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Technical Paper

Evaluation of Three-Way Catalysts - Part III Formation of NH3, Its Suppression by SO2 and Re-Oxidation

1978-02-01
780606
This is the third and final communication in this series of laboratory evaluation of three-way catalysts. The effect of inlet NO concentration and temperature on the NH3 formation over fresh, pulsator-aged and dynamometer-aged three-way catalysts of the current generation has been investigated under temperatures and exhaust compositions of practical interest. In spite of differences in aging procedures employed, both the pulsator and dynamometer-aged catalysts show similar selectivity behavior. The effect of SO2 in feed-gas on gross NO conversion and NH3 formation was studied over Pt-Rh and Pt-Rh-Ru types of three-way catalysts. A strong dependence of the gross NO conversion on the SO2 concentration in exhaust gas mixtures was noted. A simultaneous suppression of gross NO conversion and NH3 formation, in presence of SO2 in feed-gas, is attributed to the poisoning of Pt sites on aged three-way catalysts.
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