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Water reuse is essential for long duration space missions. However, water recycle systems also provide a habitat for microorganisms and allow accumulation of chemical compounds which may be acutely or chronically toxic to mission crew members. Contaminant fate and accumulation in closed-loop water recycle systems is being investigated at the University of Colorado and Martin Marietta as part of the activities of the Center for Space Environmental Health (CSEH), a NASA Specialized Center of Research and Training (NSCORT). The water contaminant distribution research uses a scaled-down physical model of a water (shower, laundry, urine and/or condensate) recycle system to analyze for and model four “indicator” contaminants: viruses and bacteria, nitrogen species, and selected organic and inorganic compounds. The water recycle test bed is comprised of five or more individual water treatment processes linked in a closed loop, and spiked with chemical and biological contaminants.

Iodine is being considered for disinfection of recycled hygiene and potable water in Space Station Freedom. Like chlorine, the halogen iodine can form disinfection by-products (DBPs) when used as a disinfectant in waters with dissolved or colloidal organic compounds. Recycled shower and laundry wastewater, urine and condensate from the space cabin atmosphere all have large amounts of dissolved and colloidal organic compounds and may generate iodinated DBP's which can be toxic to humans. We have investigated the formation of iodinated DBP's (IDP's) in model compounds typical of shower wastewater and condensate. The selection of these model compounds and flask experiments to test for IDP formation have been described. Methods for reaction, extraction and analysis for IDP's also have been developed. We have tentatively identified likely organic precursors from recycled water and several iodinated organic compounds formed during the reaction with iodine.