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To avoid frequent regeneration intervals leading to expeditious ageing of the catalyst and substantial fuel penalty for the owner, it is always desired to estimate the soot coming from diesel exhaust emission, the soot accumulated and burnt in the Diesel Particulate Filter (DPF). Certain applications and vehicle duty cycles cannot make use of the differential pressure sensor for estimating the soot loading in the DPF because of the limitations of the sensor tolerance and measurement accuracy. The physical soot model is always active and hence a precise and more accurate model is preferred to calibrate & optimize the regeneration interval. This paper presents the approach to estimate the engine-out soot and the accumulated soot in the DPF using a graphical calculation tool (AVL Concerto CalcGraf™).

Fuel injection is a key process influencing the performance of Gasoline Direct Injection (GDI) Engines. Injecting fuel at elevated temperature can initiate flash boiling which can lead to faster breakup, reduced penetration, and increased spray-cone angle. Thus, it impacts engine efficiency in terms of combustion quality, CO2, NOx and soot emission levels. This research deals with modelling of flash boiling processes occurring in gasoline fuel injectors. The flashing mass transfer rate is modelled by the advanced Hertz-Knudsen model considering the deviation from the thermodynamic-equilibrium conditions. The effect of nucleation-site density and its variation with degree of superheat is studied. The model is validated against benchmark test cases and a substantiated comparison with experiment is achieved.

Recently, a particle number (PN) limit was introduced in the European light-duty vehicles legislation. The legislation requires measurement of PN, and particulate mass (PM), from the full dilution tunnel with constant volume sampling (CVS). Furthermore, PN measurements will be introduced in the next stage of the European Heavy-Duty regulation. Heavy-duty engine certification can be done either from the CVS or from a partial flow dilution system (PFDS). For research and development purposes, though, measurements are often conducted from the raw exhaust, thereby avoiding the high installation costs of CVS and PFDS. Although for legislative measurements requirements exist regarding sampling and transport of the aerosol sample, such requirements do not necessarily apply for raw exhaust measurements. Thus, measurement differences are often observed depending on where in the experimental set up sampling occurs.

Particulate emissions cause adverse health effects and for this reason they are regulated since the 80s. Vehicle regulations cover particulate emission measurements of a model before its sale, known as type approval or homologation. For heavy-duty engines the emissions are measured on an engine dynamometer with steady state points and transient cycles. For light-duty vehicles (i.e. the full power train) the particulate emissions are assessed on a chassis dynamometer. The measurement of particulate emissions is conducted either by diluting the whole exhaust in a dilution tunnel with constant volume sampling or by extracting a small proportional part of the exhaust gas and diluting it. Particulate emissions are measured by passing part of the diluted exhaust aerosol through a filter paper. The increase of the weight of the filter is used to calculate the particulate matter mass (PM) emissions.

The particulate emissions of two brake systems were characterized in a dilution tunnel optimized for PM10 measurements. The larger of them employed a fixed caliper (FXC) and the smaller one a floating caliper (FLC). Both used ECE brake pads of the same lining formulation. Measured properties included gravimetric PM2.5 and PM10, Particle Number (PN) concentrations of both untreated and thermally treated (according to exhaust PN regulation) particles using Condensation Particle Counters (CPCs) having 23 and 10 nm cut-off sizes, and an Optical Particle Sizer (OPS). The brakes were tested over a section (trip-10) novel test cycle developed from the database of the Worldwide harmonized Light-Duty vehicles Test Procedure (WLTP). A series of trip-10 tests were performed starting from unconditioned pads, to characterize the evolution of emissions until their stabilization. Selected tests were also performed over a short version of the Los Angeles City Cycle.

Trends towards lower vehicle fuel consumption and smaller environmental impact will increase the share of Diesel hybrids and Diesel Range Extended Vehicles (REV). Because of the Diesel engine presence and the ever tightening soot particle emissions, these vehicles will still require soot particle emissions control systems. Ceramic wall-flow monoliths are currently the key players in the Diesel Particulate Filter (DPF) market, offering certain advantages compared to other DPF technologies such as the metal based DPFs. The latter had, in the past, issues with respect to filtration efficiency, available filtration area and, sometimes, their manufacturing cost, the latter factor making them less attractive for most of the conventional Diesel engine powered vehicles. Nevertheless, metal substrate DPFs may find a better position in vehicles like Diesel hybrids and REVs in which high instant power consumption is readily offered enabling electrical filter regeneration.

It is a big challenge how to satisfy both the purification of exhaust gas and the decrease of fuel penalty, that is, carbon-dioxide emission. Regarding the Diesel Particulate Filter (DPF) applied in the diesel after-treatment system, it must be effective for lowering the fuel penalty to prolong the interval and reduce the frequency of the DPF regeneration operation. This can be achieved by a DPF that has high Particulate Matter (PM) mass limit and high PM oxidation performance that is enough to regenerate the DPF continuously during the normal running operation. In this study, the examination of the pore structure of the wall of a DPF that could expand the continuous regeneration region in the engine operation map was carried out. Several porous materials with a wide range of pore structure were prepared and coated with a Mixed Oxide Catalyst (MOC). The continuous regeneration performance was evaluated under realistic conditions in the exhaust of a diesel engine.

Direct catalytic soot oxidation is expected to become an important component of future diesel particulate emission control systems. The development of advanced Catalytic Diesel Particulate Filters (CDPFs relies on the interplay of chemistry and geometry in order to enhance soot-catalyst proximity. An extensive set of well-controlled experiments has been performed to provide direct catalytic soot oxidation rates in CDPFs employing small-scale side-stream sample exposure. The experiments are analyzed with a state-of-the-art diesel particulate filter simulator and a set of kinetic parameters are derived for direct catalytic soot oxidation by fuel-borne catalysts as well as by catalytic coatings. The influence of soot-catalyst proximity, on catalytic soot oxidation is found to be excellently described by the so-called Two-Layer model, developed previously by the authors.

Novel catalytic coatings with a variety of methods based on conventional and novel synthesis routes are developed for Diesel Particulate Filters (DPFs). The developed catalytic composition exhibits significant direct soot oxidation as evaluated by reacting mixtures of diesel soot and catalyst powders in a thermogravimetric analysis apparatus (TGA). The catalyst composition was further deposited on oxide and non-oxide porous filter structures that were evaluated on an engine bench with respect to their filtration efficiency, pressure drop behavior and direct soot oxidation activity under realistic conditions. The effect of the catalyst amount on the filtration efficiency of non-oxide filters was also investigated. Evaluation of the indirect soot oxidation was conducted on non-oxide catalytic filters coated with precious metal.

The regulation of particle number (PN) has been introduced in the Euro 5/6 light-duty vehicle legislation, as a result of the light duty inter-laboratory exercise of the Particle Measurement Program (PMP). The heavy-duty inter-laboratory exercise investigates whether the same or a similar procedure can be applied to the heavy-duty regulation. In the heavy-duty exercise two "golden" PN systems sample simultaneously; the first from the full dilution tunnel and the second from the partial flow system. One of the targets of the exercise is to compare the PN results from the two systems. In this study we follow a different approach: We use a PMP compliant system at different positions (full flow, partial flow and tailpipe) and we compare its emissions with a "reference" system always sampling from the full flow dilution tunnel.

The DEXA Cluster consisted of three closely interlinked projects. In 2003 the DEXA Cluster concluded by demonstrating the successful development of critical technologies for Diesel exhaust particulate after-treatment, without adverse effects on NOx emissions and maintaining the fuel economy advantages of the Diesel engine well beyond the EURO IV (2000) emission standards horizon. In the present paper the most important results of the DEXA Cluster projects in the demonstration of advanced particulate control technologies, the development of a simulation toolkit for the design of diesel exhaust after-treatment systems and the development of novel particulate characterization methodologies, are presented. The motivation for the DEXA Cluster research was to increase the market competitiveness of diesel engine powertrains for passenger cars worldwide, and to accelerate the adoption of particulate control technology.

Diesel Particulate Filter (DPF) behavior depends strongly on the microstructural properties of the deposited soot aggregates. In the past the issue of the growth process of soot deposits in honeycomb ceramic filters has been addressed under non-reactive conditions and the influence of the filter operating conditions has been defined in terms of the dimensionless Peclet number. In the present work appropriate soot cake microstructural descriptors are studied under reactive conditions for different oxidation modes. To this end the effect of deposit microstructure on the soot oxidation kinetics is investigated. Different microstructural models for the reacting soot deposit are examined in a unified fashion and a generalized constitutive equation is obtained, describing several modes of microstructure evolution (shrinking layer, shrinking density, discrete columnar and continuous columnar).

A major challenge in the development of diesel filter systems is the selection of the appropriate filter medium in terms of its geometric configuration (cell density, wall thickness) and its physical properties (porosity, pore size). This selection aims to achieve minimization of the filter pressure drop as well as more efficient filter regeneration. The aim of the present work is to provide engineering criteria to support the design and selection of suitably sized wall-flow monolithic filters for diesel particulate control.

The reduction of particulate emissions limits requires new tools for the tuning of engines and exhaust aftertreatment systems. Time-resolved monitoring of low soot emissions is a key feature for such developments. The paper describes an improved photoacoustic soot sensor, and presents its applications for the characterization of transient exhaust soot emissions before and after Diesel emission after-treatment systems. The detection limit of the unit is around 5 μg/m3 soot, which is two orders of magnitude better than conventional time-resolved transmission measurement. Additionally, a wide dynamic range of four orders of magnitude can be achieved without range switching. The photoacoustic signal is proportional to the soot mass, no significant cross-sensitivities to gaseous absorbers were detected.

Emission standards as proposed in Europe and the United States for heavy duty diesel engines will require a NOx and particulate reduction of more than 90%. This cannot be achieved by internal engine measures alone. Aftertreatment systems, for either one or both emission components, plus sophisticated electronic control strategies will be required. Various strategies to comply with EU 4, 5 and US 2007 are discussed, also showing their impact on engine performance. For typical 1 and 2 liter per cylinder engines, emission reduction concepts are assessed to identify the most suitable technology for major worldwide markets. The assessment is based on thermodynamic studies, test-bed results and estimates on cost and infrastructure implications.

The internal combustion engines, and the heavy duty truck diesel engines in particular, are facing a severe challenge to cope with the upcoming stringent emission legislation world-wide. To comply with these low limits, engine internal measures must be complemented with exhaust gas aftertreatment systems with sophisticated electronic control. A reduction of NOx and particulate emission of more than 90% is required. Various strategies to comply with Euro 4, 5 and US 2007 are discussed, also in view of engine performance, fuel economy and cooling system load. Recommendations are given for the most suitable approach to comply also in future with emission legislation in Europe and the United States.

In the near future the effort on the development of exhaust gas treatment systems must be increased to meet the stringent emission requirements. If the relevant physical and chemical models are available, the numerical simulation is an important tool for the design of these systems. This work presents a CFD model that allows to cover the full range of applications in this area. After a detailed presentation of the theoretical background and the modeling strategies results for the simulation of a close-coupled catalyst are shown. The presented model is also applied to the oxidation of nitrogen oxides, to a diesel particle filter and a fuel-cell reformer catalyst.

Partial flow sampling methods in emissions testing are interesting and preferred because of their lower cost, smaller size and applicability to engines of all sizes. However the agreement of the results obtained with instruments based on this method to those obtained with the traditional, large tunnel full flow sampling systems needs to be achieved, and the factors of construction that influence this agreement must be understood. These issues have received more attention lately in connection with ISO and WHDC standardization efforts underway to achieve a world-wide harmony in the sampling methods for heavy duty diesel engines, and with the introduction of similar Bag-minidiluter techniques into light duty SULEV gaseous pollutant measurement. This paper presents the theory and practice of a partial flow probe and tunnel design that addresses and minimizes the undesirable effects of the necessary differences between the two sampling methods.

As demand for wall-flow Diesel particulate filters (DPF) increases, accurate predictions of DPF behavior, and in particular of the accumulated soot mass, under a wide range of operating conditions become important. This effort is currently hampered by a lack of a systematic knowledge of the accumulated particulate deposit microstructural properties. In this work, an experimental and theoretical study of the growth process of soot cakes in honeycomb ceramic filters is presented. Particular features of the present work are the application of first- principles measurement and simulation methodology for accurate determination of soot cake packing density and permeability, and their systematic dependence on the filter operating conditions represented by the Peclet number for mass transfer. The proposed measurement methodology has been also validated using various filters on different Diesel engines.

A TGDI (turbocharged gasoline direct injection) engine is developed to realize both excellent fuel economy and high dynamic performance to guarantee fun-to-drive. In order to achieve this target, it is of great importance to develop a superior combustion system for the target engine. In this study, CFD simulation analysis, steady flow test and transparent engine test investigation are extensively conducted to ensure efficient and effective design. One dimensional thermodynamic simulation is firstly conducted to optimize controlling parameters for each representative engine operating condition, and the results serve as the input and boundary condition for the subsequent Three-dimensional CFD simulation. 3D CFD simulation is carried out to guide intake port design, which is then measured and verified on steady flow test bench.