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The combustion mechanism of the homogeneous charge compression ignition (HCCI) engine has been investigated by numerical calculations. Calculations were carried out using n-butane/air elementary reactions at 0 dimension and adiabatic condition to simplify the understanding of chemical reaction mechanisms in the HCCI engine without complexities of walls, crevices, and mixture inhomogeneities. n-Butane is the fuel with the smallest carbon number in the alkane family that shows two-stage auto-ignition, heat release with low temperature reaction (LTR) and high temperature reaction (HTR), similar to higher hydrocarbons such as gasoline at HCCI combustion. The CHEMKIN II code, SENKIN and kojima's n-butane elementary reaction scheme were used for the calculations. This paper consists of three main topics. First, the heat release mechanisms of the HCCI engine were investigated. The results show that heat release with LTR is HCHO oxidation reactions.

Homogeneous charge compression ignition (HCCI) is regarded as the next generation combustion regime in terms of high thermal efficiency and low emissions. It is difficult to control autoignition and combustion because they are controlled primarily by the chemical kinetics of air/fuel mixture. In this study, it was investigated the characteristics of autoignition and combustion of natural gas in a four-stroke HCCI engine using experiment and elementary reactions calculation. The influence of equivalence ratio, intake temperature, intake pressure and engine speed on autoignition timing, autoignition temperature, combustion duration and the emissions of THC, CO, CO2 were investigated. And also, to clarify the influence of n-butane on autoignition and combustion of natural gas, it was changed the blend ratio of n-butane from 0 mol% to 10 mol% in methane / n-butane / air mixtures.

In the HCCI (Homogeneous Charge Compression Ignition) engine, a mixture of fuel and air is supplied to the cylinder and auto-ignition occurs resulting from compression. This method can expand the lean flammability limit, realizing smokeless combustion and also having the potential for realizing low NOx and high efficiency. The optimal ignition timing is necessary in order to keep high thermal efficiency. The Ignition in the HCCI engine largely depends on the chemical reaction between the fuel and the oxidizer. Physical methods in conventional engines cannot control it, so a chemical method is demanded. Combustion duration is maintained properly to avoid knocking. In addition, the amount of HC and CO emissions must be reduced. The objective of this study is to clarify the following through calculations with detailed chemical reactions and through experiment with the 2-stroke HCCI engine: the chemical reaction mechanism, and HC and CO emission mechanisms.

The operating range is restricted by knocking and misfiring in a homogeneous charge compression ignition (HCCI) engine. In an HCCI engine, the autoignition does not always mean the high combustion efficiency because the operating range to achieve high combustion efficiency is very narrowly restricted by knocking and high THC, CO emissions. In this study, we have investigated the operating conditions to achieve high combustion efficiency and low CO emission in a four-stroke HCCI engine using experimental analysis and elementary reactions calculation. It is shown that the combustion efficiency reaches higher than 90%, and the CO emission can be reduced considerably when the in-cylinder maximum gas temperature is over 1600K.

Homogeneous Charge Compression Ignition (HCCI) is good method to be higher efficiency and to reduce NOx emission and particular matter together than conventional SI combustion engine. But HCCI depends on chemical reaction of fuel and air mixture. So controlling of ignition timing is difficult, and HCCI is high THC and CO emissions because temperature can't reach the enough temperature to reduce those. In this study, we investigated factor for auto ignition timing and combustion completion on n-Butane/Air mixture by a two-stroke HCCI engine. Auto Ignition temperature are known to be decided by fuel(1), for n-Butane, the temperature was 1150±30K. And as we researched combustion completion from In-cylinder gas temperature, increasing In-cylinder gas temperature caused high combustion efficiency and low THC, CO emissions.