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Technical Paper

Role of Fuel Decomposition Products on Formation of Sequence IIIG Piston Deposits

2010-10-25
2010-01-2259
Previous research to understand the mechanism for piston deposit formation in the Sequence IIIG engine test has focused on characterizing the piston deposits. These studies concluded that, in addition to lubricant derived materials, Sequence IIIG piston deposits contain a significant amount of fuel-derived carbonaceous material. The presence of fuel degradation by-products in Sequence IIIG deposits shows that blow-by is a significant contributor to deposit formation. However, blow-by can either assist in the degradation of the lubricant or can simply be a source for organic material which can be incorporated into the deposits. Therefore, a series of modified Sequence IIIG engine tests were conducted to better determine the effect of blow-by on deposit formation. In these studies deposit formation on different parts of the piston assembly were examined since different parts of the piston assembly are exposed to different amounts of blow-by.
Technical Paper

Characterization of TEOST Deposits and Comparison to Deposits Formed on Sequence IIIG Pistons

2009-11-02
2009-01-2663
In the next ILSAC passenger car motor oil specification the Sequence IIIG engine test, as well as two versions of the Thermo-Oxidation Engine Oil Simulation Test (TEOST) have been proposed as tests to determine the ability of crankcase oils to control engine deposits. The Sequence IIIG engine test and the TEOST MHT test are designed to assess the ability of lubricants to control piston deposits and the TEOST 33 test is designed to assess the ability of lubricants to control turbocharger deposits. We have previously characterized the chemical composition of Sequence IIIG piston deposits using thermogravimetric, infrared and SEM/EDS analyses. Sequence IIIG piston deposits contain a significant amount of carbonaceous material and the carbonaceous material is more prevalent on sections of the pistons that should encounter higher temperatures. Furthermore, the carbonaceous material appears to be a deposit formed by the Sequence IIIG fuel.
Technical Paper

Characterization of Deposits Formed on Sequence IIIG Pistons

2005-10-24
2005-01-3820
In the latest passenger car motor oil specifications the Sequence IIIG engine test is used to determine the ability of lubricants to control piston deposits. We have analyzed the chemical composition of Sequence IIIG deposits in order to determine the source of the piston deposits and determine if the mechanism for deposit formation in the Sequence IIIG engine test is similar to previously published mechanisms for formation of high temperature engine deposits. These previous mechanisms show that combustion by-products react with lubricant in the piston ring zone. The mixture of combustion by-products and lubricant are oxidized to form deposit precursors which are further oxidized to form deposits. Since the Sequence IIIG engine test uses lead-free fuel it is important to reexamine the nature of piston deposits formed in gasoline engines and in particular in the Sequence IIIG engine test.
Technical Paper

Film Formation Properties of Polymers in the Presence of Abrasive Contaminants

2002-10-21
2002-01-2793
Emission requirements for all vehicles have become increasingly more stringent. Diesel engine design changes required to meet emissions requirements result in increased levels of soot in the lubricant. This increased level of soot causes increased wear when oils are not properly formulated. Recent studies have shown that the primary cause of wear in the crossheads of Cummins M-11 and M-11/EGR engines is the abrasive nature of primary soot particles. In addition, it has also been shown that oils, which form films that are thicker than the size of primary soot particles can prevent abrasive wear. Dispersants and dispersant-polymers are known to prevent wear in the presence of soot. The goal of this study is to better understand the role of dispersants and functionalized polymers on the prevention of wear by examining their ability to form films in the presence of abrasive contaminants.
Technical Paper

Low Temperature Rheological Properties of Aged Crankcase Oils

2000-10-16
2000-01-2943
The low-temperature pumpability of engine oil throughout the engine at startup is an important property. Insuring that fresh oils can be pumped at low temperatures has been a requirement of crankcase lubricants for approximately two decades. Extending the assurance of the oil's low temperature pumpability as it ages under engine operation has been the concern of car manufacturers and lubricant marketers for some time. In order to determine the factors influencing the aged oil's low temperature pumpability, we have undertaken a fleet test. We found that as lubricants are aged, excellent low temperature pumping properties can be maintained if lubricants are formulated with viscosity-index improvers incapable of forming polymer networks, base oils with a low tendency to form wax networks, effective pour-point depressants, and if oil drain intervals are not extended beyond the performance limitations of the specific lubricant category.
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