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Journal Article

Friction and Film-Formation Properties of Oil-Soluble Inorganic Nanoparticles

2008-10-06
2008-01-2460
Many vehicle and engine test studies have shown that the fuel efficiency of automobiles can be improved by reducing friction between moving parts. Typically, organic friction modifiers such as glycerol monooleate (GMO) or metal containing friction modifiers such as molybdenum dithiocarbamate (MoDTC) have been added to engine oils to reduce boundary friction and improve fuel efficiency. These traditional friction modifiers act by forming either a self-assembled organic film (in the case of GMO) or a Mo-disulfide chemical film (in the case of MoDTC). More recently, the ability of inorganic tungsten disulfide (WS2) nanoparticles to reduce boundary friction has been described. Martin has proposed that WS2 nanoparticles are transported into a contact zone where they are compressed and peel open like an onion to form a film. In this study, oil-soluble inorganic nanoparticles containing cerium (Ce) and zinc (Zn) have been synthesized.
Technical Paper

Developing Transmission Fluids with Enhanced Durability

2007-10-29
2007-01-3986
1 Fluids for new generations of step-automatic transmissions must provide durable service under severe conditions in a variety of environments. Fluid degradation under severe stress can lead to changes in frictional properties, potentially resulting in undesirable noise, vibration and harshness (NVH) events. This paper describes the development of a new transmission fluid that delivers significant improvement in squawk durability. The formulation approach resulted in optimum friction characteristics that are essential to overcome stress-induced loss of friction and to reduce NVH. A factorial design of experiments was used in the development process to relate additive effects with friction characteristics of both fresh and aged fluids. Friction durability after laboratory aging was compared with friction characteristics and durability data obtained from field-aged fluids
Technical Paper

Characterization of Deposits Formed on Sequence IIIG Pistons

2005-10-24
2005-01-3820
In the latest passenger car motor oil specifications the Sequence IIIG engine test is used to determine the ability of lubricants to control piston deposits. We have analyzed the chemical composition of Sequence IIIG deposits in order to determine the source of the piston deposits and determine if the mechanism for deposit formation in the Sequence IIIG engine test is similar to previously published mechanisms for formation of high temperature engine deposits. These previous mechanisms show that combustion by-products react with lubricant in the piston ring zone. The mixture of combustion by-products and lubricant are oxidized to form deposit precursors which are further oxidized to form deposits. Since the Sequence IIIG engine test uses lead-free fuel it is important to reexamine the nature of piston deposits formed in gasoline engines and in particular in the Sequence IIIG engine test.
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