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Technical Paper

The Effect of Aging Temperature on Catalyst Performance of Pt/Rh and Pd/Rh TWCs

2000-06-19
2000-01-1954
With the ever-increasing stringency of emissions regulations, automotive three-way catalysts (TWCs) require much faster light-off performance and higher warmed-up activity than before. Most automotive manufacturers are considering the adoption of close-coupled catalyst systems as a means of dealing with cold start emissions and need the catalyst to have improved thermal durability. In this paper, a new Pd/Rh is reported to be suitable for high temperature application. Due to the recent increasing Pd metal cost, a Pt/Rh with equivalent or better TWC performance needs be developed to balance the PGM usage. A current Pt/Rh catalyst seems to possess comparable TWC performance to the new Pd/Rh catalyst when the catalysts are aged at 900°C. However, aging at a temperature higher than 900°C significantly deactivated the activity of the Pt/Rh catalyst to a point that is much worse than the Pd/Rh catalyst.
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