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We used a one-dimensional monolithic catalyst model to predict the transient thermal and conversion characteristics of a dual monolithic catalytic converter with a Palladium only (Pd-only) catalyst and a Palladium/Rhodium (Pd/Rh) catalyst. Prior to the numerical investigation of the dual-catalyst converter, we modified the pre-exponential factor and activation energy of each reaction for both catalysts to achieve acceptable agreement with experimental data under typical operating conditions of automobile applications. We validated the conversion behavior of the lumped parameter model for each catalyst against different engine operating conditions. Two higher cell density substrates, Pd-only catalyst (600cpsi/3.9mil) and Pd/Rh catalyst (600cpsi/4mil), for faster light-off and improved warm-up performance are used in this study and the two monoliths has been connected without the space between monoliths.

In the past few years, considerable efforts have been directed towards the further development of Urea-SCR(selective catalytic reduction) technique for diesel-driven vehicle. Although urea possesses considerable advantages over Ammonia(NH3) in terms of toxicity and handling, its necessary decomposition into Ammonia and carbon dioxide complicates the DeNOx process. Moreover, a mobile SCR system has only a short distance between engine exhaust and the catalyst entrance. Hence, this leads to not enough residence times of urea, and therefore evaporation and thermolysis can not be completed at the catalyst entrance. This may cause high secondary emissions of Ammonia and isocyanic acid from the reducing agent and also leads to the fact that a considerable section of the catalyst may be misused for the purely thermal steps of water evaporation and thermolysis of urea.