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PDF-equation approach have been extended and assessed for the diesel spray combustion computation. This approach accounts for the effects of gas turbulence and random dynamics of vaporizing liquid droplets on the chemistry. The combustion process including spray dynamics, evaporation, mixing and combustion have been treated using the combined KIVAII-PDF-equation model. Numerical computations were compared with the experimental data for spray self-ignition and combustion and with calculations using Eddy-Break-Up combustion model. Both the light-duty and heavy-duty diesel conditions have been operated in computations. Besides, the most probable self-ignition zone was computed and compared with experimental observation. It was showed that the developed here PDF model is abble to describe species concentrations, auto-ignition phenomenon and overall turbulent heat release significantly better than Eddy-Break-Up model.

A linked ignition-soot formation global kinetic model has been developed. The model has been adapted to the extended code CONCHAS-SPRAY. The so called Shell-model, which was successful in the representation of the ignition global kinetics has been used. Mass balanced reactions for the overall product path, soot formation and soot oxidation have been introduced. The feature to generate soot was prescribed to a stable hydrocarbon intermediate species typical for ignition. The soot surface growth rate was determined by experimental data of final soot volume fraction given by Wagner et al. for premixed flames. Soot oxidation rate is represented by Lee et al's formula. Turbulent transport properties are calculated with the help of the k-ε model. The numerical prediction of soot concentration level, generation of soot and resulting oxidation as well as a secondary soot formation at the spray axis have been demonstrated as being in qualitative agreement with known experimental data.