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Journal Article

Development of Clean Diesel NOx After-treatment System with Sulfur Trap Catalyst

2010-04-12
2010-01-0303
Diesel engines with relatively good fuel economy are known as an effective means of reducing CO₂ emissions. It is expected that diesel engines will continue to expand as efforts to slow global warming are intensified. Diesel particulate and NOx reduction system (DPNR), which was first developed in 2003 for introduction in the Japanese and European markets, shows high purification performance which can meet more stringent regulations in the future. However, it is poisoned by sulfur components in exhaust gas derived from fuel and lubricant. We then developed the sulfur trap DPNR with a sulfur trap catalyst that traps sulfur components in the exhaust gas. High purification performance could be achieved with a small amount of platinum group metal (PGM) due to prevention of sulfur poisoning and thermal deterioration.
Technical Paper

Effect of Sulfur-free and Aromatics-free Diesel Fuel on Vehicle Exhaust Emissions using Simultaneous PM and NOx Reduction System

2003-05-19
2003-01-1865
A new diesel after-treatment system, Diesel Particulate and NOx Reduction System (DPNR), is being developed for reducing PM and NOx emissions. We examined the effects of sulfur content in lubricants on exhaust NOx emission from DPNR catalyst, and examined the PM reduction ability using sulfur-free and aromatics-free fuel. After vehicle durability testing of 40,000 km without forced regeneration of PM and sulfur poisoning on DPNR catalyst, deterioration of DPNR was lower than using higher sulfur contents in fuel and oil. In addition to decreasing fuel sulfur, decreasing oil sulfur was also effective to maintain high NOx conversion efficiency. Although the catalyst was poisoned by sulfur in the lubricants, the influence of oil sulfur poisoning on the catalyst was lower than fuel sulfur poisoning. On the other hand, engine out PM emissions decreased by 70 % because of aromatics-free fuel. The pressure drop of DPNR did not increase during the 40,000 km vehicle durability test.
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