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Journal Article

Nonuniform Heat Source Model for a Lithium-Ion Battery at Various Operating Conditions

2011-04-12
2011-01-0654
As battery temperature greatly affects performance, safety, and life of Li-ion batteries in plug-in and electric vehicles under various driving conditions, automakers and battery suppliers are paying increased attention to thermal management for Li-ion batteries in order to reduce the high temperature excursions that could decrease the life and reduce safety of Li-Ion batteries. Currently, the lack of fundamental understanding of the heat generation mechanism due to complex electrochemical phenomena prohibits accurate estimation of the heat generation within Li-ion cells under various operating conditions. Heat from Li-ion batteries can be generated from resistive dissipation, the entropy of the cell reaction, heat of mixing, and other side chemical reactions. Each of these can be a significant source of heat under a range of circumstances.
Technical Paper

Computational Modeling of Diesel NOx Trap Desulfation

2005-10-24
2005-01-3879
The major challenge in diesel NOx aftertreatment systems using NOx adsorbers is their susceptibility to sulfur poisoning. A new computational model has been developed for the thermal management of NOx adsorber desulfation and describes the exothermic reaction mechanisms on the catalyst surface in the diesel NOx trap. Sulfur, which is present in diesel fuel, adsorbs as sulfates and accumulates at the same adsorption sites as NOx, therefore inhibiting the ability of the catalyst to adsorb NOx. Typically, a high surface temperature above 650 °C is required to release sulfur rapidly from the catalyst [1]. Since the peak temperatures of light-duty diesel engine exhaust are usually below 400 °C, additional heat is required to remove the sulfur. This report describes a new mathematical model that employs Navier-Stokes equations coupled with species transportation equations and exothermic chemical reactions.
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