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Homogeneous Charge Compression Ignition (HCCI) combustion has attracted widespread interest as a combustion system that offers the advantages of high efficiency and low exhaust emissions. However, it is difficult to control the ignition timing in an HCCI combustion system owing to the lack of a physical means of initiating ignition like the spark plug in a gasoline engine or fuel injection in a diesel engine. Moreover, because the mixture ignites simultaneously at multiple locations in the cylinder, it produces an enormous amount of heat in a short period of time, which causes greater engine noise, abnormal combustion and other problems in the high load region. The purpose of this study was to expand the region of stable HCCI engine operation by finding a solution to these issues of HCCI combustion.

There are few investigations to change wood biomasses to the industrially available energy, so that a new conversion technology of biomass to liquid fuel has been established by the direct liquefaction process. However, cellulosic liquefaction fuel (for short CLF) cold not mixed with diesel fuel. In this study, the plastic was mixed with wood to improve the solubility of CLF to diesel fuel. CLF made by the direct co-liquefaction process could be stably and completely mixed with diesel fuel in any mixing ratio and CLF included 2 wt.% of oxygen. The test engine was an air-cooled, four-stroke, single cylinder, direct fuel injection diesel engine. In the engine starting condition test, the ignition timing of 5 wt.% CLF mixed diesel fuel was slightly delayed at immediately after the engine started, however the ignition timing was almost the same as diesel fuel after the engine was warmed-up.

The purpose of this study is to clarify ignition characteristics and engine performance of FAME for 4-stroke diesel engine in low compression ratios. Diesel fuel and coconut oil methyl ester (CME) were selected as test fuels, because CME consisted of saturate FAMEs which were good ignition characteristics. To reduce the compression ratio, thin copperplates were inserted between cylinder head and cylinder block and the compression ratio was reduced from 20.6 that was standard to 15. The engine starting test and an ordinary engine performance test were made at 3600 min.-₁. In engine starting test, the engine was soaked at room temperature and the ignition timing of diesel fuel was remarkably delayed compared with CME. When the compression ratio was 16, for diesel fuel, the misfiring cycles were included during engine warming up. In case of 15 of compression ratio, the engine could not be started by diesel fuel; however the engine could be run by CME.

The ignitability and engine performance of FAMEs at the cold condition were experimentally investigated by using two FAMEs, i.e. coconut oil methyl ester (CME) and soybean oil methyl ester (SME). The cold start test and forced over cooling test were conducted. In the forced over cooling test, engine was forced cooled by the injecting water mist to engine cooling fin. In the cold start test, the cylinder pressure of CME rose earliest because CME has a superior ignitability. The crank angle at ignitions of diesel fuel and CME were not so affected by the forced over cooling, however ignition timing of SME was remarkably delayed. In cases of forced over cooling, COV of maximum combustion pressure of CME was lower than that of normal air cooling condition. The forced over cooling has a potential to reduce NOx emission, however HC, CO and smoke concentrations were increased in a high load due to incomplete combustion.

The application of emulsified fuel for diesel engines is expected to reduce NOx and soot simultaneously. The purpose of this study is to clarify the influence of water content in emulsified fuel and fuel injection timing on diesel engine performance. The engine performance of emulsified fuel was compared with the water injection method. In the water injection test, water was injected to intake manifold and diesel fuel was directly injected into combustion chamber. Two emulsified fuels of which mixing ratio of water and emulsifier to diesel fuel were 15 and 30 vol.% were tested. Engine performance and exhaust gas emission of water injection method were almost similar to those of diesel fuel, so that water presented in combustion chamber had almost no influence on engine performance. Therefore, it can be considered that the micro explosion of fuel droplet enhanced the fuel atomization and mixing of fuel and air.

The composition ratio of saturated and unsaturated fatty acid methyl esters (FAME) is depended on feedstock. Three FAMEs: soybean (SME), palm (PME) and coconut oil (CME) methyl esters were mixed to make fuels which have different composition ratio. The ignitability of fuel which mainly consisted of unsaturated FAME was inferior. Power was slightly reduced with increasing of mixing ratio of CME; however exhaust gas emissions were improved because CME contained a lot of oxygen atoms. Fuel which was equal mixture SME and CME indicated almost the same ignition characteristic as that of PME because they have same composition ratio.

A new bio-fuel i.e. the cellulosic liquefaction fuel (CLF) was developed for diesel engines. CLF was made from woods by direct liquefaction process. When neat CLF was supplied to diesel engine, the compression ignition did not occur, so that blend of CLF and diesel fuel was used. The engine could be operated when the mixing ratio of CLF was up to 35 wt%. CO, HC and NOx emissions were almost the same as those of diesel fuel when the mixing ratio of CLF was less than 20 wt% whereas the thermal efficiency slightly decreases with increase in CLF mixing ratio.

The coconut-oil methyl ester is made from coconut oil and methanol, and both cold start performance and ignition characteristics of coconut-oil methyl ester are experimentally investigated by using a diesel engine. In experiments, diesel fuel and coconut-oil methyl ester are used and the blended ratio of coconut-oil methyl ester to diesel fuel is changed. The test is conducted at full load and 3000 rpm. The diesel engine can be run stably with any mixing ratio of coconut-oil methyl ester, however the power is slightly reduced with increasing the mixing ratio of coconut-oil methyl ester. In the cold start condition, when the mixing ratio of coconut-oil methyl ester increases, the combustion chamber wall temperature rises early and the ignition timing is improved. Therefore, the coconut-oil methyl ester has superior compression ignition characteristics and reduces exhaust gas emissions, so that the coconut-oil methyl ester is good alternative fuel for diesel engines.