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This paper deals with the combustion behavior and exhaust emissions of a small compression ignition engine modified to operate in diesel/methane dual fuel mode. The engine is a three-cylinder, 1028 cm3 of displacement, equipped with a common rail injection system. The engine is provided with the production diesel oxidation catalyst. Intake manifold was modified in order to set up a gas injector managed by an external control unit. Experiments were carried out at different engine speeds and loads. For each engine operating condition, the majority of the total load was supplied by methane while a small percentage of the load was realized using diesel fuel; the latter was necessary to ignite the premixed charge of gaseous fuel. Thermodynamical analysis of the combustion phase was performed by in-cylinder pressure signal. Gas emissions and particulate matter were measured at the exhaust by commercial instruments.