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Following the ongoing software development, the continuously increasing accuracy of 0D/1D-simulation of combustion engines and chemical mechanisms for the use in reaction kinetic calculation open up a new possibility to calculate combustion processes. Particularly combustion processes with high dependency on reaction kinetics, such as knocking events, can be predicted. The simulation of knock events further allows a characterization of the knock behavior of LNG mixtures. This paper focuses on 1D-simulative investigation of knocking events to determine the Service Methane Number of different LNG mixtures and their dependency on single gas components. This is realized with two different approaches, which are presented in this work. In the first approach, measurement data and a Three-Pressure-Analysis-model are used to describe the in-cylinder condition at inlet valve closes.

Liquefied natural gas (LNG) plays an increasingly important role as a climate-friendly fuel for a sustainable mobility. Compared to diesel, LNG has a CO2 reduction potential of around 20%. There is also the possibility of reducing GHG by adding biogas or synthetic natural gas. The Methane Number (MN) characterizes the knocking properties of gaseous fuels and was defined by AVL. There is no standardized measurement procedure for the MN. Instead, there are some algorithms to calculate the MN from the gas mixture composition. Most of them are based on the original AVL measurement data, e.g. the NPL algorithm. In the AVL study, the different knocking properties of n- and iso-components of the alkanes were not investigated. This paper focuses on the experimental investigation of the knock resistance of different alkanes in LNG mixtures and the improvement of the NPL algorithm based on these results.

Legislative and customer demands in terms of fuel consumption and emissions are an enormous challenge for the development of modern combustion engines. Downsizing in combination with turbocharging and direct injection is one way to increase efficiency and therefore meet the requirements. This results in a reduction of the displacement and thus the bore diameter. The emerging trends towards long-stroke engine design and hybridization make the use of small bore diameters in future gasoline engines a realistic scenario. The application of direct injection with small cylinder dimensions increases the probability of the interaction of liquid fuel with the cylinder walls, which may result in disadvantages concerning especially particulate emissions. This leads to the question which bore diameter is feasible without drawbacks concerning emissions as a result of wall wetting.

LNG is a fuel that is under increasing discussion for transport purposes. It differs from CNG because it often has a higher concentration of hydrocarbons > C4. This affects knocking in a negative way. The knocking properties of a gaseous fuel are characterized by the Methane Number (MN) which is defined as the methane content in a mixture of methane and hydrogen which has the same knocking properties as the gas under investigation. It was defined by AVL in the late 1960s. In contrast to the Octane or Cetane Number there is no standardized measurement procedure for the MN, because the equipment AVL used was unique and does not exist anymore. But AVL created a calculation methodology based on the large amount of data they had measured. There are several software implementations of this methodology. Further there are other algorithms which are not based on the AVL data. If an MN is measured on an arbitrary engine the result is called a Service Methane Number (SMN).