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Direct injected natural gas diesel engines are currently being developed. Numerical analyses results are presented for 20.0 MPa (≈ 3000 psia; 200 atm), 444 K, natural gas injection into 4.0 MPa cylinder air where the ambient turbulence field is representative of diesel engines. Two very important non-intuitive, observations are made. First, the seemingly reasonable spatially uniform velocity profile currently used at the injector exit is not appropriate, rather a double-hump profile is correct. Second, a spatially uniform, injector exit, temperature profile results in local temperature overestimates as large as 300 K. Considering the strong role of temperature on chemical kinetics, this second observation may have profound implications on the validity of conclusions reached using uniform exit profiles.

This work presents the autoignition delay time characteristics of methane and natural gas under simulated diesel engine conditions. A constant-volume combustion vessel is used for the experiments. Results are presented for the pressure and temperature ranges of 5 to 55 atm and 600 to 1700 K, respectively. Comparisons are then made with autoignition data for methanol, ethanol, isooctane, and n-cetane. Three major trends are observed. First, there is little effect on the autoignition delay time of natural gas as the vessel pressure is increased from 5 to 55 atm. Second, there is a slight decrease in the autoignition delay time of methane-ethane gas mixtures as the concentration of ethane is increased. Third, the autoignition delay time of natural gas is strongly dependent on temperature and continually decreases with increasing temperature.