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Journal Article

Counter-Flow Silica-Titania Reactor for the Simultaneous Treatment of Air and Water Contaminated with VOCs

2009-07-12
2009-01-2524
The photocatalytic oxidation of VOCs was investigated using a novel countercurrent flow reactor designed to enable the treatment of toluene present in the gas and the aqueous phases simultaneously. The reactor was packed with silica-titania composites commingled with plastic pall rings. Using this mixed packing style was advantageous as it resulted in a higher UV penetration throughout the reactor. The average UV intensity in the reactor was determined to be 220 μW/g irradiated TiO2. It was found that under dry conditions, the STCs had a high adsorption capacity for toluene; however, this adsorption was completely hindered by the wetting of the STCs when the two phases were flowing simultaneously. The destruction of toluene in the aqueous phase was determined to follow a linear trend as a function of the contaminant concentration.
Technical Paper

TiO2 Coated Activated Carbon: A Regenerative Technology for Water Recovery

2002-07-15
2002-01-2357
Two widespread practices in water treatment are, removal of pollutants via adsorption onto activated carbon, and, oxidation of pollutants using a photocatalyst slurry and ultraviolet radiation. The ultimate goal of this research is to combine the adsorptive properties of carbon and the oxidative properties of titanium dioxide (TiO2), and construct a photocatalytically regenerative carbon filter for 100% water recovery. The premise is that the activated carbon, coated with TiO2, will capture the compounds through traditional filtration and adsorption. Once the carbon becomes exhausted, it can be regenerated in-situ by turning on the UV lamps thereby activating the photocatalyst.
Technical Paper

Post-Treatment of Anaerobically Digested Solid Waste in Long Term Space Missions

2006-07-17
2006-01-2258
Post-treatment of anaerobically digested residue produced during long term space missions was investigated. Solid waste was anaerobically digested by employing the SEBAC system. One of the goals of post-treatment step is to convert ammonia in the residue to nitrates via biological nitrification processes. It was found that anaerobically digested residue contained nitrifying microorganisms which could be activated by aeration. Without supplying any external nitrifying inoculum, nitrification was initiated within 2 days by continuously blowing air at 15 ml/min. The maximum rate was 0.78 mg /g dry weight /day. However, denitrification process occurred soon after nitrification and ∼ 50% of nitrate was denitrified. A modified system in which aeration was carried out by holding air within the reactor at a pressure of ∼ 10 psi yielded a higher initial specific nitrification rate of 1.7 mg/g dry weight/day. Moreover, nitrification was initiated within a day.
Technical Paper

Synthesis and Evaluation of Activated Carbon Composite Photocatalysts for Surface Enhanced Raman Scattering: Photocatalytic Layer Coating

2004-07-19
2004-01-2332
Finding a manner to effectively filter water to the purest standards is an ongoing battle for various sectors of science. We present a set of experiments that will report the preparation of the photocatalytic component of our composite particle via sol-gel coatings with titanium n-butoxide with subsequent heat treatment at 500°C for three hours in Argon. Our ultimate goal is to create a particle with regenerative capabilities along with a surface enhanced Raman scattering effect. Characterization techniques were performed using SEM-EDS, and XRD.
Technical Paper

Effects of High Productivity Machining on Ti-6Al-4V Surface Topography

2004-09-21
2004-01-2827
Surface defects were demonstrated to result from high productivity machining (HPM) as well as conventional machining of a titanium alloy Ti-6Al-4V, with HPM causing the larger sized defects. These defects could act as initiation sites for fatigue cracks showing that machining would affect fatigue strength and life of the part produced. A finishing pass appears to remove the defects. Better understanding is needed of the relationships between machining, surfaces, and strength.
Technical Paper

High Speed Machining of Helicopter Gearcases

2004-09-21
2004-01-2826
High speed machining of aluminum and magnesium helicopter gearcases was experimentally demonstrated to be five times more productive than contemporary conventional commercial practice for suitable operations. Appropriate techniques and performance characteristics are discussed for face milling, endmilling and planetary milling operations. Potential problem areas, such as surface characteristics and machine tool performance requirements are discussed.
Technical Paper

ALS-Integrated Food/Fiber Production and Packaging System for Long-term Space Mission to Mars

2004-07-19
2004-01-2522
This is a concept paper to help outline a roadmap for planning research and development efforts that could lead to a realistic and workable food system for long-term space travel. The paper describes a proposed system by which sufficient food and fiber can be provided for a six-person crew on a 3-year round trip mission to Mars with only a 9-month supply initially brought on board. The proposed system will also integrate with other advanced life support (ALS) subsystems in a number of synergistic ways. Rationale for this paper stems from the belief that a system based upon “backpacking” a 3-year supply of all consumables for lift off onboard the vehicle (while compacting, storing and returning with all the resulting waste and trash) will neither be technically nor economically feasible.
Technical Paper

Mission Planning for UAV Sensing Tasks in Close Proximity Environments

2007-09-17
2007-01-3846
Unmanned aerial vehicles (UAVs) stand to play a significant role in future sensing and information gathering missions. The scope of these mission scenarios is expanding to include those missions for which the sensor and carrier vehicle will be in close proximity to the surrounding environment, such as in urban operations. Several unique problems related to guidance, navigation and control are introduced that separate these tasks from the existing paradigm for information gathering missions at standoff range. This paper examines the challenges related to autonomous sensor planning missions in these close proximity environments and discusses solution strategies to achieve maximal sensing effectiveness. Specifically, results from vision-based navigation research are discussed and the concept of a geometric sensing effectiveness criterion is introduced and subsequently utilized for motion planning.
Technical Paper

Low Pressure Greenhouse Concepts for Mars: Atmospheric Composition

2002-07-15
2002-01-2392
The main principles of artificial atmospheric design for a Martian Greenhouse (MG) are described based on: 1. Cost-effective approach to MG realization; 2. Using in situ resources (e.g. CO2, O2, water); 3. Controlled greenhouse gas exchange by using independent pump in and pump out technologies. We show by mathematical modeling and numerical estimates based on reasonable assumptions that this approach for Martian deployable greenhouse (DG) implementation could be viable. A scenario of MG realization (in terms of plant biomass/photosynthesis, atmospheric composition, and time) is developed. A list is given of technologies (natural water collection, MG inflation, oxygen collection and storage, etc.) that are used in the design. The conclusions we reached are: 1. Initial stocks of oxygen and water probably would be required to initiate plant germination and growth; 2. Active control of MG ventilation could provide proper atmospheric composition for each period of plant growth; 3.
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