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The effect of different fuel parameters on emissions is difficult to understand, the response depending upon different engine technologies. In addition the isolation of some of the fuel variables is often very hard. The present paper discusses the main results obtained testing a matrix of 14 fuels designed for obtain large variations of cetane number, sulphur and aromatic contents of Diesel oil. The aromatic structure of fuels and its effect on particulate emissions was also investigated. A linear regression analysis was performed in order to isolate the main controlling factors on particulate emissions. Finally the influence of aromatic contents of fuel on unregulated emissions was also assessed.

Three dimensional computations of Diesel combustion were performed using a modified version of Kiva II code. The autoignition and combustion model were tuned on a set of experimental conditions, changing the engine design, the operating conditions and the fuel characteristics. The sensitivity of the model to the different test cases is acceptable and the experimental trends are well reproduced. In addition the peak of pressure and temperature computed by the code are quite close to the experimental values, as well as the pressure derivatives. Once tuned the combustion model constants, different but simple formulations for the soot formation and oxidation processes were implemented in the code and compared with the experimental measurements obtained both with fast sampling technique and two colors method. These formulations were found unable to give good prediction in a large range of engine operating conditions, even if the model tuning may be very good for each test point.

Cetane number, sulphur content and aromatic structure of Automotive Diesel Oil (ADO) were changed to assess their influence on emissions of light duty direct injection Diesel engine. The detailed chemical analysis of particulate soluble fraction allows to quantify the P.A.Hs emission. In addition also the aldehydes and volatile organic compounds were measured in the gaseous phase. The sulphur content of the fuel and its aromatic structure strongly influence particulate emission. The insoluble fraction of the particulate rises with an increase of the high sulphur content ADOs with about the same back end volatility. Unburned P.A.Hs control P.A.Hs emission at the part loads typical of normalized schedules for emission testing of light duty vehicles in Europe. Finally the level of emissions of benzene and 1-3 butadiene is comparable to the total P.A.Hs emission.