to initiate a comparative evaluation of the aqueous corrosion resistance of ferritic stainless steels currently used to fabricate automotive exhaust systems. Both acid condensate and double loop electrochemical potentiokinetic reactivation (DL-EPR) testing using both as-received and heat treated test coupons prepared from Types 409, 409Al, 436 and 439 stainless steel was conducted for this purpose. A truncated version of an in-house acid condensate testing protocol revealed that Type 409Al stainless steel was the most resistant to corrosion of the four ferritic stainless steels examined, whereas Type 409 stainless steel was the least resistance to corrosion.