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Atmospheric pollution is the major public health issue in many cities around the world. Internal combustion engines (ICE) and industries are common sources of pollutants that aggravate this situation. Aiming to overcome this problem, increasingly restrictive legislation on combustion pollutant emissions has been formulated and new technologies are being developed to ensure compliance with such restrictions. In this scenario, the lean mixtures appear as a possible alternative, but also bring some inconveniences such as combustion instabilities. Pre-chamber ignition systems (PCIS) enable a more stable combustion process due to high kinetic, thermal and chemical energy of the gases from the pre-chamber (PC), which pass through nozzles and begin the combustion process of the air-fuel mixture contained in the main combustion chamber (MC). However, some challenges still have to be overcome in the development of these systems, one of the main ones being hydrocarbon (HC) emissions.