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Technical Paper

Development of Time-Temperature Analysis Algorithm for Estimation of Lithium-Ion Battery Useful Life

2024-04-09
2024-01-2191
Due to the recent progress in electrification, lithium-ion batteries have been widely used for electric and hybrid vehicles. Lithium-ion batteries exhibit high energy density and high-power density which are critical for vehicle development with high driving range enhanced performance. However, high battery temperature can negatively impact the battery life, performance, and energy delivery. In this paper, we developed and applied an analytical algorithm to estimate battery life-based vehicle level testing. A set of vehicle level tests were selected to represent customer duty cycles. Thermal degradation models are applied to estimate battery capacity loss during driving and park conditions. Due to the sensitivity of Lithium-Ion batteries to heat, the effect of high ambient temperatures throughout the year is considered as well. The analysis provides an estimate of the capacity loss due to calendar and cyclic effects throughout the battery life.
Technical Paper

Sequence Training and Data Shuffling to Enhance the Accuracy of Recurrent Neural Network Based Battery Voltage Models

2024-04-09
2024-01-2426
Battery terminal voltage modelling is crucial for various applications, including electric vehicles, renewable energy systems, and portable electronics. Terminal voltage models are used to determine how a battery will respond under load and can be used to calculate run-time, power capability, and heat generation and as a component of state estimation approaches, such as for state of charge. Previous studies have shown better voltage modelling accuracy for long short-term memory (LSTM) recurrent neural networks than other traditional methods (e.g., equivalent circuit and electrochemical models). This study presents two new approaches – sequence training and data shuffling – to improve LSTM battery voltage models further, making them an even better candidate for the high-accuracy modelling of lithium-ion batteries. Because the LSTM memory captures information from past time steps, it must typically be trained using one series of continuous data.
Technical Paper

Development and Validation of Cycle and Calendar Aging Model for 144Ah NMC/Graphite Battery at Multi Temperatures, DODs, and C-Rates

2023-04-11
2023-01-0503
As compared with other batteries, lithium-ion batteries are featured by high power density, long service life, high energy density, environmental friendliness and thus have found wide application in the area of consumer electronics. However, lithium-ion batteries for electric and hybrid electric vehicles (EVs and HEVs) have high capacity and large serial-parallel numbers, which, coupled with such problems as safety, durability, cost and uniformity, imposes limitations on the wide application of lithium-ion batteries in the EVs and HEVs. The narrow area in which lithium-ion batteries operate with safety and reliability necessitates the effective control and through the use of management of battery management system. Battery state of health (SOH) monitoring has become a crucial challenge in EVs and HEVs research, as SOH significantly affects the overall vehicle performance and life cycle. This paper presents both cycling and calendar aging at high and low temperatures.
Technical Paper

Transient Electrochemical Modeling and Performance Investigation Under Different Driving Conditions for 144Ah Li-ion Cell with Two Jelly Rolls

2023-04-11
2023-01-0513
Recently, the automotive industry has experienced rapid growth in powertrain electrification, with more and more battery electric vehicles (BEV) and hybrid electric vehicles being launched. Lithium-ion batteries play an important role due to their high energy capacity and power density, however they experience high heat generation in their operation, and if not properly cooled it can lead to serious safety issues as well as lower performance and durability. In that way, good prediction of a battery behavior is crucial for successful design and management. This paper presents a 1D electrochemical model development of a 144 Ah prismatic rolled cell using the GT-Autolion software with a pseudo 2D approach. The model correlation is done at cell level comparing model results and test data of cell open circuit voltage at different temperatures and voltage and temperature profile under different C-rates and ambient temperatures.
Technical Paper

Numerical Analysis of Battery Thermal Management System Using Passive Cooling Technique

2023-03-07
2023-01-0990
Nowadays electric vehicle is replacing internal combustion engines in the transport sector. The growth of electric vehicles is increasing rapidly to reduce the impact of global warming and climate change. The battery limits the use of electric vehicles as an exact alternative to traditional IC engine vehicles. Specifically, the operating temperature, charge/discharge rates, and internal heat generation of the battery the performance of electric vehicles, like the driving range, charge storage capacity, the cycle life of the battery, and thermal runaway occurring at high temperatures. To overcome these problems, the battery thermal management system (BTMS) controls the temperature of the battery and maintains the optimal temperature to operate the battery efficiently and safely. In the heights of the above facts, the numerical analysis of 18650 Li-ion battery thermal management systems by passive cooling technology using Phase Change Material (PCM).
Technical Paper

3D FEA Thermal Modeling with Experimentally Measured Loss Gradient of Large Format Ultra-Fast Charging Battery Module Used for EVs

2022-03-29
2022-01-0711
A large amount of heat is generated in electric vehicle battery packs during high rate charging, resulting in the need for effective cooling methods. In this paper, a prototype liquid cooled large format Lithium-ion battery module is modeled and tested. Experiments are conducted on the module, which includes 31Ah NMC/Graphite pouch battery cells sandwiched by a foam thermal pad and heat sinks on both sides. The module is instrumented with twenty T-type thermocouples to measure thermal characteristics including the cell and foam surface temperature, heat flux distribution, and the heat generation from batteries under up to 5C rate ultra-fast charging. Constant power loss tests are also performed in which battery loss can be directly measured.
Technical Paper

A Comparative Study between Physics, Electrical and Data Driven Lithium-Ion Battery Voltage Modeling Approaches

2022-03-29
2022-01-0700
This paper benchmarks three different lithium-ion (Li-ion) battery voltage modelling approaches, a physics-based approach using an Extended Single Particle Model (ESPM), an equivalent circuit model, and a recurrent neural network. The ESPM is the selected physics-based approach because it offers similar complexity and computational load to the other two benchmarked models. In the ESPM, the anode and cathode are simplified to single particles, and the partial differential equations are simplified to ordinary differential equations via model order reduction. Hence, the required state variables are reduced, and the simulation speed is improved. The second approach is a third-order equivalent circuit model (ECM), and the third approach uses a model based on a Long Short-Term Memory Recurrent Neural Network (LSTM-RNN)). A Li-ion pouch cell with 47 Ah nominal capacity is used to parameterize all the models.
Technical Paper

Degradation Testing and Modeling of 200 Ah LiFePO4 Battery

2018-04-03
2018-01-0441
In this paper, a degradation testing of a lithium-ion battery used for an electric vehicle (EV) is performed and the capacity fade is measured over 400 cycles. For this, a 200 Ah LiFePO4 battery cell is tested under ambient temperature conditions with charge-discharge cycles at rate of 1C (constant current). Additionally, individual cell characterization is conducted using a C/25 (0.8A) charge-discharge cycle and hybrid pulse power characterization (HPPC). Later, the Thevenin battery model was constructed in MATLAB along with an empirical degradation model and validated in terms of voltage for all cycles. It is also found that the presented model closely estimated the profiles observed in the experimental data. Data collected from the experimental results showed that a capacity fade occurred over the 400 cycles and the discharge capacity at the end of 400th cycle is found to be 137.73 Ah. The error between model/experiments is found to be less than 3.5% for all cycles.
Technical Paper

Measurement of Temperature Gradient (dT/dy) and Temperature Response (dT/dt) of a Prismatic Lithium-Ion Pouch Cell with LiFePO4 Cathode Material

2017-03-28
2017-01-1207
Lithium-ion batteries, which are nowadays common in laptops, cell phones, toys, and other portable electronic devices, are also viewed as a most promising advanced technology for electric and hybrid electric vehicles (EVs and HEVs), but battery manufacturers and automakers must understand the performance of these batteries when they are scaled up to the large sizes needed for the propulsion of the vehicle. In addition, accurate thermo-physical property input is crucial to thermal modeling. Therefore, a designer must study the thermal characteristics of batteries for improvement in the design of a thermal management system and also for thermal modeling. This work presents a purely experimental thermal characterization in terms of measurement of the temperature gradient and temperature response of a lithium-ion battery utilizing a promising electrode material, LiFePO4, in a prismatic pouch configuration.
Journal Article

Thermal Management of Lithium-Ion Pouch Cell with Indirect Liquid Cooling using Dual Cold Plates Approach

2015-04-14
2015-01-1184
The performance, life cycle cost, and safety of electric and hybrid electric vehicles (EVs and HEVs) depend strongly on their energy storage system. Advanced batteries such as lithium-ion (Li-ion) polymer batteries are quite viable options for storing energy in EVs and HEVs. In addition, thermal management is essential for achieving the desired performance and life cycle from a particular battery. Therefore, to design a thermal management system, a designer must study the thermal characteristics of batteries. The thermal characteristics that are needed include the surface temperature distribution, heat flux, and the heat generation from batteries under various charge/discharge profiles. Therefore, in the first part of the research, surface temperature distribution from a lithium-ion pouch cell (20Ah capacity) is studied under different discharge rates of 1C, 2C, 3C, and 4C.
Technical Paper

Experimental Measurements of Thermal Characteristics of LiFePO4 Battery

2015-04-14
2015-01-1189
A major challenge in the development of the next generation electric and hybrid electric vehicle (EV and HEV) technology is the control and management of heat generation and operating temperatures. Vehicle performance, reliability and ultimately consumer market adoption are integrally dependent on successful battery thermal management designs. In addition to this, crucial to thermal modeling is accurate thermo-physical property input. Therefore, to design a thermal management system and for thermal modeling, a designer must study the thermal characteristics of batteries. This work presents a purely experimental thermal characterization of thermo-physical properties of a lithium-ion battery utilizing a promising electrode material, LiFePO4, in a prismatic pouch configuration. In this research, the thermal resistance and corresponding thermal conductivity of prismatic battery materials is evaluated.
Technical Paper

Modeling and Evaluation of Li-Ion Battery Performance Based on the Electric Vehicle Field Tests

2014-04-01
2014-01-1848
In this paper, initial results of Li-ion battery performance characterization through field tests are presented. A fully electrified Ford Escape that is equipped by three Li-ion battery packs (LiFeMnPO4) including an overall 20 modules in series is employed. The vehicle is in daily operation and data of driving including the powertrain and drive cycles as well as the charging data are being transferred through CAN bus to a data logger installed in the vehicle. A model of the vehicle is developed in the Powertrain System Analysis Toolkit (PSAT) software based on the available technical specification of the vehicle components. In this model, a simple resistive element in series with a voltage source represents the battery. Battery open circuit voltage (OCV) and internal resistance in charge and discharge mode are estimated as a function of the state of charge (SOC) from the collected test data.
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