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Theoretically, homogeneous charge compression engines (HCCI) are able to grant a high thermal efficiency, as well as a low NOx and particulate emissions. This ability is mainly due to the combustion process, which, contrary to both Diesel and Gasoline engine, is homogeneous in time and space within the combustion chamber. But despite these advantages, the engine operating condition is limited by the narrow boundaries of misfire at low load and knocking at high load. For that matter, one of the numerous ways of overcoming knocking is to deliberately create fuel inhomogeneities within the combustion chamber, since it has proved to lengthen combustion duration and to drastically reduce maximum pressure rise rate (PRR). Nevertheless, though the global effects of fuel inhomogeneities on PRR have been studied, we lack information that explains this phenomenon.

The time of, and location where ignition first occurs in a diesel fuel spray were investigated in a rapid compression machine (RCM) using the two–dimensional techniques of silicone oil particle scattering imaging (SSI), and the planar laser induced fluorescence (LIF) of formaldehyde. Formaldehyde has been hypothesized to be one of the stable intermediate species marking the start of oxidation reactions in a transient spray under compression ignition conditions. In this study, the LIF images of the formaldehyde formed in a diesel fuel spray during ignition process have been successfully obtained for the first time by exciting formaldehyde with the 3rd harmonic of the Nd:YAG laser. SSI images of the vaporizing spray, and the LIF images of formaldehyde were obtained together with the corresponding time record of combustion chamber pressures at initial ambient temperatures ranging from 580 K to 790 K.

Thermal and mixing stratifications have been thought as one of the ways to avoid an excessive pressure rise on HCCI combustion. The purpose of this research is to investigate the potential of thermal and mixing stratifications for reducing PRR (Pressure Rise Rate) on HCCI combustion. The pre-mixture with thermal and mixing stratifications is charged in RCM (Rapid Compression Machine). After that, the pre-mixture is compressed and in that process, in-cylinder gas pressure and chemiluminescence images are obtained and analyzed. Furthermore, experimental results are compared with the computational results calculated by using multi-zone model for analyzing these mechanisms.