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Emissions of nitrogen oxides (NOx) from heavy-duty diesel engines are subject to more stringent environmental legislation. Selective catalytic reduction (SCR) over metal ion-exchanged zeolites is in this connection an efficient method to reduce NOx. Understanding durability of the SCR catalyst is crucial for correct design of the aftertreatment system. In the present paper, thermal and chemical ageing of Fe-BEA as NH3-SCR catalyst is studied. Experimental results of hydrothermal ageing, and chemical ageing due to phosphorous and potassium exposure are presented. The catalyst is characterized by flow reactor experiments, nitrogen physisorption, DRIFTS, XRD, and XPS. Based on the experimental results, a multisite kinetic model is developed to describe the activity of the fresh Fe-BEA catalyst.

The effect of ammoniac deoxidizing agent (Urea) on the reduction of NOx produced in the Diesel engine was investigated numerically. Urea desolved in water was directly injected into the engine cylinder during the expansion stroke. The NOx deoxidizing process was described using a simplified chemical kinetic model coupled with the comprehensive kinetics of Diesel oil surrogate combustion. If the technology of DWI (Direct Water Injection) with the later injection timing is supposed to be used, the deoxidizing reactants could be delivered in a controlled amount directly into the flame plume zones, where NOx are forming. Numerical simulations for the Isotta Fraschini DI Diesel engine are carried out using the KIVA-3V code, modified to account for the “co-fuel” injection and reaction with combustion products. The results showed that the amount of NOx could be substantially reduced up to 80% with the injection timing and the fraction of Urea in the solution optimized.

In order to acquire knowledge about temperature vs. equivalence ratio, T-ϕ, conditions in which emissions are formed and destroyed, T-ϕ parametric maps were constructed for: 1 Soot and soot precursors (C2H2) 2 Nitrogen oxides (NO and NO2) 3 Unburnt intermediates (CH2O, H2 and CO) 4 Important radicals (HO2 and OH) Each map was obtained by plotting data from a large number of simulations for various T-ϕ combinations in a zero-dimensional, 0D, closed Perfectly Stirred Reactor, PSR. Initially, the influences of elapsed reaction time, pressure and EGR level were examined, varying one parameter at a time. Then, since both the elapsed time and pressure change in an engine cycle, the maps were constructed according to engine pressure traces obtained from Computational Fluid Dynamics, CFD, simulations. Since the pressure is changing in elapsed time intervals the maps are called transient.

In order to meet future emissions legislation for Diesel engines and reduce their CO2 emissions it is necessary to improve diesel combustion by reducing the emissions it generates, while maintaining high efficiency and low fuel consumption. Advanced injection strategies offer possible ways to improve the trade-offs between NOx, PM and fuel consumption. In particular, use of high EGR levels (⥸ 40%) together with multiple injection strategies provides possibilities to reduce both engine-out NOx and soot emissions. Comparisons of optical engine measurements with CFD simulations enable detailed analysis of such combustion concepts. Thus, CFD simulations are important aids to understanding combustion phenomena, but the models used need to be able to model cases with advanced injection strategies.

The expansion of current driving cycles for emission regulations to higher load operation in the near future (such as the US06 supplement to the FTP-75 driving cycle) requires attention to low emission combustion concepts in medium to high load regimes. One possibility to reduce NO emissions is to increase the EGR rate. The combustion-temperature reducing effects of high EGR rates can significantly reduce NO formation, to the point where engine-out NOx emissions approach zero levels. However, engine-out soot and CO emissions typically increase at high EGR levels, due to the reduced soot and CO oxidation rates at reduced combustion temperatures and oxygen concentrations. The work presented in this paper focuses on different strategies to reduce soot and CO emissions associated with EGR rates of up to 50%, at which NO formation is largely avoided, but combustion temperatures are not low enough to consider the process as Low-Temperature Combustion (LTC).

Soot formation and oxidation are complex and competing processes during diesel combustion. The balance between the two processes and their history determines engine-out soot values. Besides the efforts to lower soot formation with measures to influence the flame lift-off distance for example or to use HCCI-combustion, enhancement of late soot oxidation is of equal importance for low-λ diffusion-controlled low emissions combustion with EGR. The purpose of this study is to investigate soot oxidation in a heavy duty diesel engine by statistical analysis of engine data and in-cylinder endoscopic high speed photography together with CFD simulations with a main focus on large scale in-cylinder gas motion. Results from CFD simulations using a detailed soot model were used to reveal details about the soot oxidation.

The possibilities of operating a direct injection Diesel engine in HCCI combustion mode with early injection of conventional Diesel fuel were investigated. In order to properly phase the combustion process in the cycle and to prevent knock, the geometric compression ratio was reduced from 17.0:1 to 13.4:1 or 11.5:1. Further control of the phasing and combustion rate was achieved with high rates of cooled EGR. The engine used for the experiments was a single cylinder version of a modern passenger car type common rail engine with a displacement of 480 cc. An injector with a small included angle was used to prevent interaction of the spray and the cylinder liner. In order to create a homogeneous mixture, the fuel was injected by multiple short injections during the compression stroke. The low knock resistance of the Diesel fuel limited the operating conditions to low loads. Compared to conventional Diesel combustion, the NOx emissions were dramatically reduced.

The influence of ethanol content in gasoline on speciated emissions from a direct injection stratified charge (DISC) SI engine is assessed. The engine tested is a commercial DISC one that has a wall guided combustion system. The emissions were analyzed using both Fourier transform infrared (FTIR) spectroscopy and conventional emission measurement equipment. Seven fuels were compared in the study. The first range of fuels was of alkylate type, designed to have 0, 5, 10 and 15 % ethanol in gasoline without changing the evaporation curve. European emissions certification fuel was tested, with and without 5 % ethanol, and finally a specially blended high volatility gasoline was also tested. The measurements were conducted at part-load, where the combustion is in stratified mode. The engine used a series engine control unit (ECU) that regulated the fuel injection, ignition and exhaust gas recirculation (EGR).

A validation study of the numerical model of n-heptane spray combustion based on experimental constant-volume data [1] was done, by comparing auto-ignition delays for different pre - turbulence levels and initial temperatures, flame contours, and soot distributions under Diesel-like conditions. The basic novelty of the methodology developed in [2] - [3] is the implementation of the partially stirred reactor (PaSR) model accounting for detailed chemistry / turbulence interactions. It is based on the assumption that the chemical processes proceed in two successive steps: micro mixing, simulated on a sub - grid scale, is followed by the reaction act. When the all Re number RNG k-ε or LES models are employed, the micro mixing time can be consistently defined giving the combustion model a “well-closed” form incorporated into the KIVA-3V code.

A single cylinder, naturally aspirated, four-stroke and camless (Otto) engine was operated in homogeneous charge compression ignition (HCCI) mode with commercial gasoline. The valve timing could be adjusted during engine operation, which made it possible to optimize the HCCI engine operation for different speed and load points in the part-load regime of a 5-cylinder 2.4 liter engine. Several tests were made with differing combinations of speed and load conditions, while varying the valve timing and the inlet manifold air pressure. Starting with conventional SI combustion, the negative valve overlap was increased until HCCI combustion was obtained. Then the influences of the equivalence ratio and the exhaust valve opening were investigated. With the engine operating on HCCI combustion, unthrottled and without preheating, the exhaust valve opening, the exhaust valve closing and the intake valve closing were optimized next.

Simulations of a Direct Injection Spark Ignition (DISI) engine have been performed for both early injection with homogeneous charge combustion and for late injection with stratified charge combustion. The purpose has been to study flow characteristics, fuel/air mixing, combustion, and NOx and soot formation. Focus is put on the combustion modeling. Two different full load cases with early injection are simulated, 2000 rpm and 6000 rpm. One load point with late injection is simulated, 2000 rpm and 2.8 bar net MEP. Three different injection timings are simulated at the low load point: 77, 82, and 87 CAD bTDC. The spray simulations are tuned to match measured spray penetrations and droplet size distributions at both atmospheric and elevated pressure. Boundary conditions for the engine simulations are taken from 1-D gas exchange simulations that are tuned to match engine tests.

A complex chemistry model of reduced size (65 species and 268 reaction steps) derived on the basis of n-heptane auto-ignition kinetics, low hydrocarbon oxidation chemistry, poly-aromatic hydrocarbon (PAH) and NOx formation kinetics together with a phenomenological soot model have been integrated with the KIVA code for multidimensional diesel simulations. A partially stirred reactor model is used to handle the turbulence-chemistry interaction. The results obtained from numerical simulations for a direct-injection (DI) diesel spray, which is injected into a constant-volume combustion vessel at engine-like conditions, show that the approach is able to reproduce the transient diesel auto-ignition and combustion processes as observed in many optical imaging studies. The simulated results indicate that the auto-ignition of DI diesel spray occurs at a lean site close to the mean stoichiometric line for the cases tested.

The effects of injection pressure and duration on exhaust gas emissions, sooting flame temperature, and soot distribution for a heavy–duty single cylinder DI diesel engine were investigated experimentally. The experimental analysis included use of two–color pyrometry as well as “conventional” measuring techniques. Optical access into the engine was obtained through an endoscope mounted in the cylinder head. The sooting flame temperature and soot distribution were evaluated from the flame images using the AVL VisioScope™ system. The results show that the NOx/soot trade–off curves could be improved by increasing injection pressure. An additional reduction could also be obtained if, for the same level of injection pressure, the injection duration was prolonged.

Today numerical models are a major part of the diesel engine development. They are applied during several stages of the development process to perform extensive parameter studies and to investigate flow and combustion phenomena in detail. The models are divided by complexity and computational costs since one has to decide what the best choice for the task is. 0D models are suitable for problems with large parameter spaces and multiple operating points, e.g. engine map simulation and parameter sweeps. Therefore, it is necessary to incorporate physical models to improve the predictive capability of these models. This work focuses on turbulence and mixing modeling within a 0D direct injection stochastic reactor model. The model is based on a probability density function approach and incorporates submodels for direct fuel injection, vaporization, heat transfer, turbulent mixing and detailed chemistry.

The possibilities for extending the range of engine loads in which soot and NOx emissions can be minimised by using low temperature combustion in conjunction with high levels of EGR was investigated in a series of experiments with a single cylinder research engine. The results show that very low levels of both soot and NOx emissions can be achieved at engine loads up to 50 % by reducing the compression ratio to 14 and applying high levels of EGR (up to approximately 60 %). Unfortunately, the low temperature combustion is accompanied by increases in fuel consumption and emissions of both HC and CO. However, these drawbacks can be reduced by advancing the injection timing. The research engine was a 2 litre direct injected (DI), supercharged, heavy duty, single cylinder diesel engine with a geometry based on Volvo's 12 litre engine, and the amount of EGR was increased by adjusting the exhaust back pressure while keeping the charge air pressure constant.

This paper presents an investigation of the effects of varying needle opening pressure (NOP) (375 to 1750 bar), engine speed (1000 rpm to 1800 rpm), and exhaust gas recirculation (EGR) (0% to 20 %) on the combustion process, exhaust emissions, and fuel consumption at low (25 %) and medium (50 %) loads in a single cylinder heavy duty DI diesel research engine with a displacement of 2.02 l. The engine was equipped with an advanced two-actuator E3 Electronic Unit Injector (EUI) from Delphi Diesel, with a maximum injection pressure of 2000 bar. In previous versions of the EUI system, the peak injection pressure was a function of the injection duration, cam lift, and cam rate. The advanced EUI system allows electronic control of the needle opening and closing. This facilitates the generation of high injection pressures, independently of load and speed.

The objective of the study presented here was to examine the possibility of simultaneously reducing soot and nitrogen oxide (NOx) emissions from a heavy duty diesel engine, using very high levels of EGR (exhaust gas recirculation). The investigation was carried out using a 2 litre DI single cylinder diesel engine. Two different EGR strategies were examined. One entailed maintaining a constant charge air pressure with a varied exhaust back pressure in order to change the amount of EGR. In the other strategy a constant pressure difference was maintained over the engine, resulting in different equivalence ratios at similar EGR levels. EGR levels of 60 % or more significantly reduced both soot and NOx emissions at 25 % engine load with constant charge air pressure and increasing exhaust back pressure. However, combustion under these conditions was incomplete, resulting in high emissions of carbon monoxide (CO), unburned hydrocarbons (HC) and high fuel consumption.

The effects of EGR on diesel combustion were visually examined in a single-cylinder heavy duty research engine with a low compression ratio, low swirl, a CR fuel injection system and an eight-orifice nozzle. Optical access was primarily obtained through the cylinder head. The effects of EGR were found to be significant. NOx emissions were reduced from over 500 ppm at 0% EGR to 5 ppm at 55% EGR. At higher levels of EGR (approximately 35% or more) there was a loss in efficiency. Constant fuel masses were injected. Results from the optical measurements and global emission data were compared in order to obtain a better understanding of the spray behaviour and mixing process. Optical measurements provide fundamental insights by visualizing air motion and combustion behaviour. The NOx reductions observed might be explained by reductions in oxygen concentration associated with the increases in EGR.

Believed to have a potential in reducing the NOx emission level, hydrogen peroxide was fumigated into the inlet duct of the AVL single cylinder research engine via a standard gasoline injector, normally used in the Volvo 850-car engine. A small metallic sphere installed 3 cm downstream the injector tip, improved the spray formation and the uniform distribution of the fumigated peroxide fluid upstream the intake valve. The hydrogen peroxide flow was varied according to the desired value via an electronic pulse frequency generator. The engine, equipped with an electronic unit injector, was initially run without any fumigation fluid until the specifications of the engine test point were reached and remained very stable. Further, the hydrogen peroxide injection was activated with three different injection flows, and the engine performance, including emission levels, was compared to reference performance.

In this case study, a human factors analysis was carried out in the preliminary design phase of the Cupola, a European Space Agency (ESA) module for manned space flights for the International Space Station (ISS). The manikin software Jack® was used early in the design process before any flight hardware production. All Cupola astronaut tasks were evaluated in a virtual environment of the Cupola. Methodological aspects concerning the analysis are described, e.g. file processing, use of coordinate systems and the use of a prior task analysis. Results show that the thorough manikin analysis supported with the hierarchical task analysis results, was an important help in the design process.