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Continuous measurement of dilute exhaust gas from the CVS system, which provides gas concentrations proportional to the mass of emissions, is widely used for modal mass analysis of exhaust emission. Recently, exhaust gas flow rate measurement devices have become commercially available. Cost-effective raw exhaust modal mass analysis will be feasible with a combination of the new exhaust gas flow meters and fast response gas analyzers. In this paper, the benefits of raw exhaust modal mass measurement and the impacts of response time for the gas analyzer on the accuracy of exhaust mass calculations are discussed. Gas analyzer system with enhanced speed of response has been developed by hardware modification applied to the existing conventional bench system. De-convolution or inverse digital filter techniques that compensate the delay in the exhaust sampling system and the gas analyzer are described with comparisons to the hardware modifications.

For the purposes of environmental protection, regulations of particulate matter are becoming more stringent year by year. Accordingly, engine systems have been improved and particulate emissions are much lower compared to those of previous engine systems. The automotive industry generally uses a gravimetric method to quantify particulate emissions. It is becoming increasingly difficult to quantify particulate emissions using a conventional gravimetric balance because the amount of particulates continues to decline. In order to overcome this problem, a new method has been developed that uses gas analyzers to measure potentially as much as several micrograms of particulates. Furthermore, with this method, it is possible to simultaneously analyze volatile organic fraction (VOF), soot, and sulfates. The particles collected by a quartz filter are placed in a furnace at a specific temperature, and VOF and sulfates are vaporized in an inert atmosphere.

This paper presents a technique for examining “Goodness of Fit” of polynomial least square curves using “errorless” data. (The errors in “real world” data tend to mask a polynomial curve's lack of fit). A method of assessing the “quality” of real data before attempting to fit a curve to the data is also presented. If data “quality” proves satisfactory, a cubic spline curve can be generated which provides a much better fit to the data than can ever be attained using polynomial curves.

In order to control diesel engine emission, several after-treatment technologies have been studied and developed to reduce particulate matter (PM) and nitrogen oxides. Such reduction is making it hard to measure the mass of such pollutants. In the present study, a new method to analyze nitrogen compounds in vehicle particulate has been described. The method is based on the technique for separate analysis of SOF, soot and sulfates in particulate, which has been previously reported by the authors. The new method utilizes oxidation process in a furnace at high temperature and a chemiluminescence detector (CLD) to measure generated NO and NO2. In this paper, principle and concept of the method has been described. In addition, feasibility of the method for analyzing nitrogen compounds in vehicle PM has been discussed, with practical experiments using modeled samples and actual particulate.

The European Union has announced the next term emission regulations for light-duty vehicles which include particle number (PN) emission standards. The protocol for PN counting for the regulation is described in UNECE Regulation No.83. The PN counting system required for this regulation should consist of a Volatile Particle Remover (VPR) and a Condensation Particle Counter (CPC). The regulation also requires calibration of the VPR's Particle Concentration Reduction Factor (PCRF) periodically. Since the PCRF is directly used in the calculation of PN emission, an improper calibration of the factor can cause a significant error of PN emission result. This paper investigates propriety to use NaCl particles generated by atomizing method in the PCRF calibration as reference particles. As a result, it is shown that the NaCl particles can be used in PCRF calibration because of the sufficient stability when appropriate thermal treatment is applied.