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The objective of this work was to investigate the effect of fuel properties on atomization and spray structure of a diesel engine fuel injector, based on PDA (Phase Doppler Anemometry) measurements. Few studies have addressed the question of how fuels affect droplet size and spray structure. Thus three diesel fuels were selected: two which broadly represent the range of base fuel properties seen in current European fuels and a third which contained a high treat rate of a detergent-type additive, which, being polar, may have some surface effects which could impact spray formation. This range of diesel fuels was injected into a high pressure and temperature wind tunnel, using a single hole Bosch injector. Phase Doppler Anemometry (PDA) was used to measure the diameter, velocity and arrival time of spray droplets passing through numerous radial and longitudinal positions in the spray.